SrBaSiO4:Eu2+ phosphor: a novel application for improving the luminous flux and color quality of multi-chip white LED lamps

This paper described in detail the chromatic homogeneity and luminous flux influences in producing better quality white LED devices with various phosphor layers (MCW-LEDs). The method is to let Eu2+-activated strontium–barium silicate (SrBaSiO4:Eu2+) mixed with their phosphor compounding, which results in notable impact on lighting performance. The increase in concentration of yellow-green-emitting SrBaSiO4:Eu2+ phosphor also promotes the color performance and lumen output of WLED devices at high correlated color temperature around 8500K. This is the first time this approach is applied and it results can be utilized for better understanding of optical properties interaction with phosphor materials. Although SrBaSiO4:Eu2+ receives many positive responses, we still need to limit it concentration for high SrBaSiO4:Eu2+ concentration is detrimental to CQS. The appropriate choice of concentration and size of SrBaSiO4:Eu2+ is the principal factor to decide the performance of MCW-LEDs

The application of double-layer remote phosphor structures in increasing WLEDs color rendering index and lumen output

The remote phosphor structure often has inferior color quality but better luminous flux in than conformal or in-cup configurations. Therefore, numerous researches study remote phosphor structure for methods to enhance it chromatic quality. This study introduces the use of dual-layer remote phosphor structure in WLEDs with identical structure but at different color temperature, 6600K and 7700K, to demonstrate their effect on quality indicators. The concept is placing a green phosphor layer (Ce,Tb)MgAl11O19:Ce:Tb or a red phosphor layer MgSr3Si2O8:Eu2+,Mn2+ on the layer of yellow-emitting phosphor YAG:Ce3+ and find the suitable concentration of the additional phosphor to create the best color quality. The results showed that the increase of CRI and CQS are affected by MgSr3Si2O8:Eu2+,Mn2+, in particular, the higher the concentration of red phosphor gets the better CRI and CQS because the emitted red light in enhanced. The green phosphor layer (Ce,Tb)MgAl11O19:Ce:Tb, on the other hand, is beneficial for the luminous flux. The concentration of MgSr3Si2O8:Eu2+,Mn2+ and (Ce,Tb)MgAl11O19:Ce:Tb, however, need to be adjusted properly to avoid decreasing the luminous flux due to overgrowth. The Mie scattering theory and Beer’s law are the verification tools for these conclusions, which gives them the credibility to be applied in producing better quality WLEDs

LaSiO3Cl:Ce3+,Tb3+ and Mg2TiO4:Mn4+: quantum dot phosphors for improving the optical properties of WLEDs

In this research, we focus on the solutions to enhance the lighting properties as well as the heat regulation of the white light-emitting diodes (WLEDs) with conventional phosphor and quantum dots (QDs). Although receiving lots of attention for being an innovative lighting solution with good color rendering index, the potentials of WLEDs conjugated with quantum dots (QDS), especially the QDs-phosphor mixed nanocomposites ones, are restrained due to the lacking performance in the aspects mentioned above. The crucial requirement to produce better WLEDs is finding solutions that improve the lacking aspects, therefore, through observing previous studies and applying advanced technique, this research suggest an effective and unique packaging configuration, in which the nanocomposites QDs-phosphor layer is set horizontally to the WLED. This novel packaging configuration allow WLED performance in terms of lighting and heating to reach it peaks. This is the first time four different types of WLEDs, single-layer phosphor, dual-layer remote phosphor with yellow-red and yellow-green, and triple-layer phosphor, were simulated, utilized and compared in one study to decide the best WLED configuration. The results show that the triple-layer phosphor configurations improve the color rendering ability and lumen output better than the other configurations

The Effects of ZnO particles on the color homogeneity of phosphor-converted high-power white LED light sources

Color homogeneity is one of the goals to continuously improve WLED. Among the methods for enhancing the color uniformity of WLEDs, improving scattering in phosphor layer is considered to be the most effective. In this paper, ZnO is used for that purpose. The results show that ZnO particle size significantly affects scattering in the phosphor layer, which is a vital factor to analyze scattering, scattering sand surface, scattering coefficient and scattered phase function C_sca (D,λ), μ_sca (λ) and ρ(θ,λ). In addition, the concentration of ZnO was also analyzed with values from 2% to 22%. Color homogeneity depends not only on size but also on the concentration of added ZnO. Therefore, color homogeneity control is the control of ZnO size and concentration. The proposed result is 10% ZnO for the highest lumen of LED. With 14% and 500 nm of ZnO particles, ΔCCT reaches the lowest. Depending on the production needs, manufacturers can choose the most appropriate way. However, with both required lumen and ΔCCT, 14% ZnO is suitable for ZnO sizes

Utilizing CaCO3, CaF2, SiO2, and TiO2 particles to enhance color homogeneity and luminous flux of WLEDs

The chromatic homogeneity and luminous efficiency are two crucial elements for determining a high-quality phosphor-converted LEDs (pc-LEDs). Thus, this paper provides essential information in choosing the particles to enhance lighting properties of high performance pc-LEDs. Scattering enhancement particles (SEP) such as CaCO3, CaF2, SiO2, and TiO2, are combined with yellow phosphor Y3Al5O12:Ce3+ and applied to the lighting devices. Initially, optical simulations are carried out with the support of LightTools program. Next, the Mie-theory is applied to calculate and confirm the results. The calculation subjects are SEPs scattering properties within the band 455 -595 nm. The scattering results of TiO2 suggest it is the optimal choice for pc-LEDs color quality in comparison to the other SEPs; however, it causes the luminous flux to decrease significantly along with the increase in its concentration. Besides, with the addition of SiO2 grains, we can accomplish higher lumen output at all particle sizes. Meanwhile, the application of 30% CaCO3 can decrease the CCT deviation by 620 K making CaCO3 the potential particle to be selected for chromatic quality and light output enhancement of pc-LEDs

The options in remote phosphor structure for better white LEDs color quality

The WLEDs configuration with remote phosphor layers has higher luminescent performance than WLEDs with dispense coating or conformal coating and is applied for many modern devices. However, managing the chromatic performance of lighting structure with remote phosphor materials is a challenging objective that demands more research. This has inspired the usage of multi phosphor configurations with distance in between the layers to improve color quality. The results of this manuscript can support the manufacturers in choosing the optimal configuration for optical performance in LEDs devices with more than one phosphor material. The simulated model used in the experments is 6500 K CCT WLEDs, which results show the triple-layers structure is more favorable in terms of color quality and light output. Besides, a notable reduction occurs in color deviation means that chromatic stability is also enhanced in WLEDs with three phosphor layers. Through experimental results, which were confirmed by the Mie-scattering theory, this research offers valuable approach and details to produce better WLEDs

Y2O3:Ho3+ and ZnO:Bi3+: a selection for enhancing color quality and luminous flux of WLEDs

As the luminescence industry develops, the white light light-emitting diode (LED) package with a single chip and a single phosphor although produces good luminous flux but has a poor color rendering index (CRI) can no longer fulfill the requirements of modern lighting applications. Therefore, this research is conducted to response to the urgent demands of improving other lighting qualities of WLED while maintaining high luminous efficiency. To achieve this target, we applied the new WLED package, which contains multi-chips and multi-phosphor layers, and have obtained outstanding results in both CRI and luminous efficacy. Two types of phosphor used in the WLED package are Y2O3:Ho3+ and ZnO:Bi3+. A color configuration model is also developed to adjust the shading of the white-light LED module. The results of this research show that the triple-layer phosphorhas the best performance when applied in a white-light LED package, which is demonstrated through better color quality, CRI and luminous efficacy, The manufacturers can rely on this research to produce the optimal-quality WLED, or WLED that is appropriate to their quality demands

Improving color quality and luminous flux of white LED utilizing triple-layer remote phosphor structure

In this manuscript, we presented a research that enhance the performance of WLED using the multi-phosphor configuration. The phosphor layers in the research are separated from each other to achieved better luminous efficiency, however, it makes controlling color light quality more complex. Another issue is finding out the whether two layers of phosphor or three layers of phosphor is better in improving color quality. The research addressed this issue by analyzing the optical aspects of the respective WLEDs that employ these structure. The studied aspects are quality indicators such as luminous efficacy (LE), and color uniformity, color rendering index (CRI), color quality scale (CQS). The results of the experiments in this research, which come from the employment of WLEDs with 2 color temperatures 5600 K and 8500, suggest that WLED with three phosphor layers is better in CRI, CQS, LE. This type of phosphor structure also limits the color deviation significantly, thus, improves the color uniformity. This results is verifies with Mie theory, therefore, can be applied as reference or guideline for production of better WLED

The application of green YPO4:Ce3+,Tb3+ and red LiLaO2:Eu3+ layers to remote phosphor LED

Remote phosphor structure is commonly limited in color quality, but has greater luminous flux when comparing to structures with in-cup or conformal coating. From this dilemma, various researches with advance modifications have been proposed to perfect the chromatic performance of remote structure. In this research, we reach higher color quality by obtaining better values in quality indcators such as color rendering index (CRI) and color quality scale (CQS) with the dual-layer phosphor in our remote white light-emitting diodes (WLEDs). The idea is to ultize WLEDs with 7000 K correlated color temperature (CCT) and create dual-layer configuration with yellow phosphor YAG:Ce3+ under green phosphor YPO4:Ce3+,Tb3+ or red phosphor LiLaO2:Eu3+. After that, we search for suitable concentration of LiLaO2:Eu3+ for addition in order to acquire the finest color quality. The result shows that WLED with LiLaO2:Eu3+ has better CRI and CQS as the higher the concentration of LiLaO2:Eu3+, the larger CRI and CQS due to increased light scattered in WLEDs. Meanwhile, the green phosphor layer YPO4:Ce3+,Tb3+ give advantages to luminous flux. However, the reduction in luminous flux and color quality occurs when the concentration of LiLaO2:Eu3+ and YPO4:Ce3+,Tb3+ over increase. Results are verified by Mie theory and Beer’s Law and can be applied to practical manufacturing of high quality WLEDs