原位表征技术揭示析氢电催化剂活性中心

文章简介课题组以导电碳布上生长的氢氧化镍纳米片为模板,通过与对苯二硫酚配体反应,成功合成出具有平面Ni（SR）4配位结构的镍—硫醇配位聚合物纳米片,并发现该材料在碱性析氢测试中,催化活性随测试时间逐渐加存在明显诱导期的现象。在保持20m A/cm2的电流密度条件下,析氢所需过电位逐渐降低,约10小时后该

A 1,000 Frames/s Programmable Vision Chip with Variable Resolution and Row-Pixel-Mixed Parallel Image Processors

A programmable vision chip with variable resolution and row-pixel-mixed parallel image processors is presented. The chip consists of a CMOS sensor array, with row-parallel 6-bit Algorithmic ADCs, row-parallel gray-scale image processors, pixel-parallel SIMD Processing Element (PE) array, and instruction controller. The resolution of the image in the chip is variable: high resolution for a focused area and low resolution for general view. It implements gray-scale and binary mathematical morphology algorithms in series to carry out low-level and mid-level image processing and sends out features of the image for various applications. It can perform image processing at over 1,000 frames/s (fps). A prototype chip with 64 × 64 pixels resolution and 6-bit gray-scale image is fabricated in 0.18 μm Standard CMOS process. The area size of chip is 1.5 mm × 3.5 mm. Each pixel size is 9.5 μm × 9.5 μm and each processing element size is 23 μm × 29 μm. The experiment results demonstrate that the chip can perform low-level and mid-level image processing and it can be applied in the real-time vision applications, such as high speed target tracking

Structural and mechanistic insights into the biosynthesis of CDP-archaeol in membranes

The divergence of archaea, bacteria and eukaryotes was a fundamental step in evolution. One marker of this event is a major difference in membrane lipid chemistry between these kingdoms. Whereas the membranes of bacteria and eukaryotes primarily consist of straight fatty acids ester-bonded to glycerol-3-phosphate, archaeal phospholipids consist of isoprenoid chains ether-bonded to glycerol-1-phosphate. Notably, the mechanisms underlying the biosynthesis of these lipids remain elusive. Here, we report the structure of the CDP-archaeol synthase (CarS) of Aeropyrum pernix (ApCarS) in the CTP- and Mg(2+)-bound state at a resolution of 2.4 Å. The enzyme comprises a transmembrane domain with five helices and cytoplasmic loops that together form a large charged cavity providing a binding site for CTP. Identification of the binding location of CTP and Mg(2+) enabled modeling of the specific lipophilic substrate-binding site, which was supported by site-directed mutagenesis, substrate-binding affinity analyses, and enzyme assays. We propose that archaeol binds within two hydrophobic membrane-embedded grooves formed by the flexible transmembrane helix 5 (TM5), together with TM1 and TM4. Collectively, structural comparisons and analyses, combined with functional studies, not only elucidated the mechanism governing the biosynthesis of phospholipids with ether-bonded isoprenoid chains by CTP transferase, but also provided insights into the evolution of this enzyme superfamily from archaea to bacteria and eukaryotes.Cell Research advance online publication 29 September 2017; doi:10.1038/cr.2017.122

A high-speed CMOS image sensor for real-time vision chip

A high-speed CMOS image sensor for real-time vision chip is proposed. The high-speed CMOS image sensor consists of CMOS photodiode array, correlated double sampling(CDS) array, programmable gain amplifier(PGA) array, area-efficient single-slope analog-to-digital converter(ADC) array and controller circuit. It can perform the image capturing and row-parallel signal processing. It outputs digital signal or digital image at a frame rate of over1000 frame/s. It can reduce the fixed pattern noise(FPN) and amplify(or shrink) the output signals of the photodiode array to maintain the amplitude of the signal in row-parallel fashion. It can continuously perform8-bit ADC conversion in row-parallel. A128 pixel×128 pixel image sensor with128 rows of CDS, PGA and single-slope ADC is fabricated by using0.18μm1P6M CMOS process. The chip size is2.2 mm×2.6 mm. The measured results demonstrate that the designed chip can perform high-speed real-time optical signal capturing and processing. It can be applied to the real-time vision chip system

Improving FMCW GPR Precision through the CZT Algorithm for Pavement Thickness Measurements

Ground Penetrating Radar (GPR) application in road surface detection has been greatly developed in the past few decades, which enables rapid and economical estimation of pavement thickness and other physical properties in non-destructive testing (NDT) and non-contact testing (NCT). In recent years, with the rapid development of microwave and millimeter-wave solid-state devices and digital signal processors, the cost of Frequency-Modulated Continuous-Wave (FMCW) radar has dropped significantly, with smaller size and lighter weight. Thereafter, FMCW GPR is considered to be applied during pavement inspection. To improve the precision of FMCW GPR for NDT and NCT of pavement thickness, a Chirp Z-transform (CZT) algorithm is introduced to FMCW GPR and investigated in this paper. A FMCW + CZT GPR at 2.5 GHz with a bandwidth of 1 GHz was built, and laboratory and field experiments were carried out. The experimental results demonstrate that the FMCW + CZT GPR radar can obtain the sample thickness with low error and recognize subtle thickness variations. This method realizes the high precision thickness measurement of shallow asphalt pavement by FMCW radar with a narrow bandwidth pulse signal and would provide a promising low-cost measurement solution for GPR

Investigation of Electronic and Optical Properties of (Cs, Br, Cs-Br) Doped Mono-Layer Hexagonal Boron Nitride Using First Principles

Research on the effect of alternative doping on the photoelectric properties of boron nitride is still at an early stage. In particular, research on hexagonal boron nitride’s diatomic co-doping is still rarely studied. In this work, first-principles calculations are selected as the main method to investigate the electronic structure and optical properties of different atoms used to dope hexagonal boron nitride (h-BN). The band gap value of intrinsic h-BN is 4.66 eV. The band gap was changed after Cs, Br, and Cs-Br doping. The results show that the band gap is 4.61 eV when the Br atom replaces the N atom, while the band gap of h-BN doped with Cs is 3.52 eV. Additionally, the band gap width can be reduced to a typical narrower band gap width of 3.19 eV when Cs-Br is used for doping. At the same time, the complex dielectric function representing the optical properties is calculated after Cs, Br, and Cs-Br doping. The optical absorption peaks of Cs-Br-doped h-BN are weaker at low-frequency conditions. The optical absorption of h-BN can be modified by Cs doping, Br doping, and Cs-Br co-doping in the near-infrared, visible, or portion of the near-ultraviolet bands, which makes the doped material more suited for photoelectric detectors in the relevant frequency bands

Investigation of Electronic and Optical Properties of (Cs, Br, Cs-Br) Doped Mono-Layer Hexagonal Boron Nitride Using First Principles

Research on the effect of alternative doping on the photoelectric properties of boron nitride is still at an early stage. In particular, research on hexagonal boron nitride’s diatomic co-doping is still rarely studied. In this work, first-principles calculations are selected as the main method to investigate the electronic structure and optical properties of different atoms used to dope hexagonal boron nitride (h-BN). The band gap value of intrinsic h-BN is 4.66 eV. The band gap was changed after Cs, Br, and Cs-Br doping. The results show that the band gap is 4.61 eV when the Br atom replaces the N atom, while the band gap of h-BN doped with Cs is 3.52 eV. Additionally, the band gap width can be reduced to a typical narrower band gap width of 3.19 eV when Cs-Br is used for doping. At the same time, the complex dielectric function representing the optical properties is calculated after Cs, Br, and Cs-Br doping. The optical absorption peaks of Cs-Br-doped h-BN are weaker at low-frequency conditions. The optical absorption of h-BN can be modified by Cs doping, Br doping, and Cs-Br co-doping in the near-infrared, visible, or portion of the near-ultraviolet bands, which makes the doped material more suited for photoelectric detectors in the relevant frequency bands

A Comparative Analysis of Farmland Occupation by Urban Sprawl and Rural Settlement Expansion in China

The farmland loss caused by urban–rural land development has exacerbated China’s challenges of using limited farmland to feed more than 1.4 billion people. Earlier studies shed light on the impacts of urban sprawl and rural settlement expansion, separately. However, there is little quantitative understanding of which one has more severe impacts on farmland and its net primary productivity (NPP). Thus, this study used spatially explicit satellite data including land-use maps and estimated NPP data, as well as spatiotemporal analysis methods to conduct a comparative analysis of farmland loss due to urban sprawl and rural settlement expansion at different scales from 2000 to 2020 in China. The results show that during the study period, urban sprawl resulted in a loss of 49,086.6 km2 of farmland area and 8.34 TgC of farmland NPP, while the loss of farmland area and farmland NPP due to rural settlement expansion reached 18,006.8 km2 and 3.88 TgC. The largest gap between the total area of farmland loss due to urban sprawl and the total loss area due to rural settlement expansion was 12,983.3 km2 in Eastern China, while the smallest gap was 1291.1 km2 in Northeastern China. The largest gap between the loss of farmland NPP due to urban sprawl and the total loss due to rural settlement expansion occurred in Eastern China at 1.97 TgC. Spatially, the total loss of farmland and its NPP due to urban sprawl and rural settlement expansion occurred mainly in the eastern and central regions of China; the areas of farmland loss by urban sprawl were more concentrated than that by rural settlement expansion. The negative impacts of urban sprawl on farmland area and its NPP were greater in southern China than that of rural settlement expansion. Noticeably, the loss of NPP per unit of farmland due to rural settlement expansion was higher than that by urban sprawl, especially in the Yangtze River Delta and Beijing–Tianjin–Hebei region. The results highlight the non-negligible impacts of rural settlement expansion on farmland in China. It is necessary to improve farmland protection policies by optimizing the spatial allocation of urban and rural construction land