KONCEPCJA PARAMETRYCZNO-SEMANTYCZNEJ OTWARTEJ PLATFORMY INTELIGENTNYCH URZĄDZEŃ SENSOROWYCH

The parametric and semantic model of open platform of intelligent devices and sensor technologies based on tomography in cyber-physical self-monitoring system contains: new techniques of conducting measurements and construction of novel intelligent measurement devices, system's structure along with communication interface, unique algorithms for data optimization and analysis, algorithms for image reconstruction and technological processes monitoring, cyber-physical system's prototype.Parametryczno-semantyczny model otwartej platformy inteligentnych urządzeń sensorowych został oparty na technologiach tomograficznych. W samo-monitorującym się systemie cyber-fizycznym zastosowano nowe techniki pomiarowe i konstrukcje inteligentnych urządzeń pomiarowych. Proponowane rozwiązanie prototypu systemu cyber-fizycznego składa się z interfejsu komunikacyjnego, unikalnych algorytmów do optymalizacji i analizy danych oraz systemu monitoringu procesów logistyczno-technologicznych

Mӧssbauer spectroscopy as a useful method for distinguishing between real and false meteorites

In our paper fourMӧssbauer spectra of ordinary chondrites (previously classified by a classical method based on determining the ratio of ferrosilite (Fs) to fayalite (Fa) with an electron microprobe) are presented and discussed. These are the Mӧssbauer spectra of two ordinary chondrites type H (Pultusk and Grzempach), one ordinary chondrite type L (Hyattville) and one type LL (NWA 6287). These meteorites were compared, using their Mӧssbauer spectra with the following four other samples: a fragment of a rock that fell near Leoncin in Poland (sample No. 1), a fragment of a rock found in the vicinity of Pultusk in Poland (sample No. 2), a meteorite specimen bought on the meteorite exchange (sample No. 3) and a stone object whose decline was observed in Europe (sample No. 4). The spectrum of sample No. 1 is very similar to the spectrum of ordinary chondrite of type LL. This observation was confirmed using 4M method (previously created by us). The spectrum of sample No. 2 differs significantly from the spectrum of sample of the Pultusk meteorite. In the spectrum of sample No. 3, a clear signal from iron-nickel alloy and troilite can be observed. This fact allows us to state that sample No. 3 is a fragment of rock that was created in cosmic conditions. Sample No. 4 has a Mӧssbauer spectrum similar to the spectrum of terrestrial magmatic rocks. This observation does not clearly determine where the examined object comes from. This work demonstrates the usefulness of Mӧssbauer spectroscopy in recognizing samples that are fragments of meteorites

Comparative actualistic study hints at origins of alleged Miocene coprolites of Poland

Excrement-shaped ferruginous masses have been recovered from the Miocene of Turów mine in south-western Poland. These siderite masses have been the subject of much controversy, having been interpreted either as being coprolites, cololithes or pseudofossils created by mechanical deformation of plastic sediment. Here we present the results of mineralogical, geochemical, petrographic and microtomographical analyses. Our data indicate that these masses consist of siderite and iron oxide rather than phosphate, and rarely contain recognizable food residues, which may suggest abiotic origins of these structures. On the other hand, evidence in support of a fecal origin include: (i) the presence of two distinct morphotypes differing in size and shape, (ii) the presence of rare hair-like structures or coalified inclusions and (iii) the presence of rare fine striations on the surface. Importantly, comparative actualistic study of recent vertebrate feces shows overall resemblance of the first morphotype (sausage-shaped with rare coalified debris) to excrements of testudinoid turtles (Testudinoidea), whose shell fragment was found in the investigated locality. The second morphotype (rounded to oval-shaped with hair-like structures), in turn, is similar to the feces of some snakes (Serpentes), the remains of which were noted in the Miocene of the neighborhood areas. Other potential producers (such as lizards and crocodiles) and even abiotic origins cannot be fully excluded but are less likely

4M method-new application of Mössbauer spectroscopy to classification of meteorites. How it works?

4M method is a new application of Mössbauer spectroscopy to quantitative classification of ordinary chondrites. 4M derives from four words: meteorites, Mössbauer spectroscopy, multidimensional discriminant analysis, Mahalanobis distance. This method was published by us in 2019. In this paper we present application of 4M method to classification of four meteorites. Link to script with calculation needed for classification of ordinary chondrites was given

Comparative actualistic study hints at origins of alleged Miocene coprolites of Poland

Excrement-shaped ferruginous masses have been recovered from the Miocene of Turów mine in south-western Poland. These siderite masses have been the subject of much controversy, having been interpreted either as being coprolites, cololithes or pseudofossils created by mechanical deformation of plastic sediment. Here we present the results of mineralogical, geochemical, petrographic and microtomographical analyses. Our data indicate that these masses consist of siderite and iron oxide rather than phosphate, and rarely contain recognizable food residues, which may suggest abiotic origins of these structures. On the other hand, evidence in support of a fecal origin include: (i) the presence of two distinct morphotypes differing in size and shape, (ii) the presence of rare hair-like structures or coalified inclusions and (iii) the presence of rare fine striations on the surface. Importantly, comparative actualistic study of recent vertebrate feces shows overall resemblance of the first morphotype (sausage-shaped with rare coalified debris) to excrements of testudinoid turtles (Testudinoidea), whose shell fragment was found in the investigated locality. The second morphotype (rounded to oval-shaped with hair-like structures), in turn, is similar to the feces of some snakes (Serpentes), the remains of which were noted in the Miocene of the neighborhood areas. Other potential producers (such as lizards and crocodiles) and even abiotic origins cannot be fully excluded but are less likely

Can Mӧssbauer methods of classifying ordinary chondrites help to identify non-representative samples of these meteorites?

Mössbauer spectra of nonweathered ordinary chondrites consist of four main mineral phases: olivines, pyroxenes, metallic phase and troilite. These minerals represent more than 95% of the whole mass of an ordinary chondrite. Distribution of these mineral phases in micro-scale is not homogeneous. Nevertheless, preparation of representative sample of ordinary chondrite for Mössbauer measurements is possible. To do that a part of 1 g nonweathered material, selected from inside of meteorite without any specific intention is needed. The Warsaw group has been working on investigation of meteorites for 25 years and has analysed about 150 Mössbauer spectra of various meteorites. Among them we found 15 spectra, which could be suspected of being non-representative. These spectra were obtained from Baszkówka, Amber, Bjurböle, Krasnoi-Ugol and Chelyabinsk meteorites. The analysis of how the samples of meteorites were selected for investigation, has shown that the non-representativeness of samples may be due to: intentional choice of sample, preparation of sample from a too small part of material or the use of non-credible source of meteoritic samples. For confirmation of these assumptions, we used a new method of classification of ordinary chondrites – the 4M method. It turned out that this method is a very useful tool for investigation of non-representative samples of equilibrated ordinary chondrites

Zirconium-based metal–organic frameworks as acriflavine cargos in the battle against coronaviruses : a theoretical and experimental approach

[Image: see text] In this study, we present a complementary approach for obtaining an effective drug, based on acriflavine (ACF) and zirconium-based metal–organic frameworks (MOFs), against SARS-CoV-2. The experimental results showed that acriflavine inhibits the interaction between viral receptor-binding domain (RBD) of spike protein and angiotensin converting enzyme-2 (ACE2) host receptor driving viral cell entry. The prepared ACF@MOF composites exhibited low (MOF-808 and UiO-66) and high (UiO-67 and NU-1000) ACF loadings. The drug release profiles from prepared composites showed different release kinetics depending on the local pore environment. The long-term ACF release with the effective antiviral ACF concentration was observed for all studied ACF@MOF composites. The density functional theory (DFT) calculations allowed us to determine that π–π stacking together with electrostatic interaction plays an important role in acriflavine adsorption and release from ACF@MOF composites. The molecular docking results have shown that acriflavine interacts with several possible binding sites within the RBD and binding site at the RBD/ACE2 interface. The cytotoxicity and ecotoxicity results have confirmed that the prepared ACF@MOF composites may be considered potentially safe for living organisms. The complementary experimental and theoretical results presented in this study have confirmed that the ACF@MOF composites may be considered a potential candidate for the COVID-19 treatment, which makes them good candidates for clinical trials

Comparative actualistic study hints at origins of alleged Miocene “coprolites” of Poland (supplementary movie : Tomographic animation of Miocene coprolite from Turów.avi)

Excrement-shaped siderite masseshave been the subject of much controversy. They have been variously interpreted either as being coprolites, cololithes or pseudofossils created by mechanical deformation of plastic sediment. Here we reportexcrement-shaped ferruginous masses recovered from the Miocene of Turów mine in south-western Poland. Results of mineralogical, geochemical, petrographic and microtomographical analyses indicate that these masses consist of siderite and iron oxide rather than phosphate, and rarely contain recognizable food residues, which may suggest abiotic origins of these structures. On the other hand, evidence in support of a fecal origin include: (i) the presence of two distinct morphotypes differing in size and shape, (ii) the limited quantity of specimens, (iii) the presence of rare hair-like structures or coalified inclusions and (iv) the presence of rare fine striations on the surface. Importantly, comparative actualistic study of Recent vertebrate feces shows overall resemblance of the first morphotype (sausage-shaped with rare coalified debris) to excrements of testudinoid turtles (Testudinoidea), whose shell fragment was found in the investigated locality. The second morphotype (rounded to oval-shaped with hair-like structures), in turn, is similar to the feces of some snakes (Serpentes), the remains of which were noted in the Miocene of the neighborhood areas.This research Project is partially supported by the National Science Centre, Poland (www.ncn.gov.pl), Grant No. 2019/32/C/NZ4/00150