Generally applicable physics-based equation of state for liquids

Physics-based first-principles pressure-volume-temperature equations of state (EOS) exist for solids and gases but not for liquids due to the long-standing fundamental problems involved in liquid theory. Current EOS models that are applicable to liquids and supercritical fluids at liquid-like density under conditions relevant to planetary interiors and industrial processes are complex empirical models with many physically meaningless adjustable parameters. Here, we develop a generally applicable physics-based (GAP) EOS for liquids including supercritical fluids at liquid-like density. The GAP equation has only one dimensionless parameter: the Gr\"uneisen parameter for the fluid. The GAP equation is explicit in the internal energy, and hence links the most fundamental macroscopic static property of fluids, the pressure-volume-temperature EOS, to their key microscopic property: the molecular hopping frequency or liquid relaxation time, from which the internal energy can be obtained. We test our GAP equation against available experimental data in several different ways and find good agreement. We observe that the GAP equation is similar to the Mie-Gr\"{u}neisen solid EOS in a wide range of the liquid phase diagram. This similarity is ultimately related to the condensed state of these two phases. On the other hand, the differences between the GAP equation and EOS for gases are fundamental. Finally, we identify the key gaps in the experimental data that need to be filled in to proceed further with the liquid EOS

A preliminary study of air-pollution measurement by active remote-sensing techniques

Air pollutants are identified, and the needs for their measurement from satellites and aircraft are discussed. An assessment is made of the properties of these pollutants and of the normal atmosphere, including interactions with light of various wavelengths and the resulting effects on transmission and scattering of optical signals. The possible methods for active remote measurement are described; the relative performance capabilities of double-ended and single-ended systems are compared qualitatively; and the capabilities of the several single-ended or backscattering techniques are compared quantitatively. The differential-absorption lidar (DIAL) technique is shown to be superior to the other backscattering techniques. The lidar system parameters and their relationships to the environmental factors and the properties of pollutants are examined in detail. A computer program that models both the atmosphere (including pollutants) and the lidar system is described. The performance capabilities of present and future lidar components are assessed, and projections are made of prospective measurement capabilities for future lidar systems. Following a discussion of some important operational factors that affect both the design and measurement capabilities of airborne and satellite-based lidar systems, the extensive analytical results obtained through more than 1000 individual cases analyzed with the aid of the computer program are summarized and discussed. The conclusions are presented. Recommendations are also made for additional studies to investigate cases that could not be explored adequately during this study

Mean flow instabilities of two-dimensional convection in strong magnetic fields

The interaction of magnetic fields with convection is of great importance in astrophysics. Two well-known aspects of the interaction are the tendency of convection cells to become narrow in the perpendicular direction when the imposed field is strong, and the occurrence of streaming instabilities involving horizontal shears. Previous studies have found that the latter instability mechanism operates only when the cells are narrow, and so we investigate the occurrence of the streaming instability for large imposed fields, when the cells are naturally narrow near onset. The basic cellular solution can be treated in the asymptotic limit as a nonlinear eigenvalue problem. In the limit of large imposed field, the instability occurs for asymptotically small Prandtl number. The determination of the stability boundary turns out to be surprisingly complicated. At leading order, the linear stability problem is the linearisation of the same nonlinear eigenvalue problem, and as a result, it is necessary to go to higher order to obtain a stability criterion. We establish that the flow can only be unstable to a horizontal mean flow if the Prandtl number is smaller than order , where B0 is the imposed magnetic field, and that the mean flow is concentrated in a horizontal jet of width in the middle of the layer. The result applies to stress-free or no-slip boundary conditions at the top and bottom of the layer

Student Racial Atitudes and Perceptions of Causal Events at Entry to Graduate Social Work Education

This study assessed the racial attitudes and perceptions of causal events of 174 graduate students at the time of their entry to social work training. Results indicate that social work students had more egalitarian attitudes than nonsocial work students and were more likely to attribute causality to environmental or external factors. black students were significantly more external than white students in tneir perceptions of causality. Some differences in racial attitudes and perceptions of causal events were found among social work students, depending upon area of practice specialization. Student attitudes and perceptions did not differ according to geographical regions. implications for social work education and for future research are discussed

Comparison of Lidar Methods for Remote Measurement of Air Pollutants

This paper presents quantitative comparisons of several single-ended lidar techniques for the remote measurement of gaseous pollutants. These techniques are divided into two groups. The first group is based on the measurement of energy scattered directly by the gas of interest. The gaseous scattering processes considered are ordinary fluorescence, resonance fluorescence (also called resonance scattering), Raman scattering, and resonant (or nearly resonant) Raman scattering. The second group is based on the measurement of a characteristic differential absorption produced by the gas of interest at two discrete wavelengths, using energy scattered back toward the receiver by a remote reflector other than the gas of interest. The remote reflector may be intermixed with the gas of interest, as is the case with aerosols and atmospheric gases (principally nitrogen), or they may be fixed reflectors such as terrestrial objects or retroflectors. The detectability of a given material will depend on the magnitude and characteristics of the optical interaction with that material. The main characteristics of interest are the cross section, the response time, and the spectral response of the material relative to both the transmit and receive functions of the lidar. These characteristics and their implications for remote sensing will be reviewed for the four direct scatter processes and for the differential absorption technique. The characteristic behavior of the direct backscatter technique is different from the differential absorption technique with respect to sensitivity, concentration of material, and the effect of range. For these reasons, the direct backscatter processes cannot be compared directly to the differential absorption technique. The two techniques can be compared for specific material and system configurations, however. This paper describes specific lidar system configurations and gives the calculated performance level for these systems in both the direct backscatter and differential absorption modes for a wide variety of pollutant monitoring situations. The results of this comparison of techniques indicate that the differential- absorption lidar technique can provide adequate range and sensitivity for a wide variety of pollution monitoring applications involving a number of interesting pollutant materials. No other single technique appears to provide these capabilities for such a wide range of materials

Magnetic diffusivity tensor and dynamo effects in rotating and shearing turbulence

The turbulent magnetic diffusivity tensor is determined in the presence of rotation or shear. The question is addressed whether dynamo action from the shear-current effect can explain large-scale magnetic field generation found in simulations with shear. For this purpose a set of evolution equations for the response to imposed test fields is solved with turbulent and mean motions calculated from the momentum and continuity equations. The corresponding results for the electromotive force are used to calculate turbulent transport coefficients. The diagonal components of the turbulent magnetic diffusivity tensor are found to be very close together, but their values increase slightly with increasing shear and decrease with increasing rotation rate. In the presence of shear, the sign of the two off-diagonal components of the turbulent magnetic diffusion tensor is the same and opposite to the sign of the shear. This implies that dynamo action from the shear--current effect is impossible, except perhaps for high magnetic Reynolds numbers. However, even though there is no alpha effect on the average, the components of the alpha tensor display Gaussian fluctuations around zero. These fluctuations are strong enough to drive an incoherent alpha--shear dynamo. The incoherent shear--current effect, on the other hand, is found to be subdominant.Comment: 12 pages, 13 figures, improved version, accepted by Ap

Chandra observations of the bursting X-ray transient SAX J1747.0-2853 during low-level accretion activity

We present Chandra/ACIS observations of the bursting X-ray transient SAX J1747.0-2853 performed on 18 July 2001. We detected a bright source at the position of R.A = 17^h 47^m 02.60^s and Dec. = -28 52' 58.9'' (J2000.0; with a 1 sigma error of ~0.7 arcseconds), consistent with the BeppoSAX and ASCA positions of SAX J1747.0-2853 and with the Ariel V position of the transient GX +0.2,-0.2, which was active during the 1970's. The 0.5-10 keV luminosity of the source during our observations was ~3 x 10^{35} erg/s (assuming a distance of 9 kpc) demonstrating that the source was in a low-level accretion state. We also report on the long-term light curve of the source as observed with the all sky monitor aboard the Rossi X-ray Timing Explorer. After the initial 1998 outburst, two more outbursts (in 2000 and 2001) were detected with peak luminosities about two orders of magnitude larger than our Chandra luminosity. Our Chandra observation falls in-between those two outbursts, making the outburst history for SAX J1747.0-2853 complex. Those bright 2000 and 2001 outbursts combined with the likely extended period of low level activity in-between those outbursts strongly suggest that the classification of SAX J1747.0-2853 as a faint X-ray transient was premature. It might be possible that the other faint X-ray transients also can exhibit bright, extended outbursts which would eliminate the need for a separate sub-class of X-ray transients. We discuss our results also in the context of the behavior of X-ray binaries accreting at low levels with luminosities around 10^{35} erg/s, a poorly studied accretion rate regime.Comment: Accepte for publication in ApJ, 11 July 200

Dynamics of charged fluids and 1/L perturbation expansions

Some features of the calculation of fluid dynamo systems in magnetohydrodynamics are studied. In the coupled set of the ordinary linear differential equations for the spherically symmetric $\alpha^2-$dynamos, the problem represented by the presence of the mixed (Robin) boundary conditions is addressed and a new treatment for it is proposed. The perturbation formalism of large$-\ell$ expansions is shown applicable and its main technical steps are outlined.Comment: 16 p

Medical student intentions to move abroad: A UK-based realist evaluation

This is the final version. Available from on open access from Ubiquity Press via the DOI in this record. Data accessibility statement: The data that support the findings of this study are available from the corresponding author upon request.INTRODUCTION: Medical students moving abroad after qualification may contribute to domestic healthcare workforce shortages. Greater insights into how medical students make decisions about moving abroad may improve post-qualification retention. The aim was to develop a programme theory explaining medical students' intentions to move abroad or not. METHODS: In Phase 1 the initial programme theory was generated from a literature review. In Phase 2, the theory was developed through 30 realist interviews with medical students from a medical school in the United Kingdom. In Phase 3 the final programme theory was used to produce recommendations for stakeholders. RESULTS: The findings highlight the complex decision-making that medical students undertake when deciding whether to move abroad. We identified five contexts and six mechanisms leading to two outcomes (intention to move abroad and no intention to move abroad). CONCLUSIONS: This realist evaluation has demonstrated how contexts and mechanisms may interact to enable specific outcomes. These insights have allowed evidence-based recommendations to be made with a view to retaining graduates, including protected time within medical curricula to experience other healthcare systems, improved availability of domestic postgraduate posts providing domestic career certainty and stronger domestic-based social support networks for graduates.Association for the Study of Medical Education (ASME)General Medical Council (GMC

Wide band observations of the new X-ray burster SAX J1747.0-2853 during the March 1998 outburst

We report on our discovery and follow-up observations of the X-ray source SAX J1747.0-2853 detected in outburst on 1998, March 10 with the BeppoSAX Wide Field Cameras in the energy range 2-28 keV. The source is located about half degree off the Galactic Nucleus. A total of 14 type-I X-ray bursts were detected in Spring 1998, thus identifying the object as a likely low-mass X-ray binary harboring a weakly magnetized neutron star. Evidence for photospheric radius expansion is present in at least one of the observed bursts, leading to an estimate of the source distance of about 9 kpc. We performed a follow-up target of opportunity observation with the BeppoSAX Narrow Field Instruments on March 23 for a total elapsed time of 72 ks. The source persistent luminosity was 2.6x10^36 erg/s in the 2-10 keV energy range. The wide band spectral data (1-200 keV) are consistent with a remarkable hard X-ray spectrum detected up to 150 keV, highly absorbed at low energies (Nh of the order of 10^23 cm^-2) and with clear evidence for an absorption edge near 7 keV. A soft thermal component is also observed, which can be described by single temperature blackbody emission at about 0.6 keV.Comment: 11 pages, 3 figures, accepted for publication in ApJ Letter