29 research outputs found
Identification of active sites on supported metal catalysts with carbon nanotube hydrogen highways
Catalysts consisting of metal particles supported on reducible oxides exhibit promising
activity and selectivity for a variety of current and emerging industrial processes. Enhanced
catalytic activity can arise from direct contact between the support and the metal or from
metal-induced promoter effects on the oxide. Discovering the source of enhanced catalytic
activity and selectivity is challenging, with conflicting arguments often presented based on
indirect evidence. Here, we separate the metal from the support by a controlled distance
while maintaining the ability to promote defects via the use of carbon nanotube hydrogen
highways. As illustrative cases, we use this approach to show that the selective transformation
of furfural to methylfuran over Pd/TiO2 occurs at the Pd-TiO2 interface while anisole
conversion to phenol and cresol over Cu/TiO2 is facilitated by exposed Ti3+ cations on the
support. This approach can be used to clarify many conflicting arguments in the literatureWe acknowledge financial support from the National Science Foundation, Grant CAREER1653935. Use of the Advanced Photon Source is supported by the U.S. Department of Energy, Office of Science, and Office of Basic Energy Sciences, under Contract DE-AC02-06CH11357. MRCAT operations are supported by the Department of Energy and the MRCAT member institutions. E.C.W. and J.T.M. were supported in part by Center for Innovative Transformation of Alkane Resources (CISTAR) by the National Science Foundation under Cooperative Agreement No. EEC-1647722.
Open access fees fees for this article provided whole or in part by OU Libraries Open Access Fund.Ye
Ab Initio Screening Approach for the Discovery of Lignin Polymer Breaking Pathways
The directed depolymerization of lignin biopolymers is of utmost relevance for the valorization or commercialization of biomass fuels. We present a computational and theoretical screening approach to identify potential cleavage pathways and resulting fragments that are formed during depolymerization of lignin oligomers containing two to six monomers. We have developed a chemical discovery technique to identify the chemically relevant putative fragments in eight known polymeric linkage types of lignin. Obtaining these structures is a crucial precursor to the development of any further kinetic modeling. We have developed this approach by adapting steered molecular dynamics calculations under constant force and varying the points of applied force in the molecule to diversify the screening approach. Key observations include relationships between abundance and breaking frequency, the relative diversity of potential pathways for a given linkage, and the observation that readily cleaved bonds can destabilize adjacent bonds, causing subsequent automatic cleavage.Massachusetts Institute of Technology (Research Support Corporation, Reed Grant)United States. Dept. of Energy. Computational Science Graduate Fellowship Program (DOE-CSGF)Burroughs Wellcome Fund (Career Award at the Scientific Interface
Assessment of the strength of the lower limb muscles in subjects with stroke with portable dynamometry: a literature review
Development of Bifunctional Hydrodeoxygenation Catalyst Rh‐HY for the Generation of Biomass‐Derived High‐Energy‐Density Fuels
Effect of fines content on onset of internal instability and suffusion of sand mixtures
Internal instability or suffusion is one of the mechanisms of internal erosion in cohesionless soils, which is described by the loss of integrity of soil by seepage flow and is associated with the migration of finer particles. The contribution of the non-plastic finer fraction in a material is a key factor governing internal instability susceptibility. This study presents the experimental investigation of the influence of the fines content on the onset of internal instability of gap-graded sands using a pressure-controlled triaxial erosion device. The results indicate that the finer fraction in the soil has a significant influence on the hydraulic gradient at the onset of erosion. The underfilled soil with fines content less than 30% is vulnerable to suffusion at a relatively small hydraulic gradient. The transitional soil, whose fines content is between 30 and 35%, also exhibits suffusion, but the erosion onset hydraulic gradient significantly increases with increasing fines content. The overfilled soil with fines content larger than 35% exhibits suffosion or internal stability at a larger hydraulic gradient. The results also highlight the necessity of the multiple indices, such as mass loss, volumetric change and change in permeability, in evaluating the onset of various instability phenomena