Azimuthons in weakly nonlinear waveguides of different symmetries

We show that weakly guiding nonlinear waveguides support stable propagation of rotating spatial solitons (azimuthons). We investigate the role of waveguide symmetry on the soliton rotation. We find that azimuthons in circular waveguides always rotate rigidly during propagation and the analytically predicted rotation frequency is in excellent agreement with numerical simulations. On the other hand, azimuthons in square waveguides may experience spatial deformation during propagation. Moreover, we show that there is a critical value for the modulation depth of azimuthons above which solitons just wobble back and forth, and below which they rotate continuously. We explain these dynamics using the concept of energy difference between different orientations of the azimuthon.Comment: 12 pages, 8 figure

A Unified Picture of S* in Carotenoids

In π-conjugated chain molecules such as carotenoids, coupling between electronic and vibrational degrees of freedom is of central importance. It governs both dynamic and static properties, such as the time scales of excited state relaxation as well as absorption spectra. In this work, we treat vibronic dynamics in carotenoids on four electronic states (|S₀⟩, |S₁⟩, |S₂⟩, and |S_n⟩) in a physically rigorous framework. This model explains all features previously associated with the intensely debated S* state. Besides successfully fitting transient absorption data of a zeaxanthin homologue, this model also accounts for previous results from global target analysis and chain length-dependent studies. Additionally, we are able to incorporate findings from pump-deplete-probe experiments, which were incompatible to any pre-existing model. Thus, we present the first comprehensive and unified interpretation of S*-related features, explaining them by vibronic transitions on either S₁, S₀, or both, depending on the chain length of the investigated carotenoid

A Unified Picture of S* in Carotenoids

D.A. and V.B. acknowledge the support from the Research Council of Lithuania(MIP-090/2015 and MIP-090/2016). T.P. thanks the Czech Science Foundation (Grant No. 16-10417S) for financial support. A. G. P. and J. H. acknowledge funding by the Austrian Science Fund (FWF): START project Y631−N27