Kinetic conversion of CO to CH4 in the Solar System

Some of the most interesting chemistry in the Solar System involves changes in the oxidation state of the simple carbon species. The chemical pathways for the conversion of CH4 to CO and CO2 are for the most part known. The reverse process, the reduction of CO to CH4, is, however, poorly understood. This is surprising in view of the importance of the reduction process in the chemistry of the Solar System. Recently we investigated the chemical kinetics of a hitherto unsuspected reaction. It is argued that the formation of the methoxy radical (CH3O) from H+H2CO may play an essential role in the reduction of CO to CH4. The rate coefficient for this reaction has been estimated using the approximate theory of J. Troe and transition state theory. We will discuss the implications of this reaction for the chemistry of CO on Jupiter, in the solar nebula, for interpreting the laboratory experiments of A. Bar-Nun and A. Shaviv and A. Bar-Nun and S. Chang, and for organic synthesis in the prebiotic terrestrial atmosphere. The possible relation of CO reduction in the solar nebula and polyoxymethylene observed in comet Halley will be discussed

Non-Linear Affine Embedding of the Dirac Field from the Multiplicity-Free SL(4,R) Unirreps

The correspondence between the linear multiplicity-free unirreps of SL(4, R) studied by Ne'eman and {\~{S}}ija{\~{c}}ki and the non-linear realizations of the affine group is worked out. The results obtained clarify the inclusion of spinorial fields in a non-linear affine gauge theory of gravitation.Comment: 13 pages, plain TeX, macros include

Understanding chemical evolution in resolved galaxies -- I The local star fraction-metallicity relation

This work studies the relation between gas-phase oxygen abundance and stellar-to-gas fraction in nearby galaxies. We first derive the theoretical prediction, and argue that this relation is fundamental, in the sense that it must be verified regardless of the details of the gas accretion and star formation histories. Moreover, it should hold on "local" scales, i.e. in regions of the order of 1 kpc. These predictions are then compared with a set of spectroscopic observations, including both integrated and resolved data. Although the results depend somewhat on the adopted metallicity calibration, observed galaxies are consistent with the predicted relation, imposing tight constraints on the mass-loading factor of (enriched) galactic winds. The proposed parametrization of the star fraction-metallicity relation is able to describe the observed dependence of the oxygen abundance on gas mass at fixed stellar mass. However, the "local" mass-metallicity relation also depends on the relation between stellar and gas surface densities.Comment: 10 pages, 4 figures. Matches accepted version (significant typo corrected

Effective Potential and Thermodynamics for a Coupled Two-Field Bose Gas Model

We study the thermodynamics of a two-species homogeneous and dilute Bose gas that is self-interacting and quadratically coupled to each other. We make use of field theoretical functional integral techniques and evaluate the one-loop finite temperature effective potential for this system considering the resummation of the leading order temperature dependent as well as infrared contributions. The symmetry breaking pattern associated to the model is then studied by considering different values of self and inter-species couplings. We pay special attention to the eventual appearance of reentrant phases and/or shifts in the observed critical temperatures as compared to the monoatomic (one-field Bose) case.Comment: 21 pages, 4 eps figure

The Dog on the Ship: The "Canis Major Dwarf Galaxy" as an Outlying Part of the Argo Star System

Overdensities in the distribution of low latitude, 2MASS giant stars are revealed by systematically peeling away from sky maps the bulk of the giant stars conforming to ``isotropic'' density laws generally accounting for known Milky Way components. This procedure, combined with a higher resolution treatment of the sky density of both giants and dust allows us to probe to lower Galactic latitudes than previous 2MASS giant star studies. While the results show the swath of excess giants previously associated with the Monoceros ring system in the second and third Galactic quadrants at distances of 6-20 kpc, we also find a several times larger overdensity of giants in the same distance range concentrated in the direction of the ancient constellation Argo. Isodensity contours of the large structure suggest that it is highly elongated and inclined by about 3 deg to the disk, although details of the structure -- including the actual location of highest density, overall extent, true shape -- and its origin, remain unknown because only a fraction of it lies outside highly dust-obscured, low latitude regions. Nevertheless, our results suggest that the 2MASS M giant overdensity previously claimed to represent the core of a dwarf galaxy in Canis Major (l ~ 240 deg) is an artifact of a dust extinction window opening to the overall density rise to the more significant Argo structure centered at larger longitude (l ~ 290 +- 10 deg, b ~ -4 +- 2 deg).Comment: 4 pages, 4 figure

Ground-state van der Waals forces in planar multilayer magnetodielectrics

Within the frame of lowest-order perturbation theory, the van der Waals potential of a ground-state atom placed within an arbitrary dispersing and absorbing magnetodielectric multilayer system is given. Examples of an atom situated in front of a magnetodielectric plate or between two such plates are studied in detail. Special emphasis is placed on the competing attractive and repulsive force components associated with the electric and magnetic matter properties, respectively, and conditions for the formation of repulsive potential walls are given. Both numerical and analytical results are presented.Comment: 16 pages, 8 figures, minor correction

Systematizing Planning and Formative Phases of HIV Prevention Research: Case Studies from Brazil, Mongolia, and Kazakhstan

Objectives International Community-Based Participatory Research (CBPR) is vulnerable to contextual, political, and interpersonal issues that may hamper researchers’ abilities to develop and sustain partnerships with local communities. This paper responds to a call for systematizing CBPR practices and to the urgent need for frameworks with potential to facilitate partnership building between researchers and communities in both “developed” and “developing” countries. Methods Using three brief case examples, each from a different context, with different partners and varied research questions, we demonstrate how to apply the International Participatory Research Framework (IPRF). Results IPRF consists of triangulated procedures (steps and actions) that can facilitate known participatory outcomes: (1) community-defined research goals, (2) capacity for further research, and (3) policies and programs grounded in research. Conclusions We show how the application of this model is particularly helpful in the planning and formative phases of CBPR. Other partnerships can use this framework in its entirety or aspects thereof, in different contexts. Further evaluation of how this framework can help other international partnerships, studying myriad diseases and conditions, should be a focus of future international CBPR

Intercomparison of field measurements of nitrous acid (HONO) during the SHARP campaign

Because of the importance of HONO as a radical reservoir, consistent and accurate measurements of its concentration are needed. As part of SHARP (Study of Houston Atmospheric Radical Precursors), time series of HONO were obtained by six different measurement techniques on the roof of the Moody Tower at the University of Houston. Techniques used were long path differential optical absorption spectroscopy (DOAS), stripping coil-visible absorption photometry (SC-AP), long path absorption photometry (LOPAP® ), mist chamber/ion chromatography (MC-IC), quantum cascade-tunable infrared laser differential absorption spectroscopy (QC-TILDAS), and ion drift-chemical ionization mass spectrometry (ID-CIMS). Various combinations of techniques were in operation from 15 April through 31 May 2009. All instruments recorded a similar diurnal pattern of HONO concentrations with higher median and mean values during the night than during the day. Highest values were observed in the final 2 weeks of the campaign. Inlets for the MC-IC, SC-AP, and QC-TILDAS were collocated and agreed most closely with each other based on several measures. Largest differences between pairs of measurements were evident during the day for concentrations ~100 parts per trillion (ppt). Above ~ 200 ppt, concentrations from the SC-AP, MC-IC, and QC-TILDAS converged to within about 20%, with slightly larger discrepancies when DOAS was considered. During the first 2 weeks, HONO measured by ID-CIMS agreed with these techniques, but ID-CIMS reported higher values during the afternoon and evening of the final 4 weeks, possibly from interference from unknown sources. A number of factors, including building related sources, likely affected measured concentrations