Inhibited aluminization of an ODS FeCr alloy

Aluminide coatings are of interest for fusion energy applications both for compatibility with liquid Pb-Li and to form an alumina layer that acts as a tritium permeation barrier. Oxide dispersion strengthened (ODS) ferritic steels are a structural material candidate for commercial reactor concepts expected to operate above 600 °C. Aluminizing was conducted in a laboratory scale chemical vapor deposition reactor using accepted conditions for coating Fe- and Ni base alloys. However, the measured mass gains on the current batch of ODS Fe-14Cr were extremely low compared to other conventional and ODS alloys. After aluminizing at two different Al activities at 900 °C and at 1100 °C, characterization showed that the ODS Fe-14Cr specimens formed a dense, primarily AlN layer that prevented Al uptake. This alloy batch contained a higher (> 5000 ppma) N content than the other alloys coated and this is the most likely reason for the inhibited aluminization. Other factors such as the high O content, small (~ 140 nm) grain size and Y-Ti oxide nano-clusters in ODS Fe-14Cr also could have contributed to the observed behavior. Examples of typical aluminide coatings formed on conventional and ODS Fe- and Ni-base alloys are shown for comparison

The Effect of Water Vapor on Cr Depletion in Advanced Recuperator Alloys

ABSTRACT Durable alloy foils are needed for gas turbine recuperators operating at 650°-700°C. It has been established that water vapor in the exhaust gas causes more rapid consumption of Cr in austenitic stainless steels leading to a reduction in operating lifetime of these thin-walled components. Laboratory testing at 650°-800°C of commercial and model alloys is being used to develop a better understanding of the long-term rate of Cr consumption in these environments. Results are presented for commercial alloys 709, 120 and 625. After 10,000h exposures at 650° and 700°C in humid air, grain boundary Cr depletion was observed near the surface of all these materials. In the Fe-base alloys, 709 and 120, this depletion led to localized Fe-rich nodule formation. This information then can be used to develop low-cost alternatives to currently available candidate materials. INTRODUCTION Improving gas turbine engine efficiency has always been an attractive goal for reducing operating costs and net emissions. However, increasing engine temperatures to increase efficiency often requires more expensive materials to meet durability goals. With rising fuel costs, it is easier to justify the use of such high temperature alloys in a cost benefit analysis. One example of this type of materials upgrade is for applications in recuperators or heat exchangers used to improve the efficiency of microturbines and small gas turbines In order to determine if these candidate alloys have sufficient corrosion resistance to meet the recuperator durability goal of 40,000h set by the U.S. Department of Energ y 's Distributed Energ y P r o g r am EXPERIMENTAL PROCEDURE The materials tested in this study were a combination of commercial alloys and laboratory-melted model alloys. Some of the materials were obtained from commercial vendors in foil form, while others were obtained in thicker sections and then hot and cold rolled at Oak Ridge National Laboratory (ORNL) to ≈100µm thickness with average grain sizes given in Specimens (≈1 x 12 x 18mm) cut from sheet material were polished to a 600 grit surface finish. Similar-sized foil (≈100µm) specimens were tested in the as-rolled condition. All specimens were

Nonmarine Ostracoda as proxies in (geo-)archaeology: a review

Abstract Ostracods as bioindicators are extremely useful for reconstructing palaeoenvironment and palaeoclimate and can also indicate the provenance of sediments and materials, for example, in studies on ancient commercial networks. Ostracods are small crustaceans that live in almost all aquatic habitats, both natural and man-made. Due to their calcitic carapace, they have high fossilization potential, and their use in geoarchaeology has been steadily increasing during the last decades. Their small size needs mean that only small volumes of sediment samples are needed, and species-specific ecological tolerances and preferences allow detailed palaeoenvironmental reconstructions. Typical methods of their application are palaeoecological analyses of associations based on ecological information and taphonomy, morphometric variability and stable isotope and chemistry analyses of their shells. The present paper aims to present an overview of applications of non-marine ostracods in (geo-)archaeological research, recommending sampling and analytical techniques for addressing archaeological research questions on palaeoclimate, habitat and landscape changes, water availability and quality, land use and other anthropogenic impacts, the provenance of materials and commercial networks to promote the application of Ostracoda in geoarchaeology/environmental archaeology.1 Introduction 2 Applications 2.1 short history of ostracod‐based palaeoenvironmental reconstructions 2.2 Palaeoclimate and palaeoenvironmental studies on continental archaeological sites 2.2.1 General palaeoenvironment/landscape reconstructions 2.2.2 Salinity 2.2.3 Temperature 2.2.4 Radiocarbon dating 2.3 Landscape changes by human activity 2.4 Water use and water works 2.5 Provenance studies 3 Methods for sampling and lab analyses 4 Conclusion

Effect of specimen geometry and aps flash bond coating on TBC lifetime

Thermal barrier coatings (TBCs) for land-based gas turbines are primarily thermally sprayed and are unlikely to contain precious metals. For regions of the world where natural gas prices are high, turbine efficiency is a critical issue, however, durability and reliability also are very important for large scale generation. Seeking pathways for improved performance and lifetime model development, a variety of TBC performance parameters have been investigated over the years using furnace cycle testing, including bond coating composition, substrate composition, cycle frequency and environment (i.e. additions of H2O, CO2, etc.). The baseline system has been superalloy 247 substrates with high velocity oxygen fuel (HVOF) NiCoCrAlYHfSi bond coatings and air plasma sprayed yttria-stabilized zirconia (YSZ) top coatings tested in “wet” air (10%H2O) at 900°-1150°C. Recently, specimen geometry was changed from flat disks to rods. Using similar coating parameters, FCT lifetime in 100-h cycles at 1100°C in air with 10%H2O dropped by ~5X for rods compared to disks. Coating architectures that were developed for flat disk specimens did not appear to be effective in improving lifetime in FCT for rod specimens. The addition of an APS “flash” coating resulted in a significant increase in FCT lifetime in rod specimens. The benefit of this additional bond coating layer has generally thought to be due to increased interface roughness compared to a conventional HVOF coating. The most recent testing has returned to 1-h FCT of disk specimens using ~50µm APS flash coatings of both NiCoCrAlYHfSi and NiCoCrAlY flash coatings deposited on HVOF NiCoCrAlYHfSi. A similar set of rod specimens also is being evaluated in 100-h cycles. Both tests are being conducted at 1100°C in air with 10%H2O. Both flash coatings show a statistically significant increase in FCT TBC lifetime in 1-h cycles. Surprisingly, the Y only flash coating has significantly outperformed the YHfSi flash coating with some work still in progress. Residual stress in the thermally grown alumina scale has been tracked every 100 1-h cycles and 5, 100-h cycles for one sample of each coating type to quantify the evolution of the reaction product and better understand the FCT results. Failed specimens are being characterized to better understand the benefit of flash coatings on TBC lifetime. Research was sponsored by the U. S. Department of Energy, Office of Fossil Energy, Turbine Program

Study of the reactive element effect in ODS iron-base alumina-formers

Iron aluminide (Fe{sub 3}Al) and FeCrAl compositions were dispersed with 15 different oxides in order to study the effect of oxygen- active dopants on high-temperature growth and adhesion of {alpha}- Al{sub 2}O{sub 3} scales. In these model-type, oxide dispersion strengthened (ODS) systems, the chemical effects of various cation dopants were compared to the baseline effect of an Al{sub 2}O{sub 3} oxide dispersion. By conducting isothermal and cyclic oxidation tests and by characterizing the oxidation product, effects on scale adhesion, growth rate and microstructure were evaluated. The dopants were categorized based on effectiveness in modifying the alumina scale. An Al{sub 2}O{sub 3} dispersion yielded some improvement in oxidation behavior apparently by strengthening the relatively weak substrate. However, the type of improvements in adhesion and change in growth mechanism associated with addition of reactive elements such as Y were not achieved. In general, due to the weaker substrate and the inherently faster interfacial void formation, the dispersions were less effective in ODS Fe{sub 3}Al than in ODS FeCrAl

High Temperature and Pressure Steam-H2 Interaction with Candidate Advanced LWR Fuel Claddings

This report summarizes the work completed to evaluate cladding materials that could serve as improvements to Zircaloy in terms of accident tolerance. This testing involved oxidation resistance to steam or H{sub 2}-50% steam environments at 800-1350 C at 1-20 bar for short times. A selection of conventional alloys, SiC-based ceramics and model alloys were used to explore a wide range of materials options and provide guidance for future materials development work. Typically, the SiC-based ceramic materials, alumina-forming alloys and Fe-Cr alloys with {ge}25% Cr showed the best potential for oxidation resistance at {ge}1200 C. At 1350 C, FeCrAl alloys and SiC remained oxidation resistant in steam. Conventional austenitic steels do not have sufficient oxidation resistance with only {approx}18Cr-10Ni. Higher alloyed type 310 stainless steel is protective but Ni is not a desirable alloy addition for this application and high Cr contents raise concern about {alpha}{prime} formation. Higher pressures (up to 20.7 bar) and H{sub 2} additions appeared to have a limited effect on the oxidation behavior of the most oxidation resistant alloys but higher pressures accelerated the maximum metal loss for less oxidation resistant steels and less metal loss was observed in a H{sub 2}-50%H{sub 2}O environment at 10.3 bar. As some of the results regarding low-alloyed FeCrAl and Fe-Cr alloys were unexpected, further work is needed to fundamentally understand the minimum Cr and Al alloy contents needed for protective behavior in these environments in order to assist in alloy selection and guide alloy development

Evaluation of Durable Metallic Supports for Catalytic Combustors

In 2000, a Cooperative Research and Development Agreement (CRADA) was undertaken between the Oak Ridge National Laboratory (ORNL) and Catalytica Energy Systems Incorporated (CESI) to determine the properties of current metallic catalyst supports and examine new candidate alloys for this application. A team was established at ORNL to examine oxidation-limited lifetime of these thin-walled metallic components using standard lifetime models and to measure the mechanical properties of the foils (40-200:m in thickness) which can differ substantially from bulk properties. Oxidation experiments were conducted on foil specimens at 700-1100 C in laboratory air and in air with 10 vol.% water vapor to better simulate the combustor environment. At the higher test temperatures, time to oxidation-induced (i.e. breakaway oxidation) failure was determined in 1h cycles in order to verify predictions from a standard reservoir-type oxidation lifetime model. Selected specimens were run for >10,000h in 100 or 500h cycles at lower test temperatures in order to determine the oxidation kinetics for the model. The creep properties of selected foils were measured for 4,000-8,000h at operation-relevant stresses and temperatures. None of the new candidate alloys significantly out-performed currently used alloys in laboratory testing, particularly in oxidation lifetime testing. Therefore, engine testing was not performed on any of the new candidate alloys. Both the oxidation- and creep-resistance of FeCrAl alloys was greater than expected and the results of the CRADA allowed CESI to extend life or increase operating temperatures for these lower cost substrate alloys in the next generation of catalyst modules. Three work areas were defined for the CRADA. The first area was investigating the oxidation behavior of current and candidate alloy foils. The goal was to obtain data such as the oxidation rate as a function of temperature and environment, the time to breakaway oxidation at high test temperatures and the residual Al alloy content at breakaway oxidation. These inputs are needed for a standard reservoir-type oxidation model. The second work area was to use the experimental data to model the oxidation-limited lifetime of foil materials as a function of temperature, foil thickness and composition. The third task was to measure mechanical properties, in particular creep rates and creep to failure life, of similar foils at application relevant temperatures and stress levels

Collective Antenna Effects in the Terahertz and Infrared Response of Highly Aligned Carbon Nanotube Arrays

We study macroscopically-aligned single-wall carbon nanotube arrays with uniform lengths via polarization-dependent terahertz and infrared transmission spectroscopy. Polarization anisotropy is extreme at frequencies less than $\sim$3 THz with no sign of attenuation when the polarization is perpendicular to the alignment direction. The attenuation for both parallel and perpendicular polarizations increases with increasing frequency, exhibiting a pronounced and broad peak around 10 THz in the parallel case. We model the electromagnetic response of the sample by taking into account both radiative scattering and absorption losses. We show that our sample acts as an effective antenna due to the high degree of alignment, exhibiting much larger radiative scattering than absorption in the mid/far-infrared range. Our calculated attenuation spectrum clearly shows a non-Drude peak at $\sim$10 THz in agreement with the experiment.Comment: 5 pages, 5 figure