Transformer Oil Passivation and Impact of Corrosive Sulphur

In recent years a significant volume of research has been undertaken in order to understand the recent failures in oil insulated power apparatus due to deposition of copper sulphide on the conductors and in the insulation paper. Dibenzyl Disulfide (DBDS) has been found to be the leading corrosive sulphur compound in the insulation oil [1]. The process of copper sulphide formation and the deposition in the paper is still being investigated, but a recently proposed method seems to be gaining some confidence [1]. This method suggests a two-step process; initially the DBDS and some oil soluble copper complexes are formed. Secondly the copper complexes are absorbed in the paper insulation, where they then decompose into copper sulphide [2]. The most commonly used mitigating technique for corrosive sulphur contaminated oil is passivation, normally using Irgamet 39 or 1, 2, 3-benzotriazole (BTA). The passivator is diluted into the oil to a concentration of around 100ppm, where it then reacts with the copper conductors to form a complex layer around the copper, preventing it from interacting with DBDS compounds and forming copper sulphide. This research project will investigate the electrical properties of HV transformers which have tested positive for corrosive sulphur, and the evolution of those properties as the asset degrades due to sulphur corrosion. Parallel to this the long term properties of transformers with passivated insulation oil will be analysed in order to understand the passivator stability and whether it is necessary to keep adding the passivator to sustain its performance. Condition monitoring techniques under investigation will include dielectric spectroscopy, frequency response analysis, recovery voltage method (aka interfacial polarisation) amongst others. Partial discharge techniques will not be investigated, as the voltage between the coil plates is low and therefore it will not contribute significantly to the overall insulation breakdown, in corrosive oil related faults [3]. The goal of this research is to establish key electrical properties in both passivated and non-passivated power transformers that demonstrate detectable changes as the equipment degrades due to the insulation oil being corrosive

Spodic horizon characteristics of some forest soils in the White Mountains, New Hampshire, Station Bulletin, no.507

The Bulletin is a publication of the New Hampshire Agricultural Experiment Station, College of Life Sciences and Agriculture, University of New Hampshire, Durham, New Hampshire

Genetic Sampling of Palmer\u27s Chipmunks in the Spring Mountains, Nevada

Palmer\u27s chipmunk (Neotamias palmeri) is a medium-sized chipmunk whose range is limited to the higherelevation areas of the Spring Mountain Range, Nevada. A second chipmunk species, the Panamint chipmunk (Neotamias panamintinus), is more broadly distributed and lives in lower-elevation, primarily pinyon-juniper (Pinus monophylla-Juniperus osteosperma) habitat types. Panamint chipmunks are not closely related to Palmer\u27s, but field identification of the 2 species is unreliable. Palmer\u27s chipmunk is a species of concern in the state of Nevada and is listed by the International Union for Conservation of Nature (IUCN) as endangered. As such, conservation of Palmer\u27s chipmunks is a priority in the Spring Mountains National Recreation Area. We sampled putative Palmer\u27s chipmunks from 13 sites distributed across the Spring Mountains during 2010–2011. We removed Panamint chipmunks by using DNA-based identifications and then analyzed the genetic population structure of Palmer\u27s chipmunks by using a panel of 9 microsatellites. Of the 228 samples that were genotyped, 186 were Palmer\u27s; there was no evidence of hybridization between species. Four sites had exclusively Panamint chipmunks, 5 had exclusively Palmer\u27s chipmunks, and 3 had a mixture of the 2 species. In this study, Palmer\u27s chipmunks were exclusively captured at sites above 2400 m elevation, and Panamint chipmunks were exclusively captured at sites below 2200 m. Panamint chipmunks were trapped in areas typed as pinyon-juniper, but they were also trapped at sites typed as ponderosa pine (Pinus ponderosa) and mixed conifer. Both species were trapped at 3 sites; at all 3 sites, the lowerelevation traps contained Panamint chipmunks and the higher ones Palmer\u27s chipmunks. Population structure within Palmer\u27s chipmunks was minimal: heterozygosity was relatively high, and the populations displayed no signs of recent bottlenecks. Indications are that the distribution of Palmer\u27s chipmunk is limited to higher-elevation areas in the Spring Mountains, but within this area, Palmer\u27s chipmunk occurs as a single, large, well-connected, and stable population

Something’s Fishy: A Genetic Investigations Of Sculpin Species In Western Montana

Sculpin (Cottus spp.) are small, cryptic, bottom-dwelling fish native to cool and coldwater systems throughout North America. Although three species of primarily streamdwelling sculpin are thought to occur in Montana (one of which is a species of concern), their taxonomy, distribution, and origin are not well understood. In western Montana, the present distribution of sculpin species may have been shaped by both historical events, e.g., the Columbian Ice Sheet, and contemporary landscape changes (passage barriers, climate change, pollution, etc.). To evaluate sculpin presence, and species diversity, we analyzed sculpins from river drainages throughout western Montana—the Clark Fork, Blackfoot, Flathead, Bitterroot, Kootenai, Gallatin, Madison, and Missouri—east and west of the Continental Divide. We analyzed 135 samples at the mitochondrial DNA COXI gene and at 11 microsatellite DNA loci. Preliminary results of genetic analysis suggest the presence of four distinct species with hybridization among three of the species in some locations. Hybridization led to uncertainty in species designations based on morphology, but even genetically pure fish were occasionally misidentified. One species may represent an undescribed taxon that is limited in its distribution to the St. Regis drainage, although its relation to sculpin in Idaho is unknown. A second species, previously thought to be Cottus bairdii, is distinct from that taxon and is distributed on both sides of the Continental Divide

Density fluctuations and single-particle dynamics in liquid lithium

The single-particle and collective dynamical properties of liquid lithium have been evaluated at several thermodynamic states near the triple point. This is performed within the framework of mode-coupling theory, using a self-consistent scheme which, starting from the known static structure of the liquid, allows the theoretical calculation of several dynamical properties. Special attention is devoted to several aspects of the single-particle dynamics, which are discussed as a function of the thermodynamic state. The results are compared with those of Molecular Dynamics simulations and other theoretical approaches.Comment: 31 pages (in preprint format), 14 figures. Submitted to Phys. Rev.

Probing the Sensitivity of Electron Wave Interference to Disorder-Induced Scattering in Solid-State Devices

The study of electron motion in semiconductor billiards has elucidated our understanding of quantum interference and quantum chaos. The central assumption is that ionized donors generate only minor perturbations to the electron trajectories, which are determined by scattering from billiard walls. We use magnetoconductance fluctuations as a probe of the quantum interference and show that these fluctuations change radically when the scattering landscape is modified by thermally-induced charge displacement between donor sites. Our results challenge the accepted understanding of quantum interference effects in nanostructures.Comment: 8 pages, 5 figures, Submitted to Physical Review

The ethos of physical activity delivery in mental health: a narrative study of service user experiences.

Our research into the physical activity experiences of people with severe mental illness has led us to take seriously the social and cultural environment in which physical activity is delivered. In this study, through narrative methodology, we examine service user accounts of physical activity to illuminate the characteristics of physical activity groups that are experienced as positive, helpful, or beneficial. We present several qualities and show how effective leadership and coaching is central to these qualities being present. We conclude that it is not so much what activity is delivered, but how it is delivered that is critical for sustained participation and positive outcomes

Predicted Infrared and Raman Spectra for Neutral Ti_8C_12 Isomers

Using a density-functional based algorithm, the full IR and Raman spectra are calculated for the neutral Ti_8C_12 cluster assuming geometries of Th, Td, D2d and C3v symmetry. The Th pentagonal dodecahedron is found to be dynamically unstable. The calculated properties of the relaxed structure having C3v symmetry are found to be in excellent agreement with experimental gas phase infrared results, ionization potential and electron affinity measurements. Consequently, the results presented may be used as a reference for further experimental characterization using vibrational spectroscopy.Comment: 6 pages, 5 figures. Physical Review A, 2002 (in press

Anomalous vacuum energy and stability of a quantum liquid

KT is grateful to EPSRC and V V Brazhkin to RSF 14-22- 00093 for support