Calibration of ultrafiltration membranes against size exclusion chromatography columns

Using the extension of the concept of universal calibration parameter, yielding a relation between the hydrodynamic volume of molecules and the elution volume in sizeexclusionchromatography (SEC), to retention coefficients in ultrafiltration (UF), we propose a direct calibration of UF membranes against chromatography columns. Plotting the retention coefficient by one given UF membrane of a series of probe molecules versus their elution volume in SEC chromatography provides a calibration curve for this membrane. For a wide range of retentions, such calibration can be directly used to predict the retention of any molecule: one only needs to measure its exclusion volume by the SEC column, and read the retention by the calibrated membrane on the calibration curves. The method has been tested with dextran and PEG for the calibration, and milk proteins as test molecules, for three different membranes. The predicted values of the retention are in rather good agreement with those experimentally measured in a UF cell

The origin ofhigh hydraulic resistance for filter cakes ofdef ormable particles: cell-bed deformation or surface-layer effect?

This study reports a numerical approach for modeling the hydraulic resistance ofa filter cake ofdef ormable cells. First, a mechanical and osmotic model that describes the volume fraction ofsolids in a bed ofyeast cells as a function ofthe compressive pressure it experiences is presented. The effects ofpressure on the compressibility ofyeast cells beds were further investigated both by filtration experiments and by centrifugal experiments based on the multiple speed equilibrium sediment height technique. When comparing the latter measurements with compression model calculations, we observed that the method based on centrifugal experiments suffers from rapid relaxation of the compressed bed. Concerning the filtration experiments, specific resistance ofwell-defined bed ofcells were calculated by a combination of the compression model with a formulation for hydraulic resistivity developed using the Lattice Boltzmann method. We further explain the experimental values observed for the hydraulic resistance ofcell beds, assuming that the first layer ofcells in contact with the membrane partially blocks the membrane area open to flow. In such a case, the blocked area seems to be a constant fraction of the normal cell–cell contact area

Experimental study of depolarization and antenna correlation in tunnels in the 1.3 GHz band

Measurements have been carried out in a low-traffic road tunnel to investigate the influence of the polarization of the transmitting and receiving antennas on the channel characteristics. A real-time channel sounder working in a frequency band around 1.3 GHz has been used, the elements of the transmitting and receiving arrays being dual-polarized patch antennas. Special emphasis is made on cross-polarization discrimination factor and on the spatial correlation between array elements which has a great influence on the performances of transmit/receive diversity schemes. Various polarizations both at the transmitter and the receiver have been tested to minimize this spatial correlation while keeping the size of the array as small as possible

Supernovae: an example of complexity in the physics of compressible fluids

The supernovae are typical complex phenomena in fluid mechanics with very different time scales. We describe them in the light of catastrophe theory, assuming that successive equilibria between pressure and gravity present a saddle-node bifurcation. In the early stage we show that the loss of equilibrium may be described by a generic equation of the Painlev\'e I form. In the final stage of the collapse, just before the divergence of the central density, we show that the existence of a self-similar collapsing solution compatible with the numerical observations imposes that the gravity forces are stronger than the pressure ones. This situation differs drastically in its principle from the one generally admitted where pressure and gravity forces are assumed to be of the same order. Our new self-similar solution (based on the hypothesis of dominant gravity forces) which matches the smooth solution of the outer core solution, agrees globally well with our numerical results. Whereas some differences with the earlier self-similar solutions are minor, others are very important. For example, we find that the velocity field becomes singular at the collapse time, diverging at the center, and decreasing slowly outside the core, whereas previous works described a finite velocity field in the core which tends to a supersonic constant value at large distances. This discrepancy should be important for explaining the emission of remnants in the post-collapse regime. Finally we describe the post-collapse dynamics, when mass begins to accumulate in the center, also within the hypothesis that gravity forces are dominant.Comment: Workshop in Honor of Paul Manneville, Paris (2013

A Novel Communication and Radar System for Underground Railway Applications

A system allowing data to be exchanged between two successive trains in a tunnel, while simultaneously measuring the distance between them, would help to optimize train traffic in very long tunnels, without lowering safety standards. A study including both theoretical and experimental phases was conducted to design and optimize such a system and focused on the Channel Tunnel, between France and England, where a minimum range of 5 km is necessary for operational use. A prototype, operating at 2.45 GHz and based on this new concept, produced successful results. Given that this technique would also be useful in any underground rail system, particularly those that are automated, the prototype was also tested on subway lines, in Lille and Paris

Channel correlation-based approach for feedback overhead reduction in massive MIMO

For frequency-division duplex multiple-input-multiple-output (MIMO) systems, the channel state information at the transmitter is usually obtained by sending pilots or reference signals from all elements of the antenna array. The channel is then estimated by the receiver and communicated back to the transmitter. However, for massive MIMO, this periodical estimation of the full transfer matrix can lead to prohibitive overhead. To reduce the amount of data, we propose to estimate the updated channel matrix from the knowledge of the full correlation matrix at the transmitter made during some initialization time and the instantaneous measured channel matrix of smaller size, characterizing the link between the user and a limited number of reference array elements. The proposed algorithm is validated with measured massive MIMO channel transfer functions at 3.5GHz between a $9 \times 9$ uniform rectangular array and different user positions. Since measurements were made in static conditions, the criteria chosen for evaluating the performance of the algorithm are based on a comparison of the predicted channel capacity calculated from either the measured or estimated channel matrix

Experimental investigation of V2I radio channel in an arched tunnel

This paper describes the results of the experimental radio channel sounding campaign performed in an arched road tunnel in Le Havre, France. The co-polar and cross-polar channels measurements are carried out in the closed side lane, while the lane along the center of the tunnel is open to traffic. We investigate the channel characteristics in terms of: path loss, fading distribution, polarization power ratios and delay spread. All these parameters are essential for the deployment of vehicular communication systems inside tunnels. Our results indicate that, while the H-polar channel gain attenuates slower than the V-polar channel due to the geometry of the tunnel, the mean delay spread of the H-polar channel is larger than that of the V-polar channel

Mechanical behaviour of iron oxide scale: Experimental and numerical study

2nd International Conference on Tribology in Manufacturing Processes (ICTMP2004), Nyborg, Denmark, June 15-18, 2004International audienceThe paper addresses the identification of constitutive parameters of thick, brittle layers on metal substrates. Application is to the iron oxide behaviour during hot rolling processes of steel, where oxide scale breaking and embedding is one of the major causes of surface defects. Contact management of a FEM software has been adapted in order to address the transitions corresponding to transverse oxide fracture, along with two other mechanisms, namely delamination and interfacial stick/slip. It is applied to the hot strip rolling process to show pre-bite cracking and its consequences ("micro-extrusion" of the metal). To approximate the stress state prevailing at roll bite entry, the Four-Point Hot Bending Test (4PHBT) has been selected for the measurement of oxide properties. Oxidation is made in situ in the test rig under conditions similar to a hot strip mill (HSM) environment. Comparison of load-deflection curves for oxidized and non-oxidized samples allows the mechanical properties of the oxide to be determined. Above a critical temperature T-c - around 700 degrees C, but depending on strain rate - the oxide is ductile (with a very narrow plastic strain range, epsilon(p) < 10(-2)) and elastic-viscoplastic (EVP) constitutive parameters are identified numerically. Below T-c, brittleness is manifested by an array of transverse, through-thickness cracks. Acoustic emission (AE) has been used to help detect the onset of fracture, while numerical simulation gives the critical fracture stress at the corresponding point of the load-deflection curve. Results for four low carbon steel grades are compared