45 research outputs found
Transcritical mixing of sprays for multi-component fuel mixtures
[EN] The mixing of fuels with oxidizer has been an increasingly interesting area of research with new engine technologies
and the need to reduce emissions, while leveraging efficiency. High-efficiency combustion systems such as diesel
engines rely on elevated chamber pressures to maximize power density, producing higher output. In such systems,
the fuel is injected under liquid state in a chamber filled with pressurized air at high temperatures. Theoretical
calculations on the thermodynamics of fuel mixing processes under these conditions suggest that the injected liquid
can undergo a transcritical change of state. Our previous experimental efforts in that regard showed through highspeed
imaging that spray droplets transition to fluid parcels mixing without notable surface tension forces,
supporting a transcritical process. Only mono-component fuels were used in these studies to provide full control
over boundary conditions, which prevented extrapolation of the findings to real systems in which multi-component
fuels are injected. Multi-component fuels add another layer of complexity, especially when detailed experiments
serve model development, requiring the fuels to be well characterized. In this work, we performed high-speed
microscopy in the near-field of high-pressure sprays injected into elevated temperature and pressure environments.
A reference diesel fuel and several multi-component surrogates were studied and compared to single component
fuels. The results support that a transition occurs under certain thermodynamic conditions for all fuels. As
anticipated, the transition from classical evaporation to diffusive mixing is affected by ambient conditions, fuel
properties, droplet size and velocity, as well as time scales. Analogous to previous observations made with the
normal alkane sprays, the behavior of the multi-component fuels correlate well with their bulk critical properties.This work was supported by the UK’s Engineering and Physical Science Research Council [grant number EP/K020528/1]. The authors gratefully acknowledge Coordinating Research Council Project AVFL-18a for formulating, characterizing, and providing the target and surrogate fuels used in this study. This study was performed at the Combustion Research Facility, Sandia National Laboratories is a multi-mission laboratory managed and operated by National Technology and Engineering Solutions of Sandia, LLC., a wholly owned subsidiary of Honeywell International, Inc., for the U.S. Department of Energy’s National Nuclear Security Administration under contract DE-NA0003525.Manin, J.; Crua, C.; Pickett, LM. (2017). Transcritical mixing of sprays for multi-component fuel mixtures. En Ilass Europe. 28th european conference on Liquid Atomization and Spray Systems. Editorial Universitat Politècnica de València. 553-560. https://doi.org/10.4995/ILASS2017.2017.5065OCS55356
On the transcritical mixing of fuels at diesel engine conditions
Whilst the physics of both classical evaporation and supercritical fluid mixing are reasonably well characterized and understood in isolation, little is known about the transition from one to the other in the context of liquid fuel systems. The lack of experimental data for microscopic droplets at realistic operating conditions impedes the development of phenomenological and numerical models. To address this issue we performed systematic measurements using high-speed long-distance microscopy, for three single-component fuels (n-heptane, n-dodecane, n-hexadecane), into gas at elevated temperatures (700-1200 K) and pressures (2-11 MPa). We describe these high-speed visualizations and the time evolution of the transition from liquid droplet to fuel vapour at the microscopic level. The measurements show that the classical atomization and vaporisation processes do shift to one where surface tension forces diminish with increasing pressure and temperature, but the transition to diffusive mixing does not occur instantaneously when the fuel enters the chamber. Rather, subcritical liquid structures exhibit surface tension in the near-nozzle region and then, after time surrounded by the hot ambient gas and fuel vapour, undergo a transition to a dense miscible fluid. Although there was clear evidence of surface tension and primary atomization for n-dodecane and n-hexadecane for a period of time at all the above conditions, n-heptane appeared to produce a supercritical fluid from the nozzle outlet when injected at the most elevated conditions (1200 K, 10 MPa). This demonstrates that the time taken by a droplet to transition to diffusive mixing depends on the pressure and temperature of the gas surrounding the droplet as well as the fuel properties. We summarise our observations into a phenomenological model which describes the morphological evolution and transition of microscopic droplets from classical evaporation through a transitional mixing regime and towards diffusive mixing, as a function of operating conditions. We provide criteria for these regime transitions as reduced pressure–temperature correlations, revealing the conditions where transcritical mixing is important to diesel fuel spray mixing
A conceptual model of the flame stabilization mechanisms for a lifted Diesel-type flame based on direct numerical simulation and experiments
This work presents an analysis of the stabilization of diffusion flames created by the injection of fuel into hot air, as found in Diesel engines. It is based on experimental observations and uses a dedicated Direct Numerical Simulation (DNS) approach to construct a numerical setup, which reproduces the ignition features obtained experimentally. The resulting DNS data are then used to classify and analyze the events that allow the flame to stabilize at a certain Lift-Off Length (LOL) from the fuel injector. Both DNS and experiments reveal that this stabilization is intermittent: flame elements first auto-ignite before being convected downstream until another sudden auto-ignition event occurs closer to the fuel injector. The flame topologies associated to such events are discussed in detail using the DNS results, and a conceptual model summarizing the observation made is proposed. Results show that the main flame stabilization mechanism is auto-ignition. However, multiple reaction zone topologies, such as triple flames, are also observed at the periphery of the fuel jet helping the flame to stabilize by filling high-temperature burnt gases reservoirs localized at the periphery, which trigger auto-ignitions
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The effect of oxygenate molecular structure on soot production in direct-injection diesel engines.
A combined experimental and kinetic modeling study of soot formation in diesel engine combustion has been used to study the addition of oxygenated species to diesel fuel to reduce soot emissions. This work indicates that the primary role of oxygen atoms in the fuel mixture is to reduce the levels of carbon atoms available for soot formation by fixing them in the form of CO or COz. When the structure of the oxygenate leads to prompt and direct formation of CO2, the oxygenate is less effective in reducing soot production than in cases when all fuel-bound 0 atoms produce only CO. The kinetic and molecular structure principles leading to this conclusion are described
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Summary report : universal fuel processor.
The United States produces only about 1/3 of the more than 20 million barrels of petroleum that it consumes daily. Oil imports into the country are roughly equivalent to the amount consumed in the transportation sector. Hence the nation in general, and the transportation sector in particular, is vulnerable to supply disruptions and price shocks. The situation is anticipated to worsen as the competition for limited global supplies increases and oil-rich nations become increasingly willing to manipulate the markets for this resource as a means to achieve political ends. The goal of this project was the development and improvement of technologies and the knowledge base necessary to produce and qualify a universal fuel from diverse feedstocks readily available in North America and elsewhere (e.g. petroleum, natural gas, coal, biomass) as a prudent and positive step towards mitigating this vulnerability. Three major focus areas, feedstock transformation, fuel formulation, and fuel characterization, were identified and each was addressed. The specific activities summarized herein were identified in consultation with industry to set the stage for collaboration. Two activities were undertaken in the area of feedstock transformation. The first activity focused on understanding the chemistry and operation of autothermal reforming, with an emphasis on understanding, and therefore preventing, soot formation. The second activity was focused on improving the economics of oxygen production, particularly for smaller operations, by integrating membrane separations with pressure swing adsorption. In the fuel formulation area, the chemistry of converting small molecules readily produced from syngas directly to fuels was examined. Consistent with the advice from industry, this activity avoided working on improving known approaches, giving it an exploratory flavor. Finally, the fuel characterization task focused on providing a direct and quantifiable comparison of diesel fuel and JP-8
Passive scalar mixing in a planar shear layer with laminar and turbulent inlet conditions
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