Incidence of the Tomonaga-Luttinger liquid state on the NMR spin lattice relaxation in Carbon Nanotubes

We report 13C nuclear magnetic resonance measurements on single wall carbon nanotube (SWCNT) bundles. The temperature dependence of the nuclear spin-lattice relaxation rate, 1/T1, exhibits a power-law variation, as expected for a Tomonage-Luttinger liquid (TLL). The observed exponent is smaller than that expected for the two band TLL model. A departure from the power law is observed only at low T, where thermal and electronic Zeeman energy merge. Extrapolation to zero magnetic field indicates gapless spin excitations. The wide T range on which power-law behavior is observed suggests that SWCNT is so far the best realization of a one-dimensional quantum metal.Comment: 5 pages, 4 figure

Topological Quantum Optics in Two-Dimensional Atomic Arrays

We demonstrate that two-dimensional atomic emitter arrays with subwavelength spacing constitute topologically protected quantum optical systems where the photon propagation is robust against large imperfections while losses associated with free space emission are strongly suppressed. Breaking time-reversal symmetry with a magnetic field results in gapped photonic bands with non-trivial Chern numbers and topologically protected, long-lived edge states. Due to the inherent nonlinearity of constituent emitters, such systems provide a platform for exploring quantum optical analogues of interacting topological systems.Comment: 11 pages and 9 figures; paper updated to match published versio

Photoreforming of food waste into value-added products over visible-light-absorbing catalysts

Food and mixed wastes are converted into H2 and organics over CdS and carbon nitride photocatalysts.</p

Low temperature fullerene encapsulation in single wall carbon nanotubes: synthesis of N@C60_{60}@SWCNT

High filling of single wall carbon nanotubes (SWCNT) with C$_{60}$ and C$_{70}$ fullerenes in solvent is reported at temperatures as low as 69 $^{o}$C. A 2 hour long refluxing in n-hexane of the mixture of the fullerene and SWCNT results in a high yield of C$_{60}$,C$_{70}$@SWCNT, fullerene peapod, material. The peapod filling is characterized by TEM, Raman and electron energy loss spectroscopy and X-ray scattering. We applied the method to synthesize the temperature sensitive (N@C$_{60}$:C$_{60}$)@SWCNT as proved by electron spin resonance spectroscopy. The solvent prepared peapod samples can be transformed to double walled nanotubes enabling a high yield and industrially scalable production of DWCNT

Potential Performance Enhancement of a Solar Combisystem with an Intelligent Controller

Solar thermal systems in residential buildings are generally controlled by two-level controllers, which activate solar thermal or at times with low solar radiation auxiliary energy supply into a thermal storage. Simple controllers do not have any information on actual or expected solar radiation. This leads to interference of auxiliary- and solar heat supply, which reduces the share of solar thermal energy fed into the thermal storage. Increasing accuracy of weather forecast data suggests incorporation of this information in the control algorithm. This work analyzes the maximum potential performance enhancement when applying such an intelligent predictive control. Two solar thermal systems with one auxiliary source respectively are designed in TRNSYS - these systems represent the base case. Further, a number of simulations are conducted with minor variations for the plant parameters - this gives generic results for different system configurations. In addition, each system configuration is altered to mimic the behavior of a plant with intelligent predictive control. Comparison of results indicates an improvement potential up to 10% for annual solar fractions and up to 30% for monthly solar fractions. The performance bound with respect to the annual auxiliary energy savings is approximately 8%

Phonon surface mapping of graphite: disentangling quasi--degenerate phonon dispersions

The two-dimensional mapping of the phonon dispersions around the $K$ point of graphite by inelastic x-ray scattering is provided. The present work resolves the longstanding issue related to the correct assignment of transverse and longitudinal phonon branches at $K$. We observe an almost degeneracy of the three TO, LA and LO derived phonon branches and a strong phonon trigonal warping. Correlation effects renormalize the Kohn anomaly of the TO mode, which exhibits a trigonal warping effect opposite to that of the electronic band structure. We determined the electron--phonon coupling constant to be 166$\rm(eV/\AA)^2$ in excellent agreement to $GW$ calculations. These results are fundamental for understanding angle-resolved photoemission, double--resonance Raman and transport measurements of graphene based systems