5 research outputs found
Study of the electrochemical properties of rutin in different inert electrolytes
U ovom radu je opisano ispitivanje elektrokemijskih svojstava rutina (3`,4`,5,7-tetrahidroksiflavon--rutinozida) u tri razliÄita inertna elektrolita: KCl, NaCl i LiCl. Mjerenja su izvedena pomoÄu diferencijalne pulsne voltametrije. Iz voltamograma je vidljivo da struja i potencijal oksidacijskih strujnih vrhova rastu s porastom koncentracije rutina. Najbolji kalibracijski dijagram je dobiven u otopini s kalijevim kloridom kao inertnim elektrolitom, pa je za odreÄivanje nepoznate koncentracije rutina u ekstraktu kore jabuke Zimnjare koriÅ”ten taj kalibracijski dijagram. OdreÄena koncentracija rutina u ispitivanom ekstraktu iznosi 18,7ā mol .In this work, a study of electrochemical characterizations of rutin (3ā,4ā,5,7-tetrahydroxyflavone--rutinoside) in three different inert electrolytes: KCl, NaCl and LiCl is described. Measurements were performed by differential pulse voltammetry. Voltammograms have shown that current and potential were increasing with the increase of rutin concentration. The best calibration diagram was obtained in solution with potassium chloride as inert electrolyte, so this calibration diagram was used for determination of rutin concentration in an apple peel extract of Zimnjara. Concentration of rutin in apple peel extract is 18,7ā mol
RužiÄka days : International conference 16th RužiÄka Days āToday Science ā Tomorrow Industryā : Proceedings
Proceedings contains articles presented at Conference divided into sections: open lecture (1), chemical analysis and synthesis (3), chemical and biochemical engineering (8), food technology and biotechnology (8), medical chemistry and pharmacy (3), environmental protection (11) and meeting of young chemists (2)
Study of the electrochemical properties of rutin in different inert electrolytes
U ovom radu je opisano ispitivanje elektrokemijskih svojstava rutina (3`,4`,5,7-tetrahidroksiflavon--rutinozida) u tri razliÄita inertna elektrolita: KCl, NaCl i LiCl. Mjerenja su izvedena pomoÄu diferencijalne pulsne voltametrije. Iz voltamograma je vidljivo da struja i potencijal oksidacijskih strujnih vrhova rastu s porastom koncentracije rutina. Najbolji kalibracijski dijagram je dobiven u otopini s kalijevim kloridom kao inertnim elektrolitom, pa je za odreÄivanje nepoznate koncentracije rutina u ekstraktu kore jabuke Zimnjare koriÅ”ten taj kalibracijski dijagram. OdreÄena koncentracija rutina u ispitivanom ekstraktu iznosi 18,7ā mol .In this work, a study of electrochemical characterizations of rutin (3ā,4ā,5,7-tetrahydroxyflavone--rutinoside) in three different inert electrolytes: KCl, NaCl and LiCl is described. Measurements were performed by differential pulse voltammetry. Voltammograms have shown that current and potential were increasing with the increase of rutin concentration. The best calibration diagram was obtained in solution with potassium chloride as inert electrolyte, so this calibration diagram was used for determination of rutin concentration in an apple peel extract of Zimnjara. Concentration of rutin in apple peel extract is 18,7ā mol
Characterization of the structural features of ripple phase of phosphocholine liposomes using FT-IR spectroscopy
Molekule 1,2-dipalmitoil-sn-glicero-3-fosfokolina (engl. 1,2-dipalmitoyl-sn-glicero-3-
phosphatidylcholine, DPPC) u vodenom mediju stvaraju hidrirane dvosloje koji se, ovisno o
temperaturi, nalaze u odreÄenoj fazi. Prijelaz DPPC-a iz faze gela (LĪ²') u fazu fluida (LĪ±),
odnosno glavni fazni prijelaz opažen pri temperaturi mekŔanja (Tm), prekinut je valovitom
fazom (PĪ²') koja se opaža pri temperaturi pretprijelaza (Tp). BuduÄi da su Tm i Tp iznimno
osjetljive na ugradnju organskih molekula u lipidni dvosloj, posebice onih koje su kadre
primati i otpuŔtati proton, u sklopu ovog diplomskog rada istraženi su viŔestruki hidrirani
dvosloji DPPC lipida u odsutnosti i prisutnosti male koliÄine palmitinske kiseline (engl.
palmitic acid, PA) u puferima razliÄitih pH vrijednosti. Tm i Tp odreÄene su analizom
vibracijskih potpisa metilenskih (Ī½sCH2) i fosfatnih (Ī½asPO2ā) skupina iz temperaturno-ovisnih
FT-IR spektara. Dobiveni podaci su djelomiÄno upotpunjeni onima dobivenima iz
razlikovno-pretražne kalorimetrije (engl. differential scanning calorimetry, DSC).1,2-dipalmitoyl-sn-glycero-3-phosphocoline form hydrated bilayers in an aqueous medium
which, depending on the temperature, can be found in certain phase. The transition from gel
(LĪ²') to fluid phase (LĪ±), assigned as the main phase transition with a peak at melting point
temperature (Tm), is interrupted by the ripple phase (PĪ²') observed at the pretransition
temeprature (Tp). Since Tm and Tp are extremely sensitive to the incorporation of organic
molecules into the lipid bilayer, especially those capable of receiving and releasing a proton,
multiple hydrated bilayers of DPPC lipids in the absence and presence of small amounts of
palmitic acid (PA) in buffers of different pH values have been investigated across this thesis.
Tm and Tp have been determined by the analysis of vibrational signatures of methylene
(Ī½sCH2) and phosphate (Ī½asPO2ā) groups from temperature-dependent FT-IR spectra. These
data have been partially supplemented by those obtained from differential scanning
calorimetry (DSC)
Characterization of the structural features of ripple phase of phosphocholine liposomes using FT-IR spectroscopy
Molekule 1,2-dipalmitoil-sn-glicero-3-fosfokolina (engl. 1,2-dipalmitoyl-sn-glicero-3-
phosphatidylcholine, DPPC) u vodenom mediju stvaraju hidrirane dvosloje koji se, ovisno o
temperaturi, nalaze u odreÄenoj fazi. Prijelaz DPPC-a iz faze gela (LĪ²') u fazu fluida (LĪ±),
odnosno glavni fazni prijelaz opažen pri temperaturi mekŔanja (Tm), prekinut je valovitom
fazom (PĪ²') koja se opaža pri temperaturi pretprijelaza (Tp). BuduÄi da su Tm i Tp iznimno
osjetljive na ugradnju organskih molekula u lipidni dvosloj, posebice onih koje su kadre
primati i otpuŔtati proton, u sklopu ovog diplomskog rada istraženi su viŔestruki hidrirani
dvosloji DPPC lipida u odsutnosti i prisutnosti male koliÄine palmitinske kiseline (engl.
palmitic acid, PA) u puferima razliÄitih pH vrijednosti. Tm i Tp odreÄene su analizom
vibracijskih potpisa metilenskih (Ī½sCH2) i fosfatnih (Ī½asPO2ā) skupina iz temperaturno-ovisnih
FT-IR spektara. Dobiveni podaci su djelomiÄno upotpunjeni onima dobivenima iz
razlikovno-pretražne kalorimetrije (engl. differential scanning calorimetry, DSC).1,2-dipalmitoyl-sn-glycero-3-phosphocoline form hydrated bilayers in an aqueous medium
which, depending on the temperature, can be found in certain phase. The transition from gel
(LĪ²') to fluid phase (LĪ±), assigned as the main phase transition with a peak at melting point
temperature (Tm), is interrupted by the ripple phase (PĪ²') observed at the pretransition
temeprature (Tp). Since Tm and Tp are extremely sensitive to the incorporation of organic
molecules into the lipid bilayer, especially those capable of receiving and releasing a proton,
multiple hydrated bilayers of DPPC lipids in the absence and presence of small amounts of
palmitic acid (PA) in buffers of different pH values have been investigated across this thesis.
Tm and Tp have been determined by the analysis of vibrational signatures of methylene
(Ī½sCH2) and phosphate (Ī½asPO2ā) groups from temperature-dependent FT-IR spectra. These
data have been partially supplemented by those obtained from differential scanning
calorimetry (DSC)