Why Jokes are Funny and the Language of the New Testament

Doctoral Presentatio

An Analysis of the –μός Suffix in the New Testament

This dissertation describes and analyzes the –μός suffix in the New Testament. This suffix indicates a noun derived from a verbal stem, i.e., a deverbal noun. Due to the lack of an in-depth analysis of this suffix, some incomplete ideas about this suffix have appeared in Greek grammars. Along with scholarship in Greek grammar, this dissertation employs terms from the field of linguistics, as well as patterns suggested from studies of deverbal nouns in other languages. This method will reveal two groups of conclusions. First, it will reveal that the suffix and nouns in which it occurs follow traditional expectations, such as morphological and grammatical rules. Second, it will reveal general principles to help scholars interpret –μός nouns. Principles for interpretation will first aid in distinguishing between occurrences that refer to a process and those that refer to a result. For occurrences that refer to a process, a second set of principles will equip scholars to determine the subject, object, and other important parts of the implied process

Direct Observation of the Dynamics of Ylide Solvation by Hydrogen-bond Donors using Time-Resolved Infrared Spectroscopy

[Image: see text] The photoexcitation of α-diazocarbonyl compounds produces singlet carbene intermediates that react with nucleophilic solvent molecules to form ylides. The zwitterionic nature of these newly formed ylides induces rapid changes in their interactions with the surrounding solvent. Here, ultrafast time-resolved infrared absorption spectroscopy is used to study the ylide-forming reactions of singlet carbene intermediates from the 270 nm photoexcitation of ethyl diazoacetate in various solvents and the changes in the subsequent ylide–solvent interactions. The results provide direct spectroscopic observation of the competition between ylide formation and C–H insertion in reactions of the singlet carbene with nucleophilic solvent molecules. We further report the specific solvation dynamics of the tetrahydrofuran (THF)-derived ylide (with a characteristic IR absorption band at 1636 cm(–1)) by various hydrogen-bond donors and the coordination by lithium cations. Hydrogen-bonded ylide bands shift to a lower wavenumber by −19 cm(–1) for interactions with ethanol, −14 cm(–1) for chloroform, −10 cm(–1) for dichloromethane, −9 cm(–1) for acetonitrile or cyclohexane, and −16 cm(–1) for Li(+) coordination, allowing the time evolution of the ylide–solvent interactions to be tracked. The hydrogen-bonded ylide bands grow with rate coefficients that are close to the diffusional limit. We further characterize the specific interactions of ethanol with the THF-derived ylide using quantum chemical (MP2) calculations and DFT-based atom-centered density matrix propagation trajectories, which show preferential coordination to the α-carbonyl group. This coordination alters the hybridization character of the ylidic carbon atom, with the greatest change toward sp(2) character found for lithium-ion coordination

Response and Recovery of the Comanche Carbonate Platform Surrounding Multiple Cretaceous Oceanic Anoxic Events, Northern Gulf of Mexico

The ubiquity of carbonate platforms throughout the Cretaceous Period is recognized as a product of high eustatic sea-level and a distinct climatic optimum induced by rapid sea-floor spreading and elevated levels of atmospheric carbon-dioxide. Notably, a series of global oceanic anoxic events (OAEs) punctuate this time-interval and mark periods of significantly reduced free oxygen in the world's oceans. The best records of these events are often from one-dimensional shelf or basin sections where only abrupt shifts between oxygenated carbonates and anoxic shales are recorded. The Comanche Platform of central Texas provides a unique opportunity to study these events within a well-constrained stratigraphic framework in which their up-dip and down-dip sedimentologic effects can be observed and the recovery of the platform to equilibrium states can be timed and understood. Stable isotope data from whole cores in middle Hauterivian through lower Campanian mixed carbonate-siliciclastic strata are used to construct a 52-myr carbon isotope reference profile for the northern Gulf of Mexico. Correlation of this composite curve to numerous global reference profiles permits identification of several anoxic events and allows their impact on platform architecture and fades distribution to be documented. Oceanic anoxic events la, 1b, 1d, and 2 occurred immediately before, after, or during shale deposition in the Pine Island Member, Bexar Member, Del Rio Formation, and Eagle Ford Group, respectively. Oceanic anoxic event 3 corresponds to deposition of the Austin Chalk Group. Platform drowning on three occasions more closely coincided with globally recognized anoxic sub-events such as the Fallot, Albian-Cenomanian, and Mid-Cenomanian events. This illustrates that the specific anoxic event most affecting a given carbonate platform varied globally as a function of regional oceanographic circumstances. Using chemo- and sequence-stratigraphic observations, a four-stage model is proposed to describe the changing fades patterns, fauna, sedimentation accumulation rates, platform architectures, and relative sea-level trends of transgressive-regressive composite sequences that developed in response to global carbon-cycle perturbations. The four phases of platform evolution include the equilibrium, crisis, anoxic, and recovery stages. The equilibrium stage is characterized by progradational shelf geometries and coralrudist phototrophic faunal assemblages. Similar phototrophic fauna typify the crisis stage; however, incipient biocalcification crises of this phase led to retrogradational shelf morphologies, transgressive facies patterns, and increased clay mineral proportions. Anoxic stages of the Comanche Platform were coincident with back-ground deposition of organic-rich shale on drowned shelves and heterotrophic fauna dominated by oysters or coccolithophorids. Eustatic peaks of this stage were of moderate amplitude (similar to 30 m), yet relative sea-level rises were greatly enhanced by reduced sedimentation rates. In the recovery stage, heterotrophic carbonate factories re-established at the shoreline as progradational ramp systems and sediment accumulation rates slowly increased as dysoxia diminished. Full recovery to equilibrium conditions may or may not have followed. Geochemical and stratigraphic trends present in the four stages are consistent with increased volcanism along mid-ocean ridges and in large-igneous provinces as primary drivers of Cretaceous OAEs and the resulting transgressive-regressive composite sequences. (C) 2014 Elsevier Ltd. All rights reserved.BHP-BillitonReservoir Characterization Research Laboratory, the Bureau of Economic GeologyJackson School of Geosciences at the University of Texas at AustinBureau of Economic Geolog

The Great Commissioning: An Exegesis of Matthew 28:16-20

Throughout the history of Christianity, evangelism has been an often-discussed topic. At certain times the discussion has revolved around the question of whether or not there is a command to actively seek out unbelievers for the purpose of evangelism in the Bible that applies to Christians in the world they live in. One of the most common verses cited as a command for evangelism is Matthew 28:18-20, commonly called the Great Commission. However, some Christians argue that this is a command for discipleship and not evangelism. While it is hard to make a distinction based on this verse alone, Matthew has included in this command of Christ to teach all that I have commanded you. This crucial line of text provides two inferences. First, if the disciples were to teach everything Christ commanded them, then teaching their disciples to create other disciples would be part of this, and the command would be reciprocal. Second, if there is another command for evangelism within Matthew\u27s Gospel that is included as part of all that I have commanded you, then this would be a command for evangelism. Because both of these conditional statements prove to be true, then believer\u27s at all times have a command to spread the gospel (evangelize) to unbelievers

Testing USDA Certified Organic and Non-GMO Verified Project Labeled Foods for the Presence of Genetic Modifications

Genetically Modified Organisms (GMOs) are plants or animals that have been produced using genetic insertion or deletion via technology (also called genetic engineering or GE). Merged DNA from different species creates combinations of plant, animal, bacteria and/or virus genes that cannot occur in nature or in traditional crossbreeding. Our goal was to determine the presence or absence of GMO markers in USDA Organic Certified and in Non-GMO Project food products. We investigated only corn or soy-based products that were purchased from many types of retailers. Our study was limited to products that contained a label for USDA organic certification and/or Non-GMO Verified Project. DNA from each product was extracted, tested for purity, and examined for specific markers denoting the presence of genetic modification. Modified DNA was amplified using PCR techniques and tested against standards on electrophoretic agarose gel. Based on these results, we detected evidence of genetic modification in 75% of soy and 83.3% of corn claiming USDA Organic Certification and 0% of soy and 100% of corn claiming Non-GMO Verified Certification

Equatorial restriction of the photoinduced Jahn–Teller switch in Mn(iii)-cyclam complexes

Ultrafast transient absorption spectra were recorded for solutions of [MnIII(cyclam)(H2O)(OTf)][OTf]2 (cyclam = 1,4,8,11-tetraazacyclotetradecane and OTf = trifluoromethanesulfonate) in water to explore the possibility to restrict the equatorial expansion following photoexcitation of the dxy ← dz2 electronic transition, often resulting in a switch from axial to equatorial Jahn–Teller distortion in MnIII complexes. Strong oscillations were observed in the excited state absorption signal and were attributed to an excited state wavepacket. The structural rigidity of the cyclam ligand causes a complex reaction coordinate with frequencies of 333, 368, 454 and 517 cm−1, and a significantly shorter compressed-state lifetime compared to other MnIII complexes with less restricted equatorial ligands. Complementary density functional theory quantum chemistry calculations indicate a switch from an axially elongated to a compressed structure in the first excited quintet state Q1, which is accompanied by a modulation of the axial tilt angle. Computed harmonic frequencies for the axial stretching mode (∼379 cm−1) and the equatorial expansions (∼410 and 503 cm−1) of the Q1 state agree well with the observed coherences and indicate that the axial bond length contraction is significantly larger than the equatorial expansion, which implies a successful restriction of the wavepacket motion. The weak oscillation observed around 517 cm−1 is assigned to a see-saw motion of the axial tilt (predicted ∼610 cm−1). The results provide insights into the structural perturbations to the molecular evolution along excited state potential energy surfaces of MnIII octahedral complexes and can be used to guide the synthesis of optically controlled MnIII-based single-molecule magnets