133 research outputs found
Electrochemical properties of micro-batteries with single NCM-111 secondary particles as cathode
Although lithium ion batteries (LIB) are already used in numerous applications, e.g. as power source in portable devices, the optimization of the battery performance, such as life-time, cyclability and energy density, is of large interest for using LIBs in e.g. electrical vehicles or temporary storage systems for renewable energy sources. Typically, the performance of the cathode active material is investigated using composite electrodes. Advanced composite electrodes consist of a complex architecture with comparably large secondary particles (10 ”m - 30 ”m) of the active material built up from nanometer sized primary particles. Furthermore, they also contain additives influencing the electrochemical properties of the composite electrode. To avoid such influences and to further optimize the performance of the cathodeâs active material a detailed understanding of the impact of the cathode architecture on the ionic and electronic transport processes is necessary.
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Improved thermoelectric properties of nanostructured composites out of Bi1âxSbx nanoparticles and carbon phases
Thermoelectric figures of merit of ZT â 0.4 at room temperature were achieved in nanostructured composite materials prepared by uniaxial pressing of Bi1âxSbx nanoparticles and 0.3 wt.% of a carbon phase. This constitutes a significant improvement of the low-temperature thermoelectric material Bi1âxSbx and strongly suggests the possibility of employing these materials in efficient thermoelectric devices working at room temperature. Interestingly, the beneficial effect of the carbon phase added to nanostructured Bi1âxSbx is the same for either carbon nanotubes or active carbon. This finding is attributed, on the one hand, to a combination of electronic band gap engineering due to nanostructuring and energy filtering due to graphene-like interlayers between Bi1âxSbx grains and, on the other hand, to modified phonon scattering at the grain boundaries and additional phonon scattering by agglomeration sites of carbon material on the ÎŒm scale
Improved thermoelectric properties of nanostructured composites out of Bi1âxSbx nanoparticles and carbon phases
Thermoelectric figures of merit of ZT â 0.4 at room temperature were achieved in nanostructured composite materials prepared by uniaxial pressing of Bi1âxSbx nanoparticles and 0.3 wt.% of a carbon phase. This constitutes a significant improvement of the low-temperature thermoelectric material Bi1âxSbx and strongly suggests the possibility of employing these materials in efficient thermoelectric devices working at room temperature. Interestingly, the beneficial effect of the carbon phase added to nanostructured Bi1âxSbx is the same for either carbon nanotubes or active carbon. This finding is attributed, on the one hand, to a combination of electronic band gap engineering due to nanostructuring and energy filtering due to graphene-like interlayers between Bi1âxSbx grains and, on the other hand, to modified phonon scattering at the grain boundaries and additional phonon scattering by agglomeration sites of carbon material on the ÎŒm scale
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Monitoring the thermally induced transition from sp3-hybridized into sp2-hybridized carbons
The preparation of carbons for technical applications is typically based on a treatment of a precursor, which is transformed into the carbon phase with the desired structural properties. During such treatment the material passes through several different structural stages, for example, starting from precursor molecules via an amorphous phase into crystalline-like phases. While the structure of non-graphitic and graphitic carbon has been well studied, the transformation stages from molecular to amorphous and non-graphitic carbon are still not fully understood. Disordered carbon often contains a mixture of sp3-, sp2-and sp1-hybridized bonds, whose analysis is difficult to interpret. We systematically address this issue by studying the transformation of purely sp3-hybridized carbons, that is, nanodiamond and adamantane, into sp2-hybridized non-graphitic and graphitic carbon. The precursor materials are thermally treated at different temperatures and the transformation stages are monitored. We employ Raman spectroscopy, WAXS and TEM to characterize the structural changes. We correlate the intensities and positions of the Raman bands with the lateral crystallite size La estimated by WAXS analysis. The behavior of the D and G Raman bands characteristic for sp2-type material formed by transforming the sp3-hybridized precursors into non-graphitic and graphitic carbon agrees well with that observed using sp2-structured precursors
Long-lived states in synchronized traffic flow. Empirical prompt and dynamical trap model
The present paper proposes a novel interpretation of the widely scattered
states (called synchronized traffic) stimulated by Kerner's hypotheses about
the existence of a multitude of metastable states in the fundamental diagram.
Using single vehicle data collected at the German highway A1, temporal velocity
patterns have been analyzed to show a collection of certain fragments with
approximately constant velocities and sharp jumps between them. The particular
velocity values in these fragments vary in a wide range. In contrast, the flow
rate is more or less constant because its fluctuations are mainly due to the
discreteness of traffic flow.
Subsequently, we develop a model for synchronized traffic that can explain
these characteristics. Following previous work (I.A.Lubashevsky, R.Mahnke,
Phys. Rev. E v. 62, p. 6082, 2000) the vehicle flow is specified by car
density, mean velocity, and additional order parameters and that are
due to the many-particle effects of the vehicle interaction. The parameter
describes the multilane correlations in the vehicle motion. Together with the
car density it determines directly the mean velocity. The parameter , in
contrast, controls the evolution of only. The model assumes that
fluctuates randomly around the value corresponding to the car configuration
optimal for lane changing. When it deviates from this value the lane change is
depressed for all cars forming a local cluster. Since exactly the overtaking
manoeuvres of these cars cause the order parameter to vary, the evolution
of the car arrangement becomes frozen for a certain time. In other words, the
evolution equations form certain dynamical traps responsible for the long-time
correlations in the synchronized mode.Comment: 16 pages, 10 figures, RevTeX
IMPLEmenting a clinical practice guideline for acute low back pain evidence-based manageMENT in general practice (IMPLEMENT) : cluster randomised controlled trial study protocol
Background: Evidence generated from reliable research is not frequently implemented into clinical practice. Evidence-based clinical practice guidelines are a potential vehicle to achieve this. A recent systematic review of implementation strategies of guideline dissemination concluded that there was a lack of evidence regarding effective strategies to promote the uptake of guidelines. Recommendations from this review, and other studies, have suggested the use of interventions that are theoretically based because these may be more effective than those that are not. An evidencebased clinical practice guideline for the management of acute low back pain was recently developed in Australia. This provides an opportunity to develop and test a theory-based implementation intervention for a condition which is common, has a high burden, and for which there is an evidence-practice gap in the primary care setting. Aim: This study aims to test the effectiveness of a theory-based intervention for implementing a clinical practice guideline for acute low back pain in general practice in Victoria, Australia. Specifically, our primary objectives are to establish if the intervention is effective in reducing the percentage of patients who are referred for a plain x-ray, and improving mean level of disability for patients three months post-consultation. Methods/Design: This study protocol describes the details of a cluster randomised controlled trial. Ninety-two general practices (clusters), which include at least one consenting general practitioner, will be randomised to an intervention or control arm using restricted randomisation. Patients aged 18 years or older who visit a participating practitioner for acute non-specific low back pain of less than three months duration will be eligible for inclusion. An average of twenty-five patients per general practice will be recruited, providing a total of 2,300 patient participants. General practitioners in the control arm will receive access to the guideline using the existing dissemination strategy. Practitioners in the intervention arm will be invited to participate in facilitated face-to-face workshops that have been underpinned by behavioural theory. Investigators (not involved in the delivery of the intervention), patients, outcome assessors and the study statistician will be blinded to group allocation. Trial registration: Australian New Zealand Clinical Trials Registry ACTRN012606000098538 (date registered 14/03/2006).The trial is funded by the NHMRC by way of a Primary Health Care Project Grant (334060). JF has 50% of her time funded by the Chief Scientist Office3/2006). of the Scottish Government Health Directorate and 50% by the University of Aberdeen. PK is supported by a NHMRC Health Professional Fellowship (384366) and RB by a NHMRC Practitioner Fellowship (334010). JG holds a Canada Research Chair in Health Knowledge Transfer and Uptake. All other authors are funded by their own institutions
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