4,465 research outputs found

    MEASURING FOOD SAFETY PREFERENCES: IDENTIFYING CONSUMER SEGMENTS

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    Conjoint analysis was used to estimate individual preference functions for food safety attributes. Consumer segments were constructed by using cluster analysis to form groups which were homogeneous with respect to preferences regarding food safety. Although substantial differences existed among the three distinct groups, consumers in all segments were willing to pay a moderate amount to ensure that apples met established safety standards. However, a policy which restricts pesticide use would likely result in substantial consumer dissatisfaction, unless it could be achieved with little impact on price or quality.Food Consumption/Nutrition/Food Safety,

    Fast microwave-assisted synthesis of Li-stuffed garnets and insights into Li diffusion from muon spin spectroscopy

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    Lithium-stuffed garnets attract huge attention due to their outstanding potential as solid-state electrolytes for lithium batteries. However, there exists a persistent challenge in the reliable synthesis of these complex functional oxides together with a lack of complete understanding of the lithium-ion diffusion mechanisms in these important materials. Addressing these issues is critical to realizing the application of garnet materials as electrolytes in all solid-state lithium-ion batteries. In this work, a cubic phase garnet of nominal composition Li6.5Al0.25La2.92Zr2O12 is synthesized through a microwave-assisted solid-state route for the first time, reducing considerably the reaction times and heating temperatures. Lithium-ion diffusion behavior is investigated by electrochemical impedance spectroscopy (EIS) and state-of-art muon spin relaxation (μSR) spectroscopy, displaying activation energies of 0.55 ± 0.03 eV and 0.19 ± 0.01 eV respectively. This difference arises from the high inter-grain resistance, which contributes to the total resistance in EIS measurements. In contrast, μSR acts as a local probe providing insights on the order of the lattice, giving an estimated value of 4.62 × 10−11 cm2 s−1 for the lithium diffusion coefficient. These results demonstrate the potential of this lithium-stuffed garnet as a solid-state electrolyte for all-solid state lithium-ion batteries, an area of growing interest in the energy storage community

    Possible quadrupolar nematic phase in the frustrated spin chain LiCuSbO4_4: an NMR investigation

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    The frustrated one-dimensional (1D) quantum magnet LiCuSbO4_4 is one rare realization of the J1−J2J_1-J_2 spin chain model with an easily accessible saturation field, formerly estimated to 12~T. Exotic multipolar nematic phases were theoretically predicted in such compounds just below the saturation field, but without unambiguous experimental observation so far. In this paper we present extensive experimental research of the compound in the wide temperature (30mK−-300K) and field (0−-13.3T) range by muon spin rotation (μ\muSR), 7^7Li nuclear magnetic resonance (NMR) and magnetic susceptibility (SQUID). μ\muSR experiments in zero magnetic field demonstrate the absence of long range 3D ordering down to 30mK. Together with former heat capacity data [S.E. Dutton \emph{et al}, Phys. Rev. Lett. 108, 187206 (2012)], magnetic susceptibility measurements suggest short range correlated vector chiral phase in the field range 0−40-4T. In the intermediate field values (5−-12T), the system enters in a 3D ordered spin density wave phase with 0.75μB\mu_B per copper site at lowest temperatures (125mK), estimated by NMR. At still higher field, the magnetization is found to be saturated above 13T where the spin lattice T1−1T_1^{-1} relaxation reveals a spin gap estimated to 3.2(2)K. We narrow down the possibility of observing a multipolar nematic phase to the range 12.5−-13T.Comment: 12 pages, 15 figure

    Cognitive impairment and decline in cognitively normal older adults with high amyloid-β: A meta-analysis

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    AbstractIntroductionThis meta-analysis aimed to characterize the nature and magnitude of amyloid (Aβ)-related cognitive impairment and decline in cognitively normal (CN) older individuals.MethodMEDLINE Ovid was searched from 2012 to June 2016 for studies reporting relationships between cerebrospinal fluid or positron emission tomography (PET) Aβ levels and cognitive impairment (cross-sectional) and decline (longitudinal) in CN older adults. Neuropsychological data were classified into domains of episodic memory, executive function, working memory, processing speed, visuospatial function, semantic memory, and global cognition. Type of Aβ measure, how Aβ burden was analyzed, inclusion of control variables, and clinical criteria used to exclude participants, were considered as moderators. Random-effects models were used for analyses with effect sizes expressed as Cohen's d.ResultsA total of 38 studies met inclusion criteria contributing 30 cross-sectional (N = 5005) and 14 longitudinal (N = 2584) samples. Aβ-related cognitive impairment was observed for global cognition (d = 0.32), visuospatial function (d = 0.25), processing speed (d = 0.18), episodic memory, and executive function (both d's = 0.15), with decline observed for global cognition (d = 0.30), semantic memory (d = 0.28), visuospatial function (d = 0.25), and episodic memory (d = 0.24). Aβ-related impairment was moderated by age, amyloid measure, type of analysis, and inclusion of control variables and decline moderated by amyloid measure, type of analysis, inclusion of control variables, and exclusion criteria used.DiscussionCN older adults with high Aβ show a small general cognitive impairment and small to moderate decline in episodic memory, visuospatial function, semantic memory, and global cognition

    Control via electron count of the competition between magnetism and superconductivity in cobalt and nickel doped NaFeAs

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    Using a combination of neutron, muon and synchrotron techniques we show how the magnetic state in NaFeAs can be tuned into superconductivity by replacing Fe by either Co or Ni. Electron count is the dominant factor, since Ni-doping has double the effect of Co-doping for the same doping level. We follow the structural, magnetic and superconducting properties as a function of doping to show how the superconducting state evolves, concluding that the addition of 0.1 electrons per Fe atom is sufficient to traverse the superconducting domain, and that magnetic order coexists with superconductivity at doping levels less than 0.025 electrons per Fe atom.Comment: 4 pages, 6 figure

    Two-gap superconductivity with line nodes in CsCa2_2Fe4_4As4_4F2_2

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    We report the results of a muon-spin rotation (μ\muSR) experiment to determine the superconducting ground state of the iron-based superconductor CsCa2_2Fe4_4As4_4F2_2 with Tc≈28.3 T_{\rm c} \approx 28.3\,K. This compound is related to the fully-gapped superconductor CaCsFe4_4As4_4, but here the Ca-containing spacer layer is replaced with one containing Ca2_2F2_2. The temperature evolution of the penetration depth strongly suggests the presence of line nodes and is best modelled by a system consisting of both an ss- and a dd-wave gap. We also find a potentially magnetic phase which appears below ≈10 \approx 10\,K but does not appear to compete with the superconductivity. This compound contains the largest alkali atom in this family of superconductors and our results yield a value for the in-plane penetration depth of λab(T=0)=423(5) \lambda_{ab}(T=0)=423(5)\,nm.Comment: 6 pages, 2 figure

    Binary black hole initial data for numerical general relativity based on post-Newtonian data

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    With the goal of taking a step toward the construction of astrophysically realistic initial data for numerical simulations of black holes, we for the first time derive a family of fully general relativistic initial data based on post-2-Newtonian expansions of the 3-metric and extrinsic curvature without spin. It is expected that such initial data provide a direct connection with the early inspiral phase of the binary system. We discuss a straightforward numerical implementation, which is based on a generalized puncture method. Furthermore, we suggest a method to address some of the inherent ambiguity in mapping post-Newtonian data onto a solution of the general relativistic constraints.Comment: 13 pages, 8 figures, RevTex
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