Degradation of Phenol in Aqueous System by Solar Photocatalysis, Photolysis and Adsorption Processes

Phenol degradation in aqueous solutions using chitosan prepared from Crassostrea gigas (Sea oyster) shells as adsorbent was investigated using photocatalysis and adsorption processes at ambient temperature. Photolysis was carried out to study the effect of light on the degradation of phenol at ambient temperature while adsorption process was carried out without utilizing solar illumination. Effect of initial concentrations of phenol (50, 75, 100 and 150 mg/l), TiO2 loading (4, 8, 16 and 20 %), and composite mass (adsorbent + TiO2) (1, 3, 5 and 8 g) were investigated using UV-Visible spectrophotometric technique. The results obtained indicate that phenol removal increases with time and concentration of the catalyst (TiO2) and decreases with increase in initial concentration of phenol and composite mass. Combination of UV irradiation with TiO2 loading gave a degradation efficiency ranging from 98.13 - 98.92 % while UV irradiation with composite mass gave a degradation efficiency ranging from 84.80 - 98.51 %. The efficiency of the processes of degradation of phenol followed the trend: photocatalysis>photolysis> adsorption. The kinetics of the degradation fitted the Langmuir and pseudo-second–order models. Keywords: Adsorption, Crassostrea gigas, Photocatalysis, Photolysis, Titanium dioxid

Effects of Planting Time and Poultry Manure on Late Season Plaintain Establishment and Yield in Owerri Rainforest Zone of Nigeria

In rainfed agriculture, plantain availability to consumer is seasonal. Late season plantain planting with appropriate organic manure application has been one of the advocated solutions. This experiment was carried out at the Federal University of Technology Teaching and Research  farm, Owerri in 2010 late season planting to determine the  appropriate time of planting and optimum manure rate that will enhance late season plantain establishment and bunch availability in the tropical rainforest. The experiment was a 3x4 factorial fitted into a randomized complete block design replicated three times. The treatments were three late season months (5th September, 5th October and 5thNovember) and four poultry manure rates (0,4,8 and 12 t.ha-1). The pre and post soil, establishment, growth and yield data were collected and analysed statistically.  The post soil chemical analysis showed an improvement on soil pH,(5.30-6.07, 5.59-5.67 and 5.73-5.72), organic matter,(2.098-2.098, 2.476-2.373 and 2.240-2.201%) calcium,(7.03-10.20, 3.60-6.40 and 5.40-5.70 l/kg) organic carbon,(1.696-1.217, 1.436-1.377 and1.436-1.277%)  phosphorous (21.39-20.86, 20.20-18.80 and14.60-13.90ppm)  and  magnesium (0.67-2.00, 0.83-1.17 and 0.83-1.00CMOL) in the treatment that received 8 and12 t ha-1 poultry manure in September, October and November planting respectively..  The residual effect of poultry manure resulted in increased yield (8.6, 7.2 and 7.0kg)  of the first ratoon crop in September, October, and November planting that received 12t ha-1poultry manure respectively.  Although poultry manure rates enhanced plantain establishment, growth and yield when planted in September, October and November, plantain planted  in September and manured with 12 t ha-1 poultry manure significantly(p=0.05) enhanced plantain establishment,(100%) ,yield (9.2kg in plant crop,8.6 first ratoon) and  income return (N 7,135,,501.8/ha) in Owerri Rainforest zone of Nigeria. Keywords: Planting time,  poultry manure, late season plantain, production, humid tropics

Assessment of the Quality of Borehole Water Sample in Federal Housing Estate and Sites and Services Areas of Owerri, Imo State, Nigeria

Assessment of the quality of borehole water samples from Federal Housing Estate and Sites and Services areas of Owerri, Imo State, Nigeria was conducted to determine the suitability of these borehole water samples. Six samples of borehole water gotten from six different families living in these areas were analyzed for microbial, chemical and physicochemical parametersusing standard analytical method of National Agency for Food and Drug Administration and Control (NAFDAC). The result of microbial analysis revealed that all the water samples (samples D, E, F, G, H, and M) had total coliform count of 64.0cfu/100ml, 5.0cfu/100ml, 41.0cfu/100ml, 16.0cfu/100ml, 124.0cfu/100ml and 0.0cfu/100ml respectively. This showed that sample D, F, G, and H exceeded the standard of 10 coliform counts/100ml. The entire samples resulted at 0 counts for Escherichia coli. Samples D, F, G and M tested negative for pseudomonas test, whereas samples E and H did not. The chemical analysis showed that all the samples did not meet up with the recommended standard of pH (6.5-8.5).However, there was significant difference (p<0.5) between samples D and E. samples F and J were significantly the same, also as samples G and M. Sample M was the least significant while sample D was the most significant at pH 4.6 and 6.4 respectively. The temperatures were all significantly the same and did not exceed standard limit of 370C. The total dissolved solid also did not exceed the limit of 500ppm and the conductivity limit was not exceeded. All the samples did not exceed limits for zinc, copper, lead, magnesium, cadmium and iron which are 3mg/l, 1mg/l, 0.01mg/l, 0.02mg/l, 0.03mg/l and 0.3mg/l  respectively except for calcium, where samples D, E, G and H were beyond standard of 0.4mg/l. All the samples were significantly different for each parameter except for lead of which the entire sample were all the same. The depth of the borehole in relation to the distance of septic tank, distance of neighbor’s septic tank and distance of refuse dump as obtained from these families revealed that sample M had the highest distance and was the least contaminated, whereas sample H had the closest distance and the greatest microbial contamination. The depth of Sample G borehole was according to the regulatory standard of 150 ft., and from the analysis the entire parameters were within standard except for pH. Keywords: Water, Standards, Microbial analysis, Total Dissolved Solid, Metals, Septic tan

In-vitro anti-inflammatory activities of 3-methoxy quercetin isolated from Nigerian mistletoe parasitic on Garcinia kola Heckel, Clusiaceae

Purpose: To evaluate the in vitro anti-oxidant and anti-inflammatory potential of the most potent and abundant metabolite, 3-methoxy quercetin (3-MQ), from extract fractions of mistletoe, Loranthus micranthus Linn (Loranthaceae) parasitic on Kola acuminata Schott & Endl, (Malvaceae), also known as Garcinia kola Heckel, (Clusiaceae).Methods: Compounds isolated through a combination of chromatographic techniques were screened for in vitro antioxidant potential using the diphenyl picrazyl hydrazine (DPPH) radical-based model. Cell viability at 1–1000 μM 3-MQ in 24 h was evaluated by 3-(4, 5-dimethylthiazol-2-yl)-2, 5- diphenyltetrazolium bromide (MTT) test. Lipopolysaccharide (LPS), phorbol 12-myristate 13-acetate (n = 5) five (5) replicates.Results: Ten (10) known compounds including 3-MQ (1) were isolated and characterized. 3-MQ exhibited highly significant (p < 0.05) antioxidant activity with 50 % inhibitory concentration (IC50) of 15.0 μM; concentrations ≤ 100 μM did not exert cytotoxic effect. 3-MQ, at 25 and 125 μM concentrations, significantly (p < 0.05) inhibited the production of TNF-α by 82 and 100 %, respectively, compared to controls.Conclusion: The results demonstrate the potent anti-inflammatory activity of 3-MQ and suggests its use as a potential alternative therapy for inflammation and related diseases.Keywords: Loranthus micranthus, Kola acuminata, Garcinia kola, Anti-inflammatory, Cytotoxicity, Chemiluminescence, Antioxidant, TNF-

Effect of Fermentation on the Anti-Nutritional Factors and

The effect of fermentation on the anti-nutritional factors and mineral composition of melon seed varieties for Ogiri production was studied. Melon seed varieties such as Citrullus vulgaris, Citrulluslanatus, Colocynthiscitrullus, Cucurbita pepo, Cucurmeropisedulis were respectively sorted, washed, boiled wrapped seed were then boiled again for 2 hours, drained, cooled and allowed to ferment naturally for 86 hours (primary fermentation). The primary fermented sees were then pounded and wrapped in little portions with “ofoala” leaf (Icacinatrichantha olive) and kept in wire mesh near a heat source for another 144 hours (secondary fermentation). Samples were drawn from the raw, boiled and fermented melon seed varieties for the quantitative analysis of mineral content and anti-nutritional prepared with the raw and primary fermented samples. Raw seed of Citrulluslanatus had the highest mineral analysis showed a decline in the boiled samples and secondary fermented sample, compared with the raw and mineral composition ranging from potassium, magnesium, cacium, iron and zinc of 1.21, 1.06, 0.89, 0.45 and 0.41mg/100g respectively followed by raw Citrullus Vulgaris with potassium, magenesium, calcium, iron and zinc of 1.18, 1.02, 0.55, 0.44 and 0.38 mg/100g respectively and 1.11, 0.94, 0.81, 0.38 and 0.31 mg/100gof potassium, magenesium, calcium, iron and zinc respectively in the primary fermented product. Statistical analysis of anti-nutrients revealed a significant reduction (p<0.05) in all the processed melon. There was a significant difference in all the processed melon with lowest anti-nutrient content ranging from alkaloid, saponin, HCN, phytate, tannin and flavonoid (0.00, 0.00, 0.00, 0.00, 0.03and 0.09 respectively) and Colocynthiscitrullus had the highest anti-nutrient content in the secondary fermentation. Keywords:Fermentation, anti-nutritional factors, Ogiri, mineral content,melon seed varieties

Organic Matter Management for Sustainable Tropical Crop Production.

Organic matter exerts a profound influence on crop nutrition, soil structure and cultivation.  Healthy soil is the foundation of the food system. It produces healthy crops that in turn nourish people. Maintaining a healthy soil demands care and effort from farmers of which organic matter management is viewed as central to the finest scale approaches used to assess the sustainability of soil systems. Nutrient exchanges   between organic matter, water and soil are essential to soil fertility and need to be maintained for sustainable production purposes  Agricultural development and production is sustainable when it is ecologically sound, economically viable, socially just, culturally appropriate, humane and based on a holistic scientific approach. This means that sustainable agriculture and rural development including forestry and fisheries must meet the nutritional requirements and other human needs of present and future generations, provide durable and decent employment and where possible enhance the productivity and regenerative capacity of the natural resource base, reduce vulnerability and strengthen self reliance.   It is obvious and  certain that where the soil is exploited for crop production without restoring the organic matter and nutrient content of the soil and maintaining a good structure, the nutrient cycles are broken, soil fertility declines and the balance in the agro-ecosystem is destroyed.

A study on the composition of heavy organic precipitates at various locations of a petroleum production line: wellhead, separator, and flowline

The heavy fractions from crude oil samples from different locations of a petroleum production line was investigated by gravimetric precipitation technique through the varying of n-alkane precipitant(s) type, volume, and volume ratios. The type of heavy organics (HOs) obtained at the different locations was studied using chromatographic fractionation into saturates, aromatics, resins and residual asphaltenes. Saturates and aromatics compositions were qualitatively and quantitatively determined by Gas Chromatographic-Flame Ionization Detection (GC-FID), while Ultraviolet-Visible spectroscopy was used for the resins. The results obtained show that the amounts of HOs precipitated changes with precipitants type, volume, and volume ratios and are in the order: wellhead (WH) > flowline (FL) > separator (SR). With changes in the total volume of precipitant binary mixtures, maximum precipitation is obtained at 40 mL/g of oil. Between 70–80 mL/g of oil, the amount of precipitate produced remain constant for all samples. There is no clear-cut trend in the concentration of individual and total saturate and aromatic compositions of the heavy organics along the different locations of the production system. However, the concentration of resins increases in the order: separator > flowline > wellhead

Achievement of therapeutic antibiotic exposures using Bayesian dosing software in critically unwell children and adults with sepsis

PURPOSE: Early recognition and effective treatment of sepsis improves outcomes in critically ill patients. However, antibiotic exposures are frequently suboptimal in the intensive care unit (ICU) setting. We describe the feasibility of the Bayesian dosing software Individually Designed Optimum Dosing Strategies (ID-ODS™), to reduce time to effective antibiotic exposure in children and adults with sepsis in ICU. METHODS: A multi-centre prospective, non-randomised interventional trial in three adult ICUs and one paediatric ICU. In a pre-intervention Phase 1, we measured the time to target antibiotic exposure in participants. In Phase 2, antibiotic dosing recommendations were made using ID-ODS™, and time to target antibiotic concentrations were compared to patients in Phase 1 (a pre-post-design). RESULTS: 175 antibiotic courses (Phase 1 = 123, Phase 2 = 52) were analysed from 156 participants. Across all patients, there was no difference in the time to achieve target exposures (8.7 h vs 14.3 h in Phase 1 and Phase 2, respectively, p = 0.45). Sixty-one courses in 54 participants failed to achieve target exposures within 24 h of antibiotic commencement (n = 36 in Phase 1, n = 18 in Phase 2). In these participants, ID-ODS™ was associated with a reduction in time to target antibiotic exposure (96 vs 36.4 h in Phase 1 and Phase 2, respectively, p < 0.01). These patients were less likely to exhibit subtherapeutic antibiotic exposures at 96 h (hazard ratio (HR) 0.02, 95% confidence interval (CI) 0.01-0.05, p < 0.01). There was no difference observed in in-hospital mortality. CONCLUSIONS: Dosing software may reduce the time to achieve target antibiotic exposures. It should be evaluated further in trials to establish its impact on clinical outcomes

Imagining an Imperial Modernity: Universities and the West African Roots of Colonial Development

© 2016 Informa UK Limited, trading as Taylor & Francis GroupThis article takes the formation and work of the ‘Elliot’ Commission on Higher Education in West Africa (1943–45) to reconsider the roots of British colonial development. Late colonial universities were major development projects, although they have rarely been considered as such. Focusing particularly on the Nigerian experience and the controversy over Yaba Higher College (founded 1934), the article contends that late colonial plans for universities were not produced in Britain and then exported to West African colonies. Rather, they were formed through interactions between agendas and ideas with roots in West Africa, Britain and elsewhere. These debates exhibited asymmetries of power but produced some consensus about university development. African and British actors conceptualised modern education by combining their local concerns with a variety of supra-local geographical frames for development, which included the British Empire and the individual colony. The British Empire did not in this case forestall development, but shaped the ways in which development was conceived