Ground-States of Two Directed Polymers

Joint ground states of two directed polymers in a random medium are investigated. Using exact min-cost flow optimization the true two-line ground-state is compared with the single line ground state plus its first excited state. It is found that these two-line configurations are (for almost all disorder configurations) distinct implying that the true two-line ground-state is non-separable, even with 'worst-possible' initial conditions. The effective interaction energy between the two lines scales with the system size with the scaling exponents 0.39 and 0.21 in 2D and 3D, respectively.Comment: 19 pages RevTeX, figures include

Nonequilibrium steady states of driven magnetic flux lines in disordered type-II superconductors

We investigate driven magnetic flux lines in layered type-II superconductors subject to various configurations of strong point or columnar pinning centers by means of a three-dimensional elastic line model and Metropolis Monte Carlo simulations. We characterize the resulting nonequilibrium steady states by means of the force-velocity / current-voltage curve, static structure factor, mean vortex radius of gyration, number of double-kink and half-loop excitations, and velocity / voltage noise spectrum. We compare the results for the above observables for randomly distributed point and columnar defects, and demonstrate that the three-dimensional flux line structures and their fluctuations lead to a remarkable variety of complex phenomena in the steady-state transport properties of bulk superconductors.Comment: 23 pages, IOP style, 18 figures include

The role of epoxyeicosatrienoic acids in the cardiovascular system.

There is increasing evidence suggesting that epoxyeicosatrienoic acids (EETs) play an important role in cardioprotective mechanisms. These include regulating vascular tone, modulating inflammatory responses, improving cardiomyocyte function and reducing ischaemic damage, resulting in attenuation of animal models of cardiovascular risk factors. This review discusses the current knowledge on the role of EETs in endothelium-dependent control of vascular tone in the healthy and in subjects with cardiovascular risk factors, and considers the pharmacological potential of targeting this pathway.Dr. Lucy Yang is funded by the Wellcome Trust TMAT programme, the Sackler fellowship, and Clare College Research Expenses Fund. Professor Ian Wilkinson and Dr. Joseph Cheriyan are both funded by the Cambridge Biomedical Research Centre. Professor Ian Wilkinson and Dr. Carmel McEniery are both funded by the British Heart Foundation.This is the final version of the article. It first appeared from Wiley via http://dx.doi.org/10.1111/bcp.1260

Collective roughening of elastic lines with hard core interaction in a disordered environment

We investigate by exact optimization methods the roughening of two and three-dimensional systems of elastic lines with point disorder and hard-core repulsion with open boundary conditions. In 2d we find logarithmic behavior whereas in 3d simple random walk-like behavior. The line 'forests' become asymptotically completely entangled as the system height is increased at fixed line density due to increasing line wandering

First measurements of the number size distribution of 1-2nm aerosol particles released from manufacturing processes in a cleanroom environment

This study was conducted to observe a potential formation and/or release of aerosol particles related to manufacturing processes inside a cleanroom. We introduce a novel technique to monitor airborne sub 2nm particles in the cleanroom and present results from a measurement campaign during which the total particle number concentration (>1nm and >7 nm) and the size resolved concentration in the 1 to 2nm size range were measured. Measurements were carried out in locations where atomic layer deposition (ALD), sputtering, and lithography processes were conducted, with a wide variety of starting materials. During our campaign in the clean room, we observed several time periods when the particle number concentration was 10(5) cm(-3) in the sub 2nm size range and 10(4) cm(-3) in the size class larger than 7nm in one of the sampling locations. The highest concentrations were related to the maintenance processes of the manufacturing machines, which were conducted regularly in that specific location. Our measurements show that around 500cm(-3) sub 2nm particles or clusters were in practice always present in this specific cleanroom, while the concentration of particles larger than 2nm was less than 2cm(-3). During active processes, the concentrations of sub 2nm particles could rise to over 10(5) cm(-3) due to an active new particle formation. The new particle formation was most likely induced by a combination of the supersaturated vapors, released from the machines, and the very low existing condensation sink, leading to pretty high formation rates J(1.4 nm) = (9 4) cm(-3) s(-1) and growth rates of particles (GR(1.1-1.3 nm) = (6 +/- 3) nm/h and GR(1.3-1.8 nm) = (14 +/- 3) nm/h).Copyright (c) 2017 American Association for Aerosol ResearchPeer reviewe

Production of neutral molecular clusters by controlled neutralization of mobility standards

Measuring aerosols and molecular clusters below the 3 nm size limit is essential to increase our understanding of new particle formation. Instruments for the detection of sub-3 nm aerosols and clusters exist and need to be carefully calibrated and characterized. So far calibrations and laboratory tests have been carried out using mainly electrically charged aerosols, as they are easier to handle experimentally. However, the charging state of the cluster is an important variable to take into account. Furthermore, instrument characterization performed with charged aerosols could be biased, preventing a correct interpretation of data when electrically neutral sub-3 nm aerosols are involved. This article presents the first steps to generate electrically neutral molecular clusters as standards for calibration. We show two methods: One based on the neutralization of well-known molecular clusters (mobility standards) by ions generated in a switchable aerosol neutralizer. The second is based on the controlled neutralization of mobility standards with mobility standards of opposite polarity in a recombination cell. We highlight the challenges of these two techniques and, where possible, point out solutions. In addition, we give an outlook on the next steps toward generating well-defined neutral molecular clusters with a known chemical composition and concentration.Peer reviewe

Ion production rate in a boreal forest based on ion, particle and radiation measurements

International audienceIn this study the ion production rates in a boreal forest were studied based on two different methods: 1) cluster ion and particle concentration measurements, 2) external radiation and radon concentration measurements. Both methods produced reasonable estimates for ion production rates. The average ion production rate calculated from aerosol particle size distribution and air ion mobility distribution measurements was 2.6 ion pairs cm-3s-1, and based on external radiation and radon measurements, 4.5 ion pairs cm-3s-1. The first method based on ion and particle measurements gave lower values for the ion production rates especially during the day. A possible reason for this is that particle measurements started only from 3nm, so the sink of small ions during the nucleation events was underestimated. It may also be possible that the hygroscopic growth factors of aerosol particles were underestimated. Another reason for the discrepancy is the nucleation mechanism itself. If the ions are somehow present in the nucleation process, there could have been an additional ion sink during the nucleation days

Onset of photosynthesis in spring speeds up monoterpene synthesis and leads to emission bursts

Emissions of biogenic volatile organic compounds (BVOC) by boreal evergreen trees have strong seasonality, with low emission rates during photosynthetically inactive winter and increasing rates towards summer. Yet, the regulation of this seasonality remains unclear. We measured in situ monoterpene emissions from Scots pine shoots during several spring periods and analysed their dynamics in connection with the spring recovery of photosynthesis. We found high emission peaks caused by enhanced monoterpene synthesis consistently during every spring period (monoterpene emission bursts, MEB). The timing of the MEBs varied relatively little between the spring periods. The timing of the MEBs showed good agreement with the photosynthetic spring recovery, which was studied with simultaneous measurements of chlorophyll fluorescence, CO2 exchange and a simple, temperature history-based proxy for state of photosynthetic acclimation, S. We conclude that the MEBs were related to the early stages of photosynthetic recovery, when the efficiency of photosynthetic carbon reactions is still low whereas the light harvesting machinery actively absorbs light energy. This suggests that the MEBs may serve a protective functional role for the foliage during this critical transitory state and that these high emission peaks may contribute to atmospheric chemistry in the boreal forest in springtime. Emissions of biogenic volatile organic compounds (BVOC) by boreal evergreen trees have strong seasonality. We measured high emission peaks from Scots pine shoots caused by enhanced monoterpene synthesis taking place simultaneously with the photosynthetic spring recovery. We conclude that the increased emissions were related to the photosynthetic recovery, when the efficiency of photosynthetic carbon reactions is low whereas the light harvesting machinery actively absorbs light energy. Increased emissions may serve a protective functional role for the foliage during the transitory state, and these high emission peaks may contribute to atmospheric chemistry in the boreal forest in springtime.Peer reviewe

Path independent integrals to identify localized plastic events in two dimensions

We use a power expansion representation of plane elasticity complex potentials due to Kolossov and Muskhelishvili, to compute the elastic fields induced by a localized plastic deformation event. Far from its center, the dominant contributions correspond to first order singularities of quadrupolar and dipolar symmetry which can be associated respectively to pure deviatoric and pure volumetric plastic strain of an equivalent circular inclusion. Constructing holomorphic functions from the displacement field and its derivatives, it is possible to define path independent Cauchy integrals which capture the amplitudes of these singularities. Analytical expressions and numerical tests on simple finite element data are presented. The development of such numerical tools is of direct interest for the identification of local structural reorganizations which are believed to be the key mechanisms for plasticity of amorphous materials

Aerosol charging state at an urban site: new analytical approach and implications for ion-induced nucleation

The charging state of aerosol populations was determined using an Ion-DMPS in Helsinki, Finland between December 2008 and February 2010. We extrapolated the charging state and calculated the ion-induced nucleation fraction to be around 1.3 % ± 0.4 % at 2 nm and 1.3 % ± 0.5 % at 1.5 nm, on average. We present a new method to retrieve the average charging state for a new particle formation event, at a given size and polarity. We improve the uncertainty assessment and fitting technique used previously with an Ion-DMPS. We also use a new theoretical framework that allows for different concentrations of small ions for different polarities (polarity asymmetry). We extrapolate the ion-induced fraction using polarity symmetry and asymmetry. Finally, a method to calculate the growth rates from the behaviour of the charging state as a function of the particle diameter using polarity symmetry and asymmetry is presented and used on a selection of new particle formation events