Molecular origin of enhanced proton conductivity in anhydrous ionic systems

YesIonic systems with enhanced proton conductivity are widely viewed as promising electrolytes in fuel cells and batteries. Nevertheless, a major challenge toward their commercial applications is determination of the factors controlling the fast proton hopping in anhydrous conditions. To address this issue, we have studied novel proton-conducting materials formed via a chemical reaction of lidocaine base with a series of acids characterized by a various number of proton-active sites. From ambient and high pressure experimental data, we have found that there are fundamental differences in the conducting properties of the examined salts. On the other hand, DFT calculations revealed that the internal proton hopping within the cation structure strongly affects the pathways of mobility of the charge carrier. These findings offer a fresh look on the Grotthuss-type mechanism in protic ionic glasses as well as provide new ideas for the design of anhydrous materials with exceptionally high proton conductivity

The structure and magnetic properties of rapidly quenched Fe72Ni8Nb4Si2B14 alloy

PING 2019 is organized with the support of funds for specific university research project SVK1-2019-002.In this work, the influence of heat treatment process on structure and magnetic properties for rapidly quenched Fe72Ni8Nb4Si2B14 alloy are reported. Firstly, for amorphous ribbons the onsets of crystallization process for bcc-Fe type phase (primary crystallization) and bct-Fe3B type phase (secondary crystallization) are defined by thermal analysis using heating rate of 10°C/min. Then basing on measured values the classical heat treatment process (with heating rate 10°C/min) in vacuum for wound toroidal cores is optimized to obtain best soft magnetic properties (B(H) dependencies and magnetic core loss Ps) at frequency 50 Hz. For heat treated samples the X-ray diffraction method is used to determine the unit cell parameters of bcc-Fe type nanocrystallites as well as their average crystallite size. Therefore, for optimal heat treated sample the complex magnetic permeability in the frequencies 106 -109 Hz for temperature range from -50°C to 100°C is measured and in the frequencies 104 -108 Hz at room temperature

Magnetocaloric Properties of Mn1.1Fe0.9P0.5As0.5−xGex (0 ≤ x ≤ 0.1) Compounds

Intermetallic compounds with the overall formula Mn1.1Fe0.9P0.5As0.5-xGex (x varies from 0 to 0.1) were investigated in order to study their magnetocaloric effect by monitoring the adiabatic temperature change, magnetic entropy change and their relation to structural parameters. It was found that the maximum of magnetocaloric effect was achieved for x = 0.02. Adiabatic temperature change for consolidated powder was equal to 2.75 K for the magnetic field change ΔB = 1.7 T for the sample with x = 0.02. For the pure non-doped sample, this parameter is much lower: ΔTad = 1.7 K @ ΔB = 1.7 T. This result was correlated with the change of structural parameters such as lattice constants and the unit cell volume

Influence of Cu Content on Structure and Magnetic Properties in Fe86-xCuxB14 Alloys

Influence of Cu content on thermodynamic parameters (configurational entropy, Gibbs free energy of mixing, Gibbs free energy of amorphous phase formation), crystallization kinetics, structure and magnetic properties of Fe86-xCuxB14 (x = 0, 0.4, 0.55, 0.7, 1) alloys is investigated. The chemical composition has been optimized using a thermodynamic approach to obtain a minimum of Gibbs free energy of amorphous phase formation (minimum at 0.55 at.% of Cu). By using differential scanning calorimetry method the crystallization kinetics of amorphous melt-spun ribbons was analyzed. It was found that the average activation energy of α-Fe phase crystallization is in the range from 201.8 to 228.74 kJ/mol for studied samples. In order to obtain the lowest power core loss values, the isothermal annealing process was optimized in the temperature range from 260 °C to 400 °C. Materials annealed at optimal temperature had power core losses at 1 T/50 Hz—0.13–0.25 W/kg, magnetic saturation—1.47–1.6 T and coercivity—9.71–13.1 A/m. These samples were characterized by the amorphous structure with small amount of α-Fe nanocrystallites. The studies of complex permeability allowed to determine a minimum of both permeability values at 0.55 at.% of Cu. At the end of this work a correlation between thermodynamic parameters and kinetics, structure and magnetic properties were described

Effect of processing parameters on microstructure and properties of CuSn10P1 alloy fabricated by SLM

PING 2019 is organized with the support of funds for specific university research project SVK1-2019-002.The interest in Cu-Sn alloys is associated with excellent flexibility, wear and corrosion resistance, and high mechanical strength. CuSn10P1 alloy has the widest applications among Cu-Sn alloys and is widely used in the shaft sleeve, bearing, gears, valves, etc. The properties of this alloy are strongly depended to the manufacturing process. Usage of the traditional casting causes the intergranular segregation and crystallization of primary α-Cu phase in a coarse mesh dendritic structure. This, in turn, manifest itself in poor properties, limiting its uses in industry. According to that new manufacturing methods should be used to improve the properties of this alloy. In this work, CuSn10P1 alloy was successfully produced using selective laser melting (SLM). The powder size was between 20-63 µm and its humidity during the process was lower than 5%. The four printing strategies were selected to investigate the impact of printing parameters on the microstructure and mechanical properties of the prints. The optimal processing conditions were chosen on the basis of optimization of laser power and scanning speed. The different process parameters result in the changes of the microstructure, especially porosity and the presence of microcracks. On the basis of the analysis of wavelength-dispersive X-ray spectroscopy, it was confirmed, that all chemical elements are evenly distributed after selective laser melting. The segregation of tin and copper can be also observed, however only under remelting of the same layer

Influence of Cu Content on Structure, Thermal Stability and Magnetic Properties in Fe72−xNi8Nb4CuxSi2B14 Alloys

The effect of substitution of Fe by Cu on the crystal structure and magnetic properties of Fe72−xNi8Nb4CuxSi2B14 alloys (x = 0.6, 1.1, 1.6 at.%) in the form of ribbons was investigated. The chemical composition of the materials was established on the basis of the calculated minima of thermodynamic parameters: Gibbs free energy of amorphous phase formation ΔGamorph (minimum at 0.6 at.% of Cu) and Gibbs free energy of mixing ΔGmix (minimum at 1.6 at.% of Cu). The characteristic crystallization temperatures Tx1onset and Tx1 of the alpha-iron phase together with the activation energy Ea for the as-spun samples were determined by differential scanning calorimetry (DSC) with a heating rate of 10–100 °C/min. In order to determine the optimal soft magnetic properties, the wound cores were subjected to a controlled isothermal annealing process in the temperature range of 340–640 °C for 20 min. Coercivity Hc, saturation induction Bs and core power losses at B = 1 T and frequency f = 50 Hz P10/50 were determined for all samples. Moreover, for the samples with the lowest Hc and P10/50, the magnetic losses were determined in a wider frequency range 50 Hz–400 kHz. The real and imaginary parts of the magnetic permeability µ′, µ″ along with the cut-off frequency were determined for the samples annealed at 360, 460, and 560 °C. The best soft magnetic properties (i.e., the lowest value of Hc and P10/50) were observed for samples annealed at 460 °C, with Hc = 4.88–5.69 A/m, Bs = 1.18–1.24 T, P10/50 = 0.072–0.084 W/kg, µ′ = 8350–10,630 and cutoff frequency at 8–9.3 × 104 Hz. The structural study of as-spun and annealed ribbons was carried out using X-ray diffraction (XRD) and a transmission electron microscope (TEM)

Effect of Co Substitution and Thermo-Magnetic Treatment on the Structure and Induced Magnetic Anisotropy of Fe84.5−xCoxNb5B8.5P2 Nanocrystalline Alloys

In the present work, we investigated in detail the thermal/crystallization behavior and magnetic properties of materials with Fe84.5-xCoxNb5B8.5P2 (x = 0, 5, 10, 15 and 20 at.%) composition. The amorphous ribbons were manufactured on a semi-industrial scale by the melt-spinning technique. The subsequent nanocrystallization processes were carried out under different conditions (with/without magnetic field). The comprehensive studies have been carried out using differential scanning calorimetry, X-ray diffractometry, transmission electron microscopy, hysteresis loop analyses, vibrating sample magnetometry and Mössbauer spectroscopy. Moreover, the frequency (up to 300 kHz) dependence of power losses and permeability at a magnetic induction up to 0.9 T was investigated. On the basis of some of the results obtained, we calculated the values of the activation energies and the induced magnetic anisotropies. The X-ray diffraction results confirm the surface crystallization effect previously observed for phosphorous-containing alloys. The in situ microscopic observations of crystallization describe this process in detail in accordance with the calorimetry results. Furthermore, the effect of Co content on the phase composition and the influence of annealing in an external magnetic field on magnetic properties, including the orientation of the magnetic spins, have been studied using various magnetic techniques. Finally, nanocrystalline Fe64.5Co20Nb5B8.5P2 cores were prepared after transverse thermo-magnetic heat treatment and installed in industrially available portable heating equipment

Fe-Co-B Soft Magnetic Ribbons: Crystallization Process, Microstructure and Coercivity

In this work, a detailed microstructural investigation of as-melt-spun and heat-treated Fe67Co20B13 ribbons was performed. The as-melt-spun ribbon was predominantly amorphous at room temperature. Subsequent heating demonstrated an amorphous to crystalline α-(Fe,Co) phase transition at 403 °C. In situ transmission electron microscopy observations, carried out at the temperature range of 25–500 °C and with the heating rate of 200 °C/min, showed that the first crystallized nuclei appeared at a temperature close to 370 °C. With a further increase of temperature, the volume of α-(Fe,Co) crystallites considerably increased. Moreover, the results showed that a heating rate of 200 °C/min provides for a fine and homogenous microstructure with the α-(Fe,Co) crystallites size three times smaller than when the ribbon is heated at 20 °C/min. The next step of this research concerned the influence of both the annealing time and temperature on the microstructure and coercivity of the ribbons. It was shown that annealing at 485 °C for a shorter time (2 s) led to materials with homogenous distribution of α-(Fe,Co) crystallites with a mean size of 30 nm dispersed in the residual amorphous matrix. This was reflected in the coercivity (20.5 A/m), which significantly depended on the volume fraction of crystallites, their size, and distribution