146 research outputs found
Electrical conductivity of carbon nanofiber reinforced resins: potentiality of Tunneling Atomic Force Microscopy (TUNA) technique
Epoxy nanocomposites able to meet pressing industrial requirements in the
field of structural material have been developed and characterized. Tunneling
Atomic Force Microscopy (TUNA), which is able to detect ultra-low currents
ranging from 80 fA to 120 pA, was used to correlate the local topography with
electrical properties of tetraglycidyl methylene dianiline (TGMDA) epoxy
nanocomposites at low concentration of carbon nanofibers (CNFs) ranging from
0.05% up to 2% by wt. The results show the unique capability of TUNA technique
in identifying conductive pathways in CNF/resins even without modifying the
morphology with usual treatments employed to create electrical contacts to the
ground
Effect of electric field polarization and temperature on the effective permittivity and conductivity of porous anodic aluminium oxide membranes
Porous insulators offer new opportunities for the controlled guestâhost synthesis of nanowires for future integrated circuits characterized by low propagation delay, crosstalk and power consumption. We propose a method to estimate the effect of the electric field polarization and temperature on the electrical properties of different types of synthesized porous anodic aluminium oxide membranes. It results that the effective permittivity along the pore axis is generally 20% higher than the one in the orthogonal direction. The type of solution and the voltage level applied during anodization are the main parameters affecting the AAO templates characteristics, i.e. their porosity and chemical content. The values of permittivity of the final material, are typically in the range 2.6â3.2 for large pore diameter membranes including phosphorus element and having a low water content, and in the range 3.5â4 for the ones with smaller pores, and showing sulphur element incorporation. Moreover, the dc conductivity of the different membranes appears to be correlated to the pore density
Electrical conductivity of carbon nanofiber reinforced resins: Potentiality of Tunneling Atomic Force Microscopy (TUNA) technique
Epoxy nanocomposites able to meet pressing industrial requirements in the
field of structural material have been developed and characterized. Tunneling
Atomic Force Microscopy (TUNA), which is able to detect ultra-low currents
ranging from 80 fA to 120 pA, was used to correlate the local topography with
electrical properties of tetraglycidyl methylene dianiline (TGMDA) epoxy
nanocomposites at low concentration of carbon nanofibers (CNFs) ranging from
0.05% up to 2% by wt. The results show the unique capability of TUNA technique
in identifying conductive pathways in CNF/resins even without modifying the
morphology with usual treatments employed to create electrical contacts to the
ground
An integrated proteomic and physiological approach to understand the adhesion mechanism of the probiotic Lactobacillus reuteri Lb2 BM DSM 16143
The role of carbon nanofiber defects on the electrical and mechanical properties of CNF-based resins
Heat treatment of carbon nanofibers has proven to be an effective method in removing defects from carbon nanofibers, causing a strong increase in their structural perfection and thermal stability. It affects the bonding states of carbon atoms in the nanofiber structure and causes a significant transformation in the hybridization state of the bonded carbon atoms.Nanofilled resins made of heat-treated CNF show significant increases in their electrical conductivity even at low concentrations. This confirms that enhancement in the perfection of the fiber structure with consequent change in the morphological features plays a prominent role in affecting the electrical properties. Indeed heat-treated CNFs display a stiff structure and a smooth surface which tends to lower the thickness of the unavoidable insulating epoxy layer formed around the CNF which, in turn, plays a fundamental role in the electrical transport properties along the conducting clusters. This might be very beneficial in terms of electrical conductivity but might have negligible effect on the mechanical properties
Study of the Electric Spark and Combustion Characteristic Times in a Mike 3 Apparatus
Understanding how dust can ignite and explode in an industrial contest is an important and complex task, and much of the work around this is mainly performed via experimental measurements, in accordance to specific standards. However, those same properties are straightforwardly closely related to the nature of the experimental tests. Among these, the Minimum Ignition Energy (MIE) of a dust cloud, that is usually measured in a MIKE 3 apparatus, can be affected by several factors, as: delay time of the electric spark with respect to the dust-air dispersion formation inside the apparatus, dust concentration, humidity content, dust granulometry, etc. The delay time is one of the worst parameters to adjust, because the fluid-dynamics of the dust-air mixture inside the tube is not easily predictable. Within this work, a study on the characteristic times of all the relevant phenomena occurring within a MIKE 3 apparatus was done by means of slow-motion videos of the tests. Particularly, three different characteristic times were compared referring to a given sample of niacin dust: dust lifting and settling times, effective spark delay time (that is, the time at which the spark is visible) and combustion time (that is, the time at which the flame is visible). According to the results, the effective delay time is almost always quite different with respect to the theoretical one, influencing the effective concentration of dust between the electrodes and, finally, the possibility to have a flame ignition or not within the apparatus. This means that the value of the MIE parameter can be profoundly influenced by the effective delay.
Keywords: Process Safety; Dust Explosions; Minimum Ignition Energy; Spark Dela
Optimization of Graphene-Based Materials Outperforming Host Epoxy Matrices
The degree of graphite exfoliation and edge-carboxylated layers can be controlled and balanced to design lightweight materials characterized by both low electrical percolation thresholds (EPT) and improved mechanical properties. So far, this challenging task has been undoubtedly very hard to achieve.
The results presented in this paper highlight the effect of exfoliation degree and the role of edge-carboxylated graphite layers to give self-assembled structures embedded in the polymeric matrix. Graphene layers inside the matrix may serve as building blocks of complex systems that could outperform the host matrix. Improvements in electrical percolation and mechanical performance have been obtained by a synergic effect due to finely balancing the degree of exfoliation and the chemistry of graphene edges which favors the interfacial interaction between polymer and carbon layers.
In particular, for epoxy-based resins including two partially exfoliated graphite samples, differing essentially in the content of carboxylated groups, the percolation threshold reduces from 3 wt% down to 0.3 wt%, as the carboxylated group content increases up to 10 wt%. Edge-carboxylated nanosheets also increase the nanofiller/epoxy matrix interaction, determining a relevant reinforcement in the elastic modulus
Studies on potential agents of mastitis in udders from small ruminants regularly slaughtered in Piemonte Region, North-Western Italy (part I): microbiological and pathological findings
Studies on potential agents of mastitis in udders from small ruminants regularly slaughtered in Piemonte Region, North-Western Italy (part II): evaluation of antimicrobial resistance
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