Li intercalation effects on magnetism in undoped and Co-doped anatase TiO2_2

The effects of $n$-type carrier doping by Li intercalation on magnetism in undoped and Co-doped anatase TiO$_2$ are investigated. We have found that doped $n$-type carriers in TiO$_2$ are localized mainly at Ti sites near the intercalated Li. With increasing the intercalation, local spins are realized at Ti. In the case of Co-doped TiO$_2$, most of the added $n$-type carriers fill the Co 3$d$ bands and the rest are localized at Ti. Therefore, Co magnetic moment vanishes by Li intercalation to have a nonmagnetic ground state.Comment: 6 pages, 2 figures, to appear in a special issue of Physica B, proceedings of the 2nd Hiroshima Workshop on Transport and Thermal Properties of Advanced Materials (Aug. 2002; Hiroshima, Japan

Overcharging of a macroion by an oppositely charged polyelectrolyte

The complexation of a polyelectrolyte with an oppositely charged spherical macroion is studied for both salt free and salty solutions. When a polyelectrolyte winds around the macroion, its turns repel each other and form an almost equidistant coil. It is shown that this repulsive correlations of turns lead to the charge inversion: more polyelectrolyte winds around the macroion than it is necessary to neutralize it. The charge inversion becomes stronger with increasing concentration of salt and can exceed 100%. This paper confirms that correlations are the universal mechanism of charge inversion.Comment: Monte-Carlo simulation details added. Many corrections and references added. Accepted to Physica

Internationalisation of Chinese SMEs: The Role of Networks and Global Value Chains

This article examines the role of networks and global value chains (GVCs), and how they influence emerging economy small and medium enterprises’ (EE-SMEs) internationalisation. Drawing on the insights, experiences and perspectives of entrepreneurs and senior managers of SMEs that have originated from China, the study adopts qualitative approach and examines nine firms’ internationalisation. We find that Chinese born-global manufacturing SMEs benefit from networks with quick insidership position into GVCs, but suffer from various obstacles that hinder their further development. The findings further indicate that network ties substantially facilitate EE-SMEs’ internationalisation, but also restrict their future global development, as their low position within the GVCs impedes further business development and capability building. The case firms’ lower position within the GVCs weakens the networks’ influence on their GVC upgrading. The research identifies key enablers of GVCs engagement and obstacles of GVCs upgrading of the case firms which play an important role in the EE-SMEs’ internationalisation

Inversion of DNA charge by a positive polymer via fractionalization of the polymer charge

Charge inversion of a DNA double helix by an oppositely charged flexible polyelectrolyte (PE) is widely used for gene delivery. It is considered here in terms of discrete charges of DNA. We concentrate on the worst scenario case when in the neutral state of the DNA-PE complex, each of the DNA charges is locally compensated by a PE charge and show that charge inversion exists even in this case. When an additional PE molecule is adsorbed by DNA, its charge gets fractionalized into monomer charges of defects (tails and arches) on the background of the perfectly neutralized DNA. These charges spread all over the DNA eliminating the self-energy of PE. Fractionalization leads to a substantial charge inversion of DNA. We show that fractionalization mechanism charge inversion works also for nonlinear polymers such as dendrimers. Remarkably, such fractionalization happens for adsorption of both PE or dendrimers on a two-dimensional charged lattice, as well. Relation of fractionalization to other mechanisms of charge inversion is discussed.Comment: Accepted for publication in Physica

Masses of composite fermions carrying two and four flux quanta: Differences and similarities

This study provides a theoretical rationalization for the intriguing experimental observation regarding the equality of the normalized masses of composite fermions carrying two and four flux quanta, and also demonstrates that the mass of the latter type of composite fermion has a substantial filling factor dependence in the filling factor range $4/17 > \nu > 1/5$, in agreement with experiment, originating from the relatively strong inter-composite fermion interactions here.Comment: 5 pages, 2 figure

Beyond paired quantum Hall states: parafermions and incompressible states in the first excited Landau level

The Pfaffian quantum Hall states, which can be viewed as involving pairing either of spin-polarized electrons or of composite fermions, are generalized by finding the exact ground states of certain Hamiltonians with k+1-body interactions, for all integers k > 0. The remarkably simple wavefunctions of these states involve clusters of k particles, and are related to correlators of parafermion currents in two-dimensional conformal field theory. The k=2 case is the Pfaffian. For k > 1, the quasiparticle excitations of these systems are expected to possess nonabelian statistics, like those of the Pfaffian. For k=3, these ground states have large overlaps with the ground states of the (2-body) Coulomb-interaction Hamiltonian for electrons in the first excited Landau level at total filling factors \nu=2+3/5, 2+2/5.Comment: 11 pages Revtex in two column format with 4 eps figures included in the M

Hamiltonian theory of gaps, masses and polarization in quantum Hall states: full disclosure

I furnish details of the hamiltonian theory of the FQHE developed with Murthy for the infrared, which I subsequently extended to all distances and apply it to Jain fractions \nu = p/(2ps + 1). The explicit operator description in terms of the CF allows one to answer quantitative and qualitative issues, some of which cannot even be posed otherwise. I compute activation gaps for several potentials, exhibit their particle hole symmetry, the profiles of charge density in states with a quasiparticles or hole, (all in closed form) and compare to results from trial wavefunctions and exact diagonalization. The Hartree-Fock approximation is used since much of the nonperturbative physics is built in at tree level. I compare the gaps to experiment and comment on the rough equality of normalized masses near half and quarter filling. I compute the critical fields at which the Hall system will jump from one quantized value of polarization to another, and the polarization and relaxation rates for half filling as a function of temperature and propose a Korringa like law. After providing some plausibility arguments, I explore the possibility of describing several magnetic phenomena in dirty systems with an effective potential, by extracting a free parameter describing the potential from one data point and then using it to predict all the others from that sample. This works to the accuracy typical of this theory (10 -20 percent). I explain why the CF behaves like free particle in some magnetic experiments when it is not, what exactly the CF is made of, what one means by its dipole moment, and how the comparison of theory to experiment must be modified to fit the peculiarities of the quantized Hall problem

Harmonic forcing of an extended oscillatory system: Homogeneous and periodic solutions

In this paper we study the effect of external harmonic forcing on a one-dimensional oscillatory system described by the complex Ginzburg-Landau equation (CGLE). For a sufficiently large forcing amplitude, a homogeneous state with no spatial structure is observed. The state becomes unstable to a spatially periodic ``stripe'' state via a supercritical bifurcation as the forcing amplitude decreases. An approximate phase equation is derived, and an analytic solution for the stripe state is obtained, through which the asymmetric behavior of the stability border of the state is explained. The phase equation, in particular the analytic solution, is found to be very useful in understanding the stability borders of the homogeneous and stripe states of the forced CGLE.Comment: 6 pages, 4 figures, 2 column revtex format, to be published in Phys. Rev.

Partially spin polarized quantum Hall effect in the filling factor range 1/3 < nu < 2/5

The residual interaction between composite fermions (CFs) can express itself through higher order fractional Hall effect. With the help of diagonalization in a truncated composite fermion basis of low-energy many-body states, we predict that quantum Hall effect with partial spin polarization is possible at several fractions between $\nu=1/3$ and $\nu=2/5$. The estimated excitation gaps are approximately two orders of magnitude smaller than the gap at $\nu=1/3$, confirming that the inter-CF interaction is extremely weak in higher CF levels.Comment: 4 pages, 3 figure

Spontaneous Pseudospin Spiral Order in Bilayer Quantum Hall Systems

Using exact diagonalization of bilayer quantum Hall systems at total filling factor $\nu_T=1$ in the torus geometry, we show that there is a new long-range interlayer phase coherence due to spontaneous pseudospin spiral order at interlayer distances larger than the critical value at which the pseudospin ferromagnetic order is destroyed. We emphasize the distinction between the interlayer phase coherence and the pseudospin ferromagnetic order.Comment: 6 pages, 4 figures, Replaced by a new extended version published in Phys. Rev.