11 research outputs found
Oxidative coupling of activated alkynes with palladium(0) olefin complexes: Side production of the highly symmetric hexamethyl mellitate species under mild conditions at low alkyne/complex molar ratios
Get PDFThe synthesis of palladacyclopentadienyl derivatives from rigid bis-alkynes and their use as precursors in the synthesis of fluoroanthene-like cycles under mild conditions. A reactivity investigation
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o-Isocyanobenzyl complexes of transition metals as novel organometallic isocyanide ligands, (.eta.5-C5H5)M(CO)3(o-CH2C6H4NC) (M = Mo, W) and Mn(CO)5(o-CH2C6H4NC). Synthesis and reactivity toward palladium(II) and platinum(II) substrates
No full textOrganometallic isocyanides of the general formula o-([M]CH2)C6H4NC ([M] = CpMo(CO)3, CpW(CO)3
(Cp = eta5-C6H5), Mn(CO)5) were prepared by reaction of o-(ICH2)C6H4NC with the corresponding metal
carbonyl anion
Mechanism of reductive elimination of 1,1,1-trifluoroethane from cis-hydrido(2,2,2-trifluoroethyl)bis(triphenylphosphine)platinum(II)
No full textMechanism of reductive elimination of 1,1,1-trifluoroethane from cis-hydrido(2,2,2-trifluoroethyl)bis(triphenylphosphine)platinum(II)
Dimerization reactions and monosubstituted derivatives of ruthenium tetracarbonyl dihalides
No full textRemarkable, Sterically Induced Rate Enhancement in the Insertion of Allenes into Palladium−Methyl Bonds
No full textPalladium(II) and Palladium(0) Complexes of Pyridylthioether-Based Metallodendrimers. Synthesis, Characterization, and Mechanistic Study of the Influence of Wedge Size on Allyl Amination
No full textSolution Behavior and X-ray Structure of Cationic Allylpalladium(II) Complexes with Iminophosphine Ligands. Kinetics and Mechanism of Allyl Amination by Secondary Amines
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