1,540 research outputs found

    The existence and stability of nonlinear wave equations

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    Second order nonlinear wave equation solution on Hilbert space with stability and uniquenes

    Photoconduction and the electronic structure of silica nanowires embedded with gold nanoparticles

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    [[abstract]]Silica nanowires (SiOx-NWs) embedded with Au peapods have been studied by energy-filtered scanning transmission electron microscopy (EFTEM), O K- and Au L3-edge x-ray absorption near-edge structure (XANES), and extended x-ray absorption fine structure (EXAFS), x-ray emission spectroscopy (XES) and scanning photoelectron microscopy. XANES and XES data show that band gaps of Au-peapod-embedded and pure SiOx-NWs were 6.8 eV. In additional, XANES and EXAFS results indicate illumination-induced electron transfer from Au peapod to SiOx-NWs and does not show any feature attributable to the formation of Au-Si bonding in the Au peapod embedded in SiOx-NWs with or without illumination. Photoresponse and EFTEM measurements show that green light has more significant enhancement of photoconductivity than red and blue light due to surface plasmon resonance and suggest that transport of electrons across SiOx-NWs is via Mott-variable-range hopping mechanism through localized or defect states.[[incitationindex]]SCI[[booktype]]紙

    Electeonic structures of group-III-nitride nanorods studied by x-ray absorption, x-ray emission, and Raman spectroscopy

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    [[abstract]]Nitrogen N and metal Al, Ga, and In K-edge x-ray absorption near-edge structure XANES , x-ray emission spectroscopy XES , and Raman scattering measurements were performed to elucidate the electronic structures of group-III–nitride nanorods and thin films of AlN, GaN, and InN. XANES spectra show slight increase of the numbers of unoccupied N p states in GaN and AlN nanorods, which may be attributed to a slight increase of the degree of localization of conduction band states. The band gaps of AlN, GaN, and InN nanorods are determined by an overlay of XES and XANES spectra to be 6.2, 3.5, and 1.9 eV, respectively, which are close to those of AlN and GaN bulk/films and InN polycrystals.[[notice]]補正完畢[[journaltype]]國外[[incitationindex]]SCI[[booktype]]紙本[[booktype]]電子版[[countrycodes]]US

    Hole Pockets in the Doped 2D Hubbard Model

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    The electronic momentum distribution n(k){\rm n({\bf k})} of the two dimensional Hubbard model is studied for different values of the coupling U/t{\rm U/t}, electronic density n{\rm \langle n \rangle}, and temperature, using quantum Monte Carlo techniques. A detailed analysis of the data on 8×88\times 8 clusters shows that features consistent with hole pockets at momenta k=(±π2,±π2){\rm {\bf k}=(\pm {\pi\over{2}},\pm {\pi\over{2}})} appear as the system is doped away from half-filling. Our results are consistent with recent experimental data for the cuprates discussed by Aebi et al. (Phys. Rev. Lett. {\bf 72}, 2757 (1994)). In the range of couplings studied, the depth of the pockets is maximum at n0.9{\rm \langle n \rangle \approx 0.9}, and it increases with decreasing temperature. The apparent absence of hole pockets in previous numerical studies of this model is explained.Comment: 11 pages, 4 postscript figures appended, RevTeX (version 3.0

    Mechanism of glycan receptor recognition and specificity switch for avian, swine, and human adapted influenza virus hemagglutinins: a molecular dynamics perspective.

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    Hemagglutinins (HA's) from duck, swine, and human influenza viruses have previously been shown to prefer avian and human glycan receptor analogues with distinct topological profiles, pentasaccharides LSTa (alpha-2,3 linkage) and LSTc (alpha-2,6 linkage), in comparative molecular dynamics studies. On the basis of detailed analyses of the dynamic motions of the receptor binding domains (RBDs) and interaction energy profiles with individual glycan residues, we have identified approximately 30 residue positions in the RBD that present distinct profiles with the receptor analogues. Glycan binding constrained the conformational space sampling by the HA. Electrostatic steering appeared to play a key role in glycan binding specificity. The complex dynamic behaviors of the major SSE and trimeric interfaces with or without bound glycans suggested that networks of interactions might account for species specificity in these low affinity and high avidity (multivalent) interactions between different HA and glycans. Contact frequency, energetic decomposition, and H-bond analyses revealed species-specific differences in HA-glycan interaction profiles, not readily discernible from crystal structures alone. Interaction energy profiles indicated that mutation events at the set of residues such as 145, 156, 158, and 222 would favor human or avian receptor analogues, often through interactions with distal asialo-residues. These results correlate well with existing experimental evidence, and suggest new opportunities for simulation-based vaccine and drug development

    Nitrogen-Functionalized Graphene Nanoflakes (GNFs:N): Tunable Photoluminescence and Electronic Structures

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    This study investigates the strong photoluminescence (PL) and X-ray excited optical luminescence observed in nitrogen-functionalized 2D graphene nanoflakes (GNFs:N), which arise from the significantly enhanced density of states in the region of {\pi} states and the gap between {\pi} and {\pi}* states. The increase in the number of the sp2 clusters in the form of pyridine-like N-C, graphite-N-like, and the C=O bonding and the resonant energy transfer from the N and O atoms to the sp2 clusters were found to be responsible for the blue shift and the enhancement of the main PL emission feature. The enhanced PL is strongly related to the induced changes of the electronic structures and bonding properties, which were revealed by the X-ray absorption near-edge structure, X-ray emission spectroscopy, and resonance inelastic X-ray scattering. The study demonstrates that PL emission can be tailored through appropriate tuning of the nitrogen and oxygen contents in GNFs and pave the way for new optoelectronic devices.Comment: 8 pages, 6 figures (including toc figure

    An integrated genomic analysis of lung cancer reveals loss of DUSP4 in EGFR-mutant tumors.

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    To address the biological heterogeneity of lung cancer, we studied 199 lung adenocarcinomas by integrating genome-wide data on copy number alterations and gene expression with full annotation for major known somatic mutations in this cancer. This showed non-random patterns of copy number alterations significantly linked to EGFR and KRAS mutation status and to distinct clinical outcomes, and led to the discovery of a striking association of EGFR mutations with underexpression of DUSP4, a gene within a broad region of frequent single-copy loss on 8p. DUSP4 is involved in negative feedback control of EGFR signaling, and we provide functional validation for its role as a growth suppressor in EGFR-mutant lung adenocarcinoma. DUSP4 loss also associates with p16/CDKN2A deletion and defines a distinct clinical subset of lung cancer patients. Another novel observation is that of a reciprocal relationship between EGFR and LKB1 mutations. These results highlight the power of integrated genomics to identify candidate driver genes within recurrent broad regions of copy number alteration and to delineate distinct oncogenetic pathways in genetically complex common epithelial cancers

    Drawing from Grotowski and Beyond: Kuo Pao Kun’s Discourse on Audiences in Singapore in the 1980s

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    Much has been researched on Kuo Pao Kun’s multilingualism and multiculturalism. However, as one of one of the most important Asian dramatists, the analysis of Kuo’s discourse on audiences remains largely unexplored. There is a pressing need to understand the ways which theatre practitioners imagine audiences as it points to issues of subjectivity, audience participation and social engagement, especially in a neoliberal society like Singapore where people are often positioned as docile economic subjects. Among the many Asian and Western dramatists Kuo drew inspiration from, Jerzy Grotowski was pivotal. This essay seeks to address this gap by examining how the latter’s ideas was crucial to understanding how Kuo envisioned theatre and audiences alongside his artistic practice
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