Nanocrystalline TiO2 and halloysite clay mineral composite films prepared by sol-gel method:Synergistic effect and the case of silver modification to the photocatalytic degradation of basic blue- 41 azo dye in water

Tubular halloysite clay mineral and nanocrystalline TiO2 were incorporated in the preparation of nanocomposite films on glass substrates via sol-gel method at 450 °C. The synthesis involves a simple chemical method employing nonionic surfactant molecule as pore directing agent along with the acetic acid-based sol-gel route without addition of water molecules. Drying and thermal treatment of composite films ensure elimination of organic material and lead to the formation of TiO2 nanoparticles homogeneously distributed on the surface of the halloysite. Nanocomposite films without cracks of active anatase crystal phase and small crystallite size on halloysite nanotubes are characterized by microscopy techniques and porosimetry methods in order to examine their structural properties. The composite halloysite-TiO2 films with variable quantities of halloysite were examined as photocatalysts to the discoloration of Basic Blue 41 azo dye in water. These nanocomposite films proved to be very promising photocatalysts and highly effective to dye's discoloration in spite of small amount of halloysite/TiO2 catalyst immobilized onto glass substrates. It also has been shown that the efficiency of the halloysite/TiO2 films could be further improved when silver particles were deposited on their surface after successful adsorption from an aqueous solution of a silver salt and UV reduction of the adsorbed ions

Biogeochemical processes at the sediment-water interface in a Northeastern Atlantic abyssal locality (Porcupine Abyssal Plain)

Abstract Temporal and spatial variability in the composition of suspended particulate material (SPM) was found at a Northeastern Atlantic abyssal locality on the Porcupine Abyssal Plain at a depth of 4850 m. Total SPM was distinctly higher in July 1997 than in March-April 1997 and October 1996. The 20 m of water immediately overlying the seabed was strongly influenced by resuspension and the suspended particulate matter was enriched with iron and manganese. Two water distinct layers, which were characterized by being enriched with SPM, Fe p , Mn p and Al p , were encountered during all sampling periods at depths of 4000 m and 4800 m. The enrichment of SPM with biogenic elements such as Ba, Ca and Sr implies it has a high biogenic content. Increases were observed in the concentrations of these biogenic elements throughout the sampling period, which indicates that the biogenic content of the SPM was steadily increased. SPM content and element/aluminum ratios increased in the spring and summer of 1997 compared to autumn 1996, probably as a result of increases in primary productivity, coincidental increases in near-bottom current velocities and possibly other processes such as increases in bacterial activity and bioturbation. Authigenic formation of solid phases of Fe and Mn were also influencing the spatial variability. Chemical reactions involving organic carbon and oxygen, which lead to the incorporation of iron and manganese in various forms into sediments were deduced. It is proposed that there was formation of lepidocrocite (γ-FeOOH) in the presence of organic carbon and oxygen, and also that iron may also have been transformed into Fe 2 O 3 . Re-precipitation of Fe and Mn is strongly enhanced by their enrichment in the SPM in the bottom waters. The sediments predominantly consist of biogenic carbonates and can be characterized as foraminiferal ooze. The proportion of these biogenic carbonates proved to be higher in the more recent sediments, either as result of recent increases in total primary productivity or because of carbonate dissolution within the subsurface sediments. Parallel increases of Mn, Fe and carbonates in the sediment layers supports the idea that the metallic ions are being adsorbed on to calcite surfaces, rather than being co-precipitated in the carbonate phases. Reprecipitation of iron and manganese in other solid phases with the involvement of organic carbon (C org ) in the oxygen penetration zone is suggested

Optical properties of ITO nanocoatings for photovoltaic and energy building applications

Targeting energy savings in buildings, photovoltaics and other sectors, significant research activity is nowadays focused on the production of spectral selective nanocoatings. In the present study an ITO coating on glass substrate is prepared from ITO powder, characterized and analysed. The spectral transmittance and reflectance of the ITO coated glass and of two other commercially developed ITO coatings on glass substrate were measured and compared. Furthermore, a simulation algorithm was developed to determine the optical properties of the ITO coatings in the visible, solar and near infrared regions in order to assess the impact of the ITO coatings in the energy performance of buildings, and particularly the application in smart windows. In addition, the current density produced by a PV assuming each of the ITO coated glass served as a cover was computed, in order to assess their effect in PV performance. The preliminary ITO coating prepared and the two other coatings exhibit different optical properties and, thus, have different impact on energy performance. The analysis assists in a better understanding of the desired optical properties of nanocoatings for improved energy performance in PV and buildings

Preliminary background indoor EMF measurements in Greece

The main purpose of this work was to investigate the fluctuation of Greek indoor electromagnetic field (EMF) intensity values and identify peaks that might occur. The scientific interest is mainly focused on the bands of extremely low-frequency (ELF) magnetic fields and radiofrequency (RF) electric fields which have been suggested to be possibly carcinogenic to humans by the Scientific Committee on Emerging and Newly Identified Health Risks (SCENIHR).Electromagnetic radiation (EMR) measurements were performed in a variety of indoor dwellings, in Attica and in the islands of Zakynthos and Lesvos.A total number of 4540 measurements were taken in a wide frequency range (50 Hz-2100 MHz) of which 3301 in Attica, 963 in Lesvos and 276 in Zakynthos.Statistical analysis of the data revealed specific statistically significant differences between the mean values of the electric (ELF and RF) but not the magnetic (ELF) field strengths measured at different distances from the EMF source, as well as between some of the mean values of the RF electric field at different bands. Some statistically significant differences between mean electric field values at different geographic locations were also identified.As far as the RF electric field is concerned, the maximum values, in most cases, were below 0.5 V/m, however increased values above 1 V/m and up to 5.6 V/m were occasionally observed. The ELF magnetic field values were lower than 1 μT. It may be concluded that overall, the observed indoor EMF intensity values remained well below domestic and European established limits. © 2015 Associazione Italiana di Fisica Medica

Self-organised critical features in soil radon and MHz electromagnetic disturbances: Results from environmental monitoring in Greece

This paper addresses the issues of self-organised critical behaviour of soil-radon and MHz-electromagnetic disorders during intense seismic activity in SW Greece. A significant radon signal is re-analysed for environmental influences with Fast Fourier Transform and multivariate statistics. Self-organisation of signals is investigated via fractal evolving techniques and detrended fluctuation analysis. New lengthy radon data are presented and analysed accordingly. The data did not show self-similarities. Similar analysis applied to new important concurrent MHz-electromagnetic signals revealed analogous behaviour to radon. The signals precursory value is discussed. © 2012 Elsevier Ltd

Environmental monitoring of radon in soil during a very seismically active period occurred in South West Greece

This paper focuses on the environmental monitoring of radon in soil as a potential trace gas in the search of earthquake precursors. The paper reports the following: (a) Pre-monitoring experiments. (b) Set-up of methods and devices. (c) Active and passive monitoring results concentrating on two extremely-strong radon anomalies (∼ 500 kBq m -3). (e) Discussion regarding the employed ±2σ technique for identifying radon disturbances. (f) Application of wavelet-power-spectrum fractal analysis for detecting power-law behaviour. The strong anomalies exhibited anti-persistent power-law-beta-values (b = (1.8 ± 0.2), b = (1.8 ± 0.3)) significantly higher than those of the baseline. Persistent b-values were also detected. The findings comply with a self-organised-critical pre-earthquake state. (h) Discussion on models that interpret the radon anomalies focusing on the recently-proposed asperity-model. (i) Application of a recent technique which showed that the two strong disturbances were proportional to the strain change. It was concluded that the strong radon disturbances may be linked to the strong earthquake of 8/6/2008, M = 6.5, occurred 29 km away from the installed instrumentation. © 2012 The Royal Society of Chemistry