225 research outputs found
Growth of Cadmium-Zinc Telluride Crystals by Controlled Seeding Contactless Physical Vapor Transport
Bulk crystals of cadmium-zinc telluride, 23 mm in diameter and up to 45 grams in weight were grown. Controlled seed formation procedure was used to limit the number of grains in the crystal. Most uniform distribution of ZnTe in the crystals was obtained using excess (Cd + Zn) pressure in the ampoule
Poisoning of Heat Pipes
Thermal management is critical to space exploration efforts. In particular, efficient transfer and control of heat flow is essential when operating high energy sources such as nuclear reactors. Thermal energy must be transferred to various energy conversion devices, and to radiators for safe and efficient rejection of excess thermal energy. Applications for space power demand exceptionally long periods of time with equipment that is accessible for limited maintenance only. Equally critical is the hostile and alien environment which includes high radiation from the reactor and from space (galactic) radiation. In space or lunar applications high vacuum is an issue, while in Martian operations the systems will encounter a CO2 atmosphere. The effect of contact at high temperature with local soil (regolith) in surface operations on the moon or other terrestrial bodies (Mars, asteroids) must be considered
Characterization of Cadmium-Zinc Telluride Crystals Grown by 'Contactless' PVT Using Synchrotron White Beam Topography
Crystals of Cd(1-x)Zn(x)Te grown by Physical Vapor Transport (PVT) using self-seeding 'contactless' techniques were characterized using synchrotron radiation (reflection, transmission, and Laue back-reflection X-ray topography). Crystals of low (x = 0.04) and high (up to x approx. = 0.4) ZnTe content were investigated. Twins and defects such as dislocations, precipitates, and slip bands were identified. Extensive inhomogeneous strains present in some samples were found to be generated by interaction (sticking) with the pedestal and by composition gradients in the crystals. Large (up to about 5 mm) oval strain fields were observed around some Te precipitates. Low angle grain boundaries were found only in higher ZnTe content (x greater than or equal to 0.2) samples
Microstructure of nanocrystalline diamond powders studied by powder diffractometry
High resolution x-ray diffraction peaks of diamond nanosize powders of nominal sizes ranging from 5 to 250ânm were analyzed and provided information on grain structure, average size of crystallites, and concentration of dislocations. Selected samples were heat treated at 1670âK at pressures 2.0 and 5.5âGPa or had surface modified by outgassing, heat treatment at vacuum conditions, and by controlled adsorption of gases. The apparent lattice parameter method was applied to characterize the structure of a shell-core model of nanosize particles. The multiple whole profile fitting provided information on crystallite sizes and density of dislocations. Population of dislocations increased with applied pressure, while strain and interplanar distances in the surface layers decreased. Adsorption of foreign gases on the grain surface modified the structure of the surface layers but did not affect dislocations near the center of the grains
Seeded Physical Vapor Transport of Cadmium-Zinc Telluride Crystals: Growth and Characterization
Crystals of Cd(1-x)Zn(x)Te with x = 0.2 and 40 g in weight were grown on monocrystalline cadmium-zinc telluride seeds by closed-ampoule physical vapor transport with or without excess (Cd + Zn) in the vapor phase. Two post-growth cool-down rates were used. The crystals were characterized using low temperature photoluminescence, atomic force microscopy, chemical etching, X-ray diffraction and electrical measurements. No formation of a second, ZnTe-rich phase was observed
Mass Flux of ZnSe by Physical Vapor Transport
Mass fluxes of ZnSe by physical vapor transport (PVT) were measured in the temperature range of 1050 to 1160 C using an in-situ dynamic technique. The starting materials were either baked out or distilled under vacuum to obtain near-congruently subliming compositions. Using an optical absorption technique Zn and Se, were found to be the dominant vapor species. Partial pressures of Zn and Se, over the starting materials at temperatures between 960 and 1140 C were obtained by measuring the optical densities of the vapor phase at the wavelengths of 2138, 3405, 3508, 3613, and 3792 A. The amount and composition of the residual gas inside the experimental ampoules were measured after the run using a total pressure gauge. For the first time, the experimentally determined partial pressures of Zn and Se, and the amount and composition of the residual gas were used in a one-dimensional diffusion limited analysis of the mass transport rates for a PVT system. Reasonable agreement between the experimental and theoretical results was observed
Compression and thermal expansion of nanocrystalline TiN
Abstract. TiN nanopowders synthesized by the application of an anaerobic "imide" route and aerosol synthesis with 5 and 26 nm average size were examined by in situ diffraction at high pressure up to 6 GPa and high temperature up to 800 o C. Overall compressibilities and thermal expansion coefficients were determined for the examined pressure and temperature intervals. Nanocrystals of TiN show core-shell type structure where elastic properties of interior and surface shell are different; surface is softer and shows larger thermal expansion than crystalline TiN. Core-shell model was confirmed by analysis of large Q powder diffraction at room temperature with application of alp-Q and PDF analysis
HighPâTNano-Mechanics of Polycrystalline Nickel
We have conducted highPâTsynchrotron X-ray and time-of-flight neutron diffraction experiments as well as indentation measurements to study equation of state, constitutive properties, and hardness of nanocrystalline and bulk nickel. Our lattice volumeâpressure data present a clear evidence of elastic softening in nanocrystalline Ni as compared with the bulk nickel. We show that the enhanced overall compressibility of nanocrystalline Ni is a consequence of the higher compressibility of the surface shell of Ni nanocrystals, which supports the results of molecular dynamics simulation and a generalized model of a nanocrystal with expanded surface layer. The analytical methods we developed based on the peak-profile of diffraction data allow us to identify âmicro/localâ yield due to high stress concentration at the grain-to-grain contacts and âmacro/bulkâ yield due to deviatoric stress over the entire sample. The graphic approach of our strain/stress analyses can also reveal the corresponding yield strength, grain crushing/growth, work hardening/softening, and thermal relaxation under highPâTconditions, as well as the intrinsic residual/surface strains in the polycrystalline bulks. From micro-indentation measurements, we found that a low-temperature annealing (T < 0.4 Tm) hardens nanocrystalline Ni, leading to an inverse HallâPetch relationship. We explain this abnormal HallâPetch effect in terms of impurity segregation to the grain boundaries of the nanocrystalline Ni
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