187 research outputs found
Electronic epidemiological query on admission: early detection of high risk patients for pulmonary tuberculosis
Icosahedral metallacarborane/carborane species derived from 1,1′-bis(o-carborane)
We thank ORSAS (GS) and the EPSRC (DE and DMcK supported by project EP/E02971X/1, WYM supported by project EP/I031545/1) for funding.Examples of singly-metallated derivatives of 1,1[prime or minute]-bis(o-carborane) have been prepared and spectroscopically and structurally characterised. Metallation of [7-(1[prime or minute]-1[prime or minute],2[prime or minute]-closo-C2B10H11)-7,8-nido-C2B9H10]2- with a {Ru(p-cymene)}2+ fragment affords both the unisomerised species [1-(1[prime or minute]-1[prime or minute],2[prime or minute]-closo-C2B10H11)-3-(p-cymene)-3,1,2-closo-RuC2B9H10] (2) and the isomerised [8-(1[prime or minute]-1[prime or minute],2[prime or minute]-closo-C2B10H11)-2-(p-cymene)-2,1,8-closo-RuC2B9H10] (3), and 2 is easily transformed into 3 with mild heating. Metallation with a preformed {CoCp}2+ fragment also affords a 3,1,2-MC2B9-1[prime or minute],2[prime or minute]-C2B10 product [1-(1[prime or minute]-1[prime or minute],2[prime or minute]-closo-C2B10H11)-3-Cp-3,1,2-closo-CoC2B9H10] (4), but if CoCl2/NaCp is used followed by oxidation the result is the 2,1,8-CoC2B9-1[prime or minute],2[prime or minute]-C2B10 species [8-(1[prime or minute]-1[prime or minute],2[prime or minute]-closo-C2B10H11)-2-Cp-2,1,8-closo-CoC2B9H10] (5). Compound 4 does not convert into 5 in refluxing toluene, but does do so if it is reduced and then reoxidised, perhaps highlighting the importance of the basicity of the metal fragment in the isomerisation of metallacarboranes. A computational study of 1,1[prime or minute]-bis(o-carborane) is in excellent agreement with a recently-determined precise crystallographic study and establishes that the {1[prime or minute],2[prime or minute]-closo-C2B10H11} fragment is electron-withdrawing compared to H.Publisher PDFPeer reviewe
Study of the Hindrance Effect in Sub-barrier Fusion Reactions
We have measured the fusion cross sections of the 12C(13C, p)24Na reaction
through off-line measurement of the beta-decay of 24Na using the beta-gamma
coincidence method. Our new measurements in the energy range of Ec.m. = 2.6-3.0
MeV do not show an obvious S-factor maximum but a plateau. Comparison between
this work and various models is presented.Comment: 3 pages, 3 figures, Talk at the "10th International Conference on
Nucleus-Nucleus Collisions", Beijing, 16-21 August 200
Sentiment analysis to support business decision-making. A bibliometric study
Customer feedback on online platforms is an unstructured database of growing importance for organizations, which, together with the rise of Natural Language Processing algorithms, is increasingly present when making decisions. In this paper, a bibliometric analysis is carried out with the intention of understanding the prevailing state of research about the adoption of sentiment analysis methods in organizations when making decisions. It is also a goal to comprehend which business sectors, and areas within the company, they are most applied, and to identify what future challenges that in this area may arise, as well as the main topics, authors, articles, countries, and universities most influential in the scientific literature. To this end, a total of 101 articles have been gathered from the Scopus and Clarivate Analytics Web of Science (WoS) databases, of which 85 were selected for analysis using the Bibliometrix tool. This study highlights the growing popularity of sentiment analysis methods combined with Multicriteria Decision Making and predictive algorithms. Twitter and Amazon are commonly used data sources, with applications across multiple sectors (supply chain, financial, etc.). Sentiment analysis enhances decision-making and promotes customer-centric approaches
Neutron Beta Decay Studies with Nab
Precision measurements in neutron beta decay serve to determine the coupling
constants of beta decay and allow for several stringent tests of the standard
model. This paper discusses the design and the expected performance of the Nab
spectrometer.Comment: Submitted to Proceedings of the Conference CIPANP12, St.Petersburg,
Florida, May 201
New measurement of the scattering cross section of slow neutrons on liquid parahydrogen from neutron transmission
Liquid hydrogen is a dense Bose fluid whose equilibrium properties are both
calculable from first principles using various theoretical approaches and of
interest for the understanding of a wide range of questions in many body
physics. Unfortunately, the pair correlation function inferred from
neutron scattering measurements of the differential cross section from different measurements reported in the literature are
inconsistent. We have measured the energy dependence of the total cross section
and the scattering cross section for slow neutrons with energies between
0.43~meV and 16.1~meV on liquid hydrogen at 15.6~K (which is dominated by the
parahydrogen component) using neutron transmission measurements on the hydrogen
target of the NPDGamma collaboration at the Spallation Neutron Source at Oak
Ridge National Laboratory. The relationship between the neutron transmission
measurement we perform and the total cross section is unambiguous, and the
energy range accesses length scales where the pair correlation function is
rapidly varying. At 1~meV our measurement is a factor of 3 below the data from
previous work. We present evidence that these previous measurements of the
hydrogen cross section, which assumed that the equilibrium value for the ratio
of orthohydrogen and parahydrogen has been reached in the target liquid, were
in fact contaminated with an extra non-equilibrium component of orthohydrogen.
Liquid parahydrogen is also a widely-used neutron moderator medium, and an
accurate knowledge of its slow neutron cross section is essential for the
design and optimization of intense slow neutron sources. We describe our
measurements and compare them with previous work.Comment: Edited for submission to Physical Review
High-Efficiency Resonant RF Spin Rotator with Broad Phase Space Acceptance for Pulsed Polarized Cold Neutron Beams
We have developed a radio-frequency resonant spin rotator to reverse the
neutron polarization in a 9.5 cm x 9.5 cm pulsed cold neutron beam with high
efficiency over a broad cold neutron energy range. The effect of the spin
reversal by the rotator on the neutron beam phase space is compared
qualitatively to RF neutron spin flippers based on adiabatic fast passage. The
spin rotator does not change the kinetic energy of the neutrons and leaves the
neutron beam phase space unchanged to high precision. We discuss the design of
the spin rotator and describe two types of transmission-based neutron spin-flip
efficiency measurements where the neutron beam was both polarized and analyzed
by optically-polarized 3He neutron spin filters. The efficiency of the spin
rotator was measured to be 98.0+/-0.8% on resonance for neutron energies from
3.3 to 18.4 meV over the full phase space of the beam. As an example of the
application of this device to an experiment we describe the integration of the
RF spin rotator into an apparatus to search for the small parity-violating
asymmetry A_gamma in polarized cold neutron capture on para-hydrogen by the
NPDGamma collaboration at LANSCE
- …