Freshwater Food Habits of Salvelinus malma (Walbaum) on Amchitka Island, Alaska

Stomach contents of 3,672 Dolly Varden char collected from September 1967 to November 1968 were examined to determine the food habits of this species. Of these, 3,100 (86%) had food in their stomachs. Aquatic invertebrates (Insecta and Crustacea) comprised over 90% of the diet. Food habits varied with habitat. Aquatic insects were most important in the diet of stream fish while aquatic insects and crustaceans were most important in the diet of lake fish. Food habits of lake fish were re- 1ated to lake bottom type and access to the sea. Fish in landlocked lakes fed primarily on aquatic insects, fish, and fish eggs. In lakes with access to the sea, crustaceans, followed by aquatic insects, were the major food items in those with firm bottoms adjacent to shore while aquatic insects, followed by crustaceans, were the major food items in those with muck bottoms adjacent to shore. As fish size increased, feeding activity decreased and aquatic insects became less important in the diet while crustaceans and fish became more important. During summer, feeding activity was highest for lake fish while it was highest during autumn and summer for stream fish. Aquatic insects were the dominant food item in summer while crustaceans and fish were dominant in spring and autumn. Mature and immature fish of similar size ate similar organisms. Mature fish, however, fed more sporadically prior to spawning. Feeding activity was highest during daylight hours. Dolly Varden selected larger food items, such as insects and amphipods and ignored small items such as nematodes and oligochaetes

Sequential biological and photocatalysis based treatments for shipboard slop purification: A pilot plant investigation

This study investigated the treatment of a shipboard slop containing commercial gasoline in a pilot plant scale consisting of a membrane biological reactor (MBR) and photocatalytic reactor (PCR) acting in series. The MBR contributed for approximately 70% to the overall slop purification. More precisely, the biological process was able to remove approximately 40%, on average, of the organic pollution in the slop. Nevertheless, the membrane was capable to retain a large amount of organic molecules within the system, amounting for a further 30% of the influent total organic content removal. However, this affected the membrane fouling, thus resulting in the increase of the pore blocking mechanism that accounted for approximately 20% to the total resistance to filtration (2.85∙10 13 m −1 ), even if a significant restoration of the original membrane permeability was obtained after chemical cleanings. On the other hand, the biological treatment produced a clear solution for the photocatalytic system, thereby optimizing the light penetration and generation of highly oxidizing active oxygen species that enabled the degradation of bio-recalcitrant compounds. Indeed, low total organic carbon (TOC) values (<10 mg L −1 ) were achieved in the output of the photocatalytic reactor by means of only 60 Einstein (E) of cumulative impinging energy after the addition of K 2 S 2 O 8 . Overall, coupling the two processes enabled very high TOC removal (ca. 95%)

An aceylcholinesterase/choline oxidase-based amperometric biosensor as a liquid chromatography detector for acetylcholine and choline determination in brain tissue

A liquid chromatography (LC) detector based on a fast response and sensitive bienzyme amperometric biosensor for acetylcholine (ACh) and choline (Ch) is described. The detector fabrication consisted of glutaraldehyde co-crosslinking of acetylcholinesterase and choline oxidase with bovine serum albumin on the Pt working electrode of a conventional thin-layer electrochemical flow cell. The influence of some experimental parameters (e.g. enzyme loading, thickness of the bienzyme layer, flow rate) on the detector characteristics has been studied in order to optimize the analyte response while minimizing band broadening and distortion. A mobile phase consisting of a phosphate buffer (I 0.1 M, pH 6.5) containing 5 mM sodium hexane sulphonate and 10 mM tetramethylammonium phosphate was found to give very satisfactory resolution and peak shape in ion-pair, reversed-phase LC. Linear responses were observed over at least four decades and absolute detection limits (at a signal to noise ratio of 3) were 12 and 27 fmole injected for Ch and ACh, respectively. After one month of intensive use in the LC system, the detector retained about 70% of its initial sensitivity. The potential of the described approach is demonstrated by the simultaneous determination of Ch and ACh in rat brain tissue homogenates

The Individual Poverty Incidence of Growth

The canonical approach to analyse the poverty impact of growth is based on the comparison of poverty before and after growth. Measurement tools endorsing this approach fail to capture the different experiences of poverty dynamic in the population: there can be groups of the population made poorer or non-poor made poor by growth. We propose an approach that allows measuring this individual poverty incidence of growth and show how it is related with existing models. We apply our framework to evaluate the poverty impact of growth in Indonesia, by comparing the 1993–2000 with the 2000–07 and 2007–14 growth spells

Effect of stacking interactions on charge transfer states in photoswitches interacting with ion channels

The activity of ion channels can be reversibly photo-controlled via the binding of molecular photoswitches, often based on an azobenzene scaffold. Those azobenzene derivatives interact with aromatic residues of the protein via stacking interactions. In the present work, the effect of face-to-face and t-shaped stacking interactions on the excited state electronic structure of azobenzene and p-diaminoazobenzene integrated into the Na V1.4 channel is computationally investigated. The formation of a charge transfer state, caused by electron transfer from the protein to the photoswitches, is observed. This state is strongly red shifted when the interaction takes place in a face-to-face orientation and electron donating groups are present on the aromatic ring of the amino acids. The low-energy charge transfer state can interfere with the photoisomerization process after excitation to the bright state by leading to the formation of radical species. </p

The classical Lenz vector and the two-dimensional quantum harmonic oscillator

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Visible Light Induced Oxidation of Trans-ferulic Acid by TiO2 Photocatalysis

The oxidation of trans-ferulic acid (C 10H 10O 4) in aqueous TiO 2 dispersion occurs via the formation of a charge-transfer complex on the TiO 2 surface that is able to absorb visible light (\u3bb 65 400 nm). The main product is CO 2, whereas secondary oxidation products are organic species such as vanillin, caffeic acid, homovanillic acid, and vanillylmandelic acid. Oxidation through the formation of a charge-transfer complex occurs only in the presence of specific TiO 2 samples. Experiments in the absence of oxygen, in the presence of bromate ions and by using a phosphate-modified TiO 2, have been carried out for investigating the reaction mechanism. In order to study the interaction between trans-ferulic acid and TiO 2 surface and to characterize the charge-transfer complex, UV-Vis diffuse reflectance and FT-IR spectroscopies have been used. FT-IR characterization of TiO 2 samples in contact with the aqueous trans-ferulic acid solution indicates that the charge-transfer complex formation occurs via adsorption of bidentate ferulate species

Highly stable defective TiO2-x with tuned exposed facets induced by fluorine: Impact of surface and bulk properties on selective UV/visible alcohol photo-oxidation

Titanium dioxide samples were prepared in the presence of different amounts of fluorine via hydrothermal method. It has been found that the presence of fluoride influenced the physico-chemical properties of TiO2 in various ways as polymorphic form stability, surface hydroxylation, generation of hydroxyl radicals under irradiation and formation of Ti3+ centers and oxygen vacancies. The generation rate of [rad]OH radicals was investigated by the photoluminescence technique in the presence of terephthalic acid. X-ray diffractometry indicated that fluorine stabilized the anatase TiO2. X-Ray photoelectron spectroscopy (XPS) revealed the presence of fluorine on the surface and the shift of the valence band edge towards less negative potentials, electron paramagnetic resonance (EPR) confirmed the formation of Ti3+ in the bulk of the photocatalysts, UV–vis spectra showed the extension of the TiO2 photo-response in the visible light region. 2-Propanol degradation and 4-methoxybenzyl alcohol partial oxidation were studied as probe reactions by using the home prepared powders as photocatalysts. Surprisingly, the photocatalytic activity resulted to be mainly affected by [rad]OH radicals formation ability under irradiation, rather than by the presence of {0 0 1} facets, although it cannot be excluded that the latter could influence the ability to form radicals under irradiation