Characterisation of flame development with ethanol, butanol, iso-octane, gasoline and methane in a direct-injection spark-ignition engine

Research into novel internal combustion engines requires consideration of the diversity in future fuels that may contain significant quantities of bio-components in an attempt to reduce CO2 emissions from vehicles and contribute to energy sustainability. However, most biofuels have different chemical and physical properties to those of typical hydrocarbons; these can lead to different mechanisms of mixture preparation and combustion. The current paper presents results from an optical study of combustion in a direct-injection spark-ignition research engine with gasoline, iso-octane, ethanol and butanol fuels injected from a centrally located multi-hole injector. Methane was also employed by injecting it into the inlet plenum of the engine to provide a benchmark case for well-mixed ‘homogeneous’ charge preparation. Crank-angle resolved flame chemiluminescence images were acquired and post-processed for a series of consecutive cycles for each fuel, in order to calculate in-cylinder rates of flame growth and motion. In-cylinder pressure traces were used for heat release analysis and for comparison with the image-processing results. All tests were performed at 1500 RPM with 0.5 bar intake plenum pressure. Stoichiometric (ϕ = 1.0) and lean (ϕ = 0.83) conditions were considered. The combustion characteristics were analysed with respect to laminar and turbulent burning velocities obtained from combustion bombs in the literature and from traditional combustion diagrams in order to bring all data into the context of current theories and allow insights by making comparisons were appropriate

An Analysis of the Combustion Behavior of Ethanol, Butanol, Iso-Octane, Gasoline, and Methane in a Direct-Injection Spark-Ignition Research Engine

Future automotive fuels are expected to contain significant quantities of bio-components. This poses a great challenge to the designers of novel low-CO2 internal combustion engines because biofuels have very different properties to those of most typical hydrocarbons. The current article presents results of firing a direct-injection spark-ignition optical research engine on ethanol and butanol and comparing those to data obtained with gasoline and iso-octane. A multihole injector, located centrally in the combustion chamber, was used with all fuels. Methane was also employed by injecting it into the inlet plenum to provide a benchmark case for well-mixed “homogeneous” charge preparation. The study covered stoichiometric and lean mixtures (λ = 1.0 and λ = 1.2), various spark advances (30–50° CA), a range of engine temperatures (20–90°C), and diverse injection strategies (single and “split” triple). In-cylinder gas sampling at the spark-plug location and at a location on the pent-roof wall was also carried out using a fast flame ionization detector to measure the equivalence ratio of the in-cylinder charge and identify the degree of stratification. Combustion imaging was performed through a full-bore optical piston to study the effect of injection strategy on late burning associated with fuel spray wall impingement. Combustion with single injection was fastest for ethanol throughout 20–90°C, but butanol and methane were just as fast at 90°C; iso-octane was the slowest and gasoline was between iso-octane and the alcohols. At 20°C, λ at the spark plug location was 0.96–1.09, with gasoline exhibiting the largest and iso-octane the lowest value. Ethanol showed the lowest degree of stratification and butanol the largest. At 90°C, stratification was lower for most fuels, with butanol showing the largest effect. The work output with triple injection was marginally higher for the alcohols and lower for iso-octane and gasoline (than with single injection), but combustion stability was worse for all fuels. Triple injection produced a lower degree of stratification, with leaner λ at the spark plug than single injection. Combustion imaging showed much less luminous late burning with tripe injection. In terms of combustion stability, the alcohols were more robust to changes in fueling (λ = 1.2) than the liquid hydrocarbons

Characterisation of Spray Development from Spark-Eroded and Laser-Drilled Multihole Injectors in an Optical DISI Engine and in a Quiescent Injection Chamber

This paper addresses the need for fundamental understanding of the mechanisms of fuel spray formation and mixture preparation in direct injection spark ignition (DISI) engines. Fuel injection systems for DISI engines undergo rapid developments in their design and performance, therefore, their spray breakup mechanisms in the physical conditions encountered in DISI engines over a range of operating conditions and injection strategies require continuous attention. In this context, there are sparse data in the literature on spray formation differences between conventionally drilled injectors by spark erosion and latest Laser-drilled injector nozzles. A comparison was first carried out between the holes of spark-eroded and Laser-drilled injectors of same nominal type by analysing their in-nozzle geometry and surface roughness under an electron microscope. Then the differences in their spray characteristics under quiescent conditions, as well as in a motoring optical engine, are discussed on the basis of high-speed imaging experiments and image processing methods. Specifically, the spray development mechanism was quantified by spray tip penetration and cone angle data under a range of representative low-load and high-low engine operating conditions (0.5 bar and 1.0 bar absolute, respectively), as well as at low and high injector body temperatures (20 °C and 90 °C) to represent cold and warm engine-head conditions. Droplet sizing was also performed with the two injectors using Phase Doppler Anemometry in a quiescent chamber

Imaging and heat flux measurements of wall impinging sprays of hydrocarbons and alcohols in a direct-injection spark-ignition engine

The latest generation of fuel systems for direct-injection spark-ignition engines uses injection nozzles that accommodate a number of holes with various angles in order to offer flexibility in in-cylinder fuel targeting over a range of engine operating conditions. However, the high-injection pressures that are needed for efficient fuel atomisation can lead to deteriorating effects with regards to engine exhaust emissions (e.g. unburned hydrocarbons and particulates) from liquid fuel impingement onto the piston and liner walls. Eliminating such deteriorating effects requires fundamental understanding of in-cylinder spray development processes, taking also into account the diversity of future commercial fuels that can contain significant quantities of bio-components with very different chemical and physical properties to those of typical liquid hydrocarbons. This paper presents high-speed imaging results of spray impingement onto the liner of a direct-injection spark-ignition engine, as well as crank-angle resolved wall heat flux measurements at the observed locations of fuel impingement for detailed characterisation of levels and timing of impingement. The tests were performed in a running engine at 1500 RPM primarily at low load (0.5 bar intake pressure) using 20, 50 and 90 °C engine temperatures. Gasoline, iso-Octane, Butanol, Ethanol and a blend of 10% Ethanol with 90% Gasoline (E10) were used to encompass a range of current and future fuel components for spark-ignition engines. The collected data were analysed to extract mean and standard deviation statistics of spray images and heat flux signals. The results were also interpreted with reference to physical pro

Spray Development, Flow Interactions and Wall Impingement in a Direct-Injection Spark-Ignition Engine

Levels of liquid fuel impingement on in-cylinder surfaces in direct injection spark ignition engines have typically been higher than those in port-fuel injection engines due to in-cylinder injection and higher injection pressures. The result is typically an increase in the levels of un-burned hydrocarbons and smoke emissions which reduce the potential fuel economy benefits associated with direct injection engines. Although different injection strategies can be used to reduce these effects to some extent, full optimisation of the injection system and combustion process is only possible through improved understanding of spray development that can be obtained from optical engine investigations under realistic operating conditions. To this extent, the spray formation from a centrally mounted multi-hole injector was studied in a single-cylinder optical direct-injection spark-ignition engine under part-load conditions (0.5 bar intake plenum pressure) at 1500 RPM. A high-speed camera and laser illumination were used to obtain Mie-scattering images of the spray development on different in-cylinder planes for a series of consecutive engine cycles. The engine temperature was varied to reflect cold-start (20 °C) and fully warm (90 °C) engine conditions. A multi-component fuel (commercial gasoline) and a single-component fuel (iso-octane) were both tested and compared to investigate the effects of fuel properties on spray formation and wall impingement. An experimental arrangement was also developed to detect in-cylinder liquid fuel impingement using heat flux sensors installed on the cylinder liner. Two different injection strategies were tested; a typical single-injection strategy in the intake stroke to promote homogeneous mixture formation, as well as a triple-injection strategy around the same timing to assess the viability of using multiple-injection strategies to reduce wall impingement and improve mixture preparation. A sweep of different locations around the cylinder bore revealed the locations of highest fuel impingement levels which did not correspond directly to the nominal spray plume trajectories as a result of spray-flow interactions. These results were analysed in conjunction with the observed effects from the parallel imaging investigation. Copyright © 2007 SAE International

Development of a Real-Size Optical Injector Nozzle for Studies of Cavitation, Spray Formation and Flash Boiling at Conditions Relevant to Direct-Injection Spark-Ignition Engines

High-pressure multi-hole injectors for direct-injection spark-ignition engines have shown enhanced fuel atomisation and flexibility in fuel targeting by selection of the number and angle of the nozzle holes. The nozzle internal flow is known to influence the characteristics of spray formation; hence, understanding its mechanisms is essential for improving mixture preparation. However, currently, no data exist for fuel temperatures representative of real engine operation, especially at low-load high-temperature conditions with early injection strategies that can lead to phase change due to fuel flash-boiling upon injection. This challenge is further complicated by the predicted fuel stocks, which may include new (e.g. bio-derived) components. The physical/chemical properties of such components can differ markedly from gasoline, and it is important to have the capability to study their effects on in-nozzle flow and spray formation, taking under consideration their different chemical compatibilities with optical materials as well. The current article presents the design and development of a real-size quartz optical nozzle, 200 µm in diameter, suitable for high-temperature applications and also compatible with new fuels such as alcohols. First, the internal geometry of a typical real multi-hole injector was analysed by electron microscopy. Mass flow was measured, and relevant fluid mechanics dimensionless parameters were derived. Laser and mechanical drilling of the quartz nozzle holes were compared. Abrasive flow machining of the optical nozzles was also performed and analysed by microscopy in comparison to the real injector. Initial validation results with a high-speed camera showed successful imaging of microscopic in-nozzle flow and cavitation phenomena, coupled to downstream spray formation, under a variety of conditions including high fuel temperature flash-boiling effects. The current work used gasoline and iso-octane to provide proof-of-concept images of the optical nozzle, and future work will include testing of a range of fuels, some of which will also be bio-derived

Acidification in the Cairngorms and Lochnagar: a palaeoecological assessment

Sensitive lakes in areas of the United Kingdom with moderate to high sulphur deposition have been acidified since the middle of the nineteenth century- (Battarbee et al. 1988). Regions such as Galloway, south west Scotland (eg. Flower and Battarbee 1983, Flower et al. 1987), Wales (eg. Battarbee et al. 1988, Fritz et aL 1990), Cumbria (eg. Battarbee et al 1988, Atkinson and Haworth 1990), and Rannoch Moor in the central Scottish Highlands (eg. Flower et al 1988) have been affected. This study extends the geographical survey of lake acidification to the Caimgorm and Lochnagar regions of north east Scotland (Figure 1). The Caimgorms and Lochnagar are areas of considerable conservation value, forming the largest single area of land over 1000 m in the UK. The Caimgorm mountain plateau is a National Nature Reserve, noted for its alpine flora and fauna, whilst the Lochnagar range is a Scottish Wildlife Trust reserve. A secondary- aim of the study was to evaluate the 11land-use 11 hypothesis (eg. Rosenqvist 1977, 1978, 1981) as a mechanism for lake acidification by examining high altitude sites with no active land-management. Sites selected are all remote, lie above the tree line and have undisturbed catchments. Lochnagar and the Caimgorms are situated on sensitive granite geology (Kinniburgh and Edmunds 1986, Wells et al. 1986) in an area of moderate acid deposition (c. 0.95 g S yr-1 ). It can be predicted that sensitive lakes in this area (those having Ca2 + values of <60 μeq i-1 ) will have acidified (Battarbee 1989)

Reconstructing North Atlantic marine climate variability using an absolutely-dated sclerochronological network

This is the final version of the article. Available from Elsevier via the DOI in this record.Reconstructing regional to hemispheric-scale climate variability requires the application of spatially representative and climatically sensitive proxy archives. Large spatial networks of dendrochronologies have facilitated the reconstruction of atmospheric variability and inferred variability in the Atlantic Ocean system. However, the marine environment has hitherto lacked the direct application of the spatial network approach because of the small number of individual absolutely-dated marine archives. In this study we present the first analyses of a network of absolutely-dated annually-resolved growth increment width chronologies from the marine bivalves Glycymeris glycymeris and Arctica islandica. The network contains eight chronologies spanning > 500 km along the western British continental shelf from the southern Irish Sea to North West Scotland. Correlation analysis of the individual chronologies and a suite of climate indices, including the Atlantic Multidecadal Oscillation (AMO), Central England surface air temperature (CET), northeast Atlantic sea surface temperatures (SST's) and the winter North Atlantic Oscillation (wNAO), demonstrates that, despite the large geographical distances been sites and the heterogeneous nature of the marine environment, the increment width variability in these series contains an element of coherence likely driven by a common response to changing environmental forcing. A nested Principal component analysis (PCA) was used to construct five composite series which explain between 31% and 74% of the variance across the individual chronologies. Linear regression analyses indicate that the composite series explain up to 41% of the variance in Northeast Atlantic SSTs over the calibration period (1975–2000). Calibration verification (reduction of error [RE] and coefficient of efficiency [CE]) statistics indicate that the composite series contains significant skill at reconstructing multi-decadal northeast Atlantic SST variability over the past two centuries (1805–2010). These data suggest that composite series derived from sclerochronology networks can facilitate the robust reconstruction of marine climate over past centuries to millennia providing invaluable baseline records of natural oceanographic variability.This work was supported financially by the NERC funded project Climate of the Last Millennium Project (CLAM; project No. NE/N001176/1) and the Marie Curie Frame work Partnership Annually Resolved Archives of Marine Climate Change (ARAMACC; Project No. FP7 604802). The authors would like to thank the three anonymous reviewer‘s for their constructive comments during the peer review process

An overview of treatment options for patients with relapsed/refractory multiple myeloma and renal impairment

Renal impairment (RI) is a relatively common complication of multiple myeloma, which increases in frequency as disease becomes more advanced and recovery of renal function becomes less likely as patients progress through lines of therapy. Clinical trials in the relapsed/refractory multiple myeloma (RRMM) setting have not uniformly included patients with RI or robustly reported their outcomes. Here, we review existing data among patients with RI and RRMM across drug classes (including immunomodulatory agents, proteasome inhibitors, monoclonal antibodies, antibody-drug conjugates, chimeric antigen receptor T-cell therapies, and exportin-1 inhibitor) to provide an improved understanding of available treatment options for this important population. We highlight data from pivotal clinical trials, including data relating to renal response (as defined by the International Myeloma Working Group) and discuss real-world experiences in patients with RI, where applicable. Despite substantial advances in RRMM treatment, the presence of RI remains associated with reduced overall survival. Consistent inclusion of patients with RI, and uniform reporting of their outcomes, should be encouraged in future prospective trials of treatments for RRMM