145 research outputs found

    Fabrication of polyaniline/TiO2 nanocomposite ammonia vapor sensor

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    Polyaniline/Titanium dioxide (PANi/TiO2) nanocomposite was fabricated from PANi, prepared by oxidative chemical polymerization and TiO2, synthesized by sol gel method. The PANi/TiO2 thin film sensors were prepared by spin coating technique. PANi/TiO2 nanocomposites were characterized by XRD and SEM. The cross sensitivity of thin film sensor indicate that the sensor exhibit selectivity to ammonia (NH3). The gas sensing measurements were carried out for different concentrations of NH3. The gas sensing study revealed that the response value increases with increasing concentration of NH3. Moreover, as concentration of NH3 increases, the response time decreases while recovery time increases, which can be attributed to the varying adsorption and desorption rates of an ambient gas with increasing concentration. When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/2791

    Fabrication of polyaniline/TiO2 nanocomposite ammonia vapor sensor

    Get PDF
    Polyaniline/Titanium dioxide (PANi/TiO2) nanocomposite was fabricated from PANi, prepared by oxidative chemical polymerization and TiO2, synthesized by sol gel method. The PANi/TiO2 thin film sensors were prepared by spin coating technique. PANi/TiO2 nanocomposites were characterized by XRD and SEM. The cross sensitivity of thin film sensor indicate that the sensor exhibit selectivity to ammonia (NH3). The gas sensing measurements were carried out for different concentrations of NH3. The gas sensing study revealed that the response value increases with increasing concentration of NH3. Moreover, as concentration of NH3 increases, the response time decreases while recovery time increases, which can be attributed to the varying adsorption and desorption rates of an ambient gas with increasing concentration. When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/2791

    Effect Of Annealing On Structure, Morphology, Electrical And Optical Properties Of Nanocrystalline TiO2 Thin Films

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    Semi-transparent and highly conducting nanostructured titanium oxide thin films have been prepared by sol-gel method. Thin films of TiO2 deposited on glass substrates using spin coating technique and the effect of annealing temperature (400 - 700 °C) on structural, microstructural, electrical and optical properties were studied. The X-ray diffraction and Atomic force microscopy measurements confirmed that the films grown by this technique have good crystalline tetragonal mixed anatase and rutile phase structure and homogeneous surface. The study also reveals that the rms value of thin film roughness increases from 7 to 19 nm. HRTEM image of TiO2 thin film (annealed at 700 °C) shows that a grain of about 50 - 60 nm in size is really aggregate of many small crystallites of around 10 - 15 nm. Electron diffraction pattern shows that the TiO2 films exhibited tetragonal structure. The surface morphology (SEM) of the TiO2 film showed that the nanoparticles are fine with an average grain size of about 50 - 60 nm. The optical band gap slightly decreases from 3.26 - 3.24 eV and the dc electrical conductivity was found in the range of 10-6 to 10-5(Ω·cm)-1 when the annealing temperature is changed from 400 to 700 °C. It is observed that TiO2 thin film annealed at 700 °C after deposition provide a smooth and flat texture suited for optoelectronic applications. When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/967

    Acute fulminant myocarditis at autopsy: A clinical masquerade?

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    Background: Myocarditis is a diagnostic challenge in cardiology. The diagnosis is frequently made post-mortem, with no clinical evidence of myocardial failure. Autopsy studies report a frequency of myocarditis ranging from 0.11-0.55% in the general population. Myocarditis is presents with varied clinical manifestations, ranging from asymptomatic to sudden cardiac death, sometimes mimicking the Myocardial Infarction (MI). Case Summary: A 55 years old male presented with sudden onset of chest pain, breathlessness at rest and flu like symptoms 5-6 days prior to admission. There was tachycardia with low Systolic blood pressure and muffled heart sounds. ECG showed ST segment & T wave changes. CK-MB was moderately raised. Though clinically diagnosed as MI and treated, patient expired the next day. On autopsy, gross examination of heart revealed no significant findings. Histological examination revealed fulminant myocarditis involving right ventricle, interventricular septum, left ventricular wall and A-V Node. Conclusion: It is not uncommon to find Myocarditis patients presenting with manifestations of MI and these cases often misdiagnosed as MI. In such cases, myocarditis should be considered as a differential diagnosis. Endomyocardial biopsies and histological examination of the myocardium is absolutely necessary for reliable diagnosis of the disease

    Implementation of a pharmacogenomics consult service to support the INGENIOUS trial

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    Hospital systems increasingly utilize pharmacogenomic testing to inform clinical prescribing. Successful implementation efforts have been modeled at many academic centers. In contrast, this report provides insights into the formation of a pharmacogenomics consultation service at a safety-net hospital, which predominantly serves low-income, uninsured, and vulnerable populations. The report describes the INdiana GENomics Implementation: an Opportunity for the UnderServed (INGENIOUS) trial and addresses concerns of adjudication, credentialing, and funding

    Mapping child growth failure across low- and middle-income countries

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    Childhood malnutrition is associated with high morbidity and mortality globally1. Undernourished children are more likely to experience cognitive, physical, and metabolic developmental impairments that can lead to later cardiovascular disease, reduced intellectual ability and school attainment, and reduced economic productivity in adulthood2. Child growth failure (CGF), expressed as stunting, wasting, and underweight in children under five years of age (0�59 months), is a specific subset of undernutrition characterized by insufficient height or weight against age-specific growth reference standards3�5. The prevalence of stunting, wasting, or underweight in children under five is the proportion of children with a height-for-age, weight-for-height, or weight-for-age z-score, respectively, that is more than two standard deviations below the World Health Organization�s median growth reference standards for a healthy population6. Subnational estimates of CGF report substantial heterogeneity within countries, but are available primarily at the first administrative level (for example, states or provinces)7; the uneven geographical distribution of CGF has motivated further calls for assessments that can match the local scale of many public health programmes8. Building from our previous work mapping CGF in Africa9, here we provide the first, to our knowledge, mapped high-spatial-resolution estimates of CGF indicators from 2000 to 2017 across 105 low- and middle-income countries (LMICs), where 99 of affected children live1, aggregated to policy-relevant first and second (for example, districts or counties) administrative-level units and national levels. Despite remarkable declines over the study period, many LMICs remain far from the ambitious World Health Organization Global Nutrition Targets to reduce stunting by 40 and wasting to less than 5 by 2025. Large disparities in prevalence and progress exist across and within countries; our maps identify high-prevalence areas even within nations otherwise succeeding in reducing overall CGF prevalence. By highlighting where the highest-need populations reside, these geospatial estimates can support policy-makers in planning interventions that are adapted locally and in efficiently directing resources towards reducing CGF and its health implications. © 2020, The Author(s)
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