504 research outputs found
What is the Entanglement Length in a Polymer Melt ?
We present results of molecular dynamics simulations of very long model
polymer chains analyzed by various experimentally relevant techniques. The
segment motion of the chains is found to be in very good agreement with the
repatation model. We also calculated the plateau-modulus G_N. The predicitions
of the entanglement length N_e from G_N and from the mean square displacements
of the chains segments disagree by a factor of about 2.2(2), indicating an
error in the prefactor in the standard formula for G_N. We show that recent
neutron spin echo measurements were carried out for chain lengths which are too
small for a correct determination of N_e.Comment: 5 pages, 4 figures, RevTe
Terahertz hot electron bolometer waveguide mixers for GREAT
Supplementing the publications based on the first-light observations with the
German Receiver for Astronomy at Terahertz frequencies (GREAT) on SOFIA, we
present background information on the underlying heterodyne detector
technology. We describe the superconducting hot electron bolometer (HEB)
detectors that are used as frequency mixers in the L1 (1400 GHz), L2 (1900
GHz), and M (2500 GHz) channels of GREAT. Measured performance of the detectors
is presented and background information on their operation in GREAT is given.
Our mixer units are waveguide-based and couple to free-space radiation via a
feedhorn antenna. The HEB mixers are designed, fabricated, characterized, and
flight-qualified in-house. We are able to use the full intermediate frequency
bandwidth of the mixers using silicon-germanium multi-octave cryogenic
low-noise amplifiers with very low input return loss. Superconducting HEB
mixers have proven to be practical and sensitive detectors for high-resolution
THz frequency spectroscopy on SOFIA. We show that our niobium-titanium-nitride
(NbTiN) material HEBs on silicon nitride (SiN) membrane substrates have an
intermediate frequency (IF) noise roll-off frequency above 2.8 GHz, which does
not limit the current receiver IF bandwidth. Our mixer technology development
efforts culminate in the first successful operation of a waveguide-based HEB
mixer at 2.5 THz and deployment for radioastronomy. A significant contribution
to the success of GREAT is made by technological development, thorough
characterization and performance optimization of the mixer and its IF interface
for receiver operation on SOFIA. In particular, the development of an optimized
mixer IF interface contributes to the low passband ripple and excellent
stability, which GREAT demonstrated during its initial successful astronomical
observation runs.Comment: Accepted for publication in A&A (SOFIA/GREAT special issue
Foraging areas of king penguins (Aptenodytes patagonicus) breeding at Possession Island in the Southern Indian Ocean
Between January and March 1994 and between January and June 1995 we used Global Location Sensors(GLS) to determine the feeding areas of King Penguins Aptenodytes patagonicus breeding at Possession Island, Crozet Archipalago. In both years, the preferred feeding area during summer was located about 300 km south of the island, being slightly more distant in 1995. Mean foraging trip duration was 5.7±1.1 days (n = 6) during summer 1994 and 8.9±3.7 days (n = 9) during summer 1995, respectively. During summer the travelling speed of the King Penguins studied was highest at the first and last days of the foraging trip (c. 8 km/h). During the middle days of foraging trips travelling speeds were much lower (< 5 km/h). In early winter, between late April and mid-June 1995, two King Penguins equipped with GLSs executed foraging trips with durations of 53 and 59 days, respectively. Both birds travelled beyond 60°S with maximum distances to the colony of 1600 and 1800 km, respectively, and total distances covered of about 5000 km. The winter trips were characterized by alternating periods of higher and lower distances covered, indicating a highly variable feeding success at different localities. The relationships between foraging trip duration (days) and maximum distance to the colony (km) and total distance covered (km) were calculated to be maximum distance = 210 + 27 d and total distance = 340 + 85 d
Quantum clocks are more accurate than classical ones
A clock is, from an information-theoretic perspective, a system that emits
information about time. One may therefore ask whether the theory of information
imposes any constraints on the maximum precision of clocks. Here we show a
quantum-over-classical advantage for clocks or, more precisely, the task of
generating information about what time it is. The argument is based on
information-theoretic considerations: we analyse how the accuracy of a clock
scales with its size, measured in terms of the number of bits that could be
stored in it. We find that a quantum clock can achieve a quadratically improved
accuracy compared to a purely classical one of the same size.Comment: 17 + 60 pages. V2: corrected typos and improved discussio
GREAT: the SOFIA high-frequency heterodyne instrument
We describe the design and construction of GREAT, the German REceiver for
Astronomy at Terahertz frequencies operated on the Stratospheric Observatory
for Infrared Astronomy (SOFIA). GREAT is a modular dual-color heterodyne
instrument for highresolution far-infrared (FIR) spectroscopy. Selected for
SOFIA's Early Science demonstration, the instrument has successfully performed
three Short and more than a dozen Basic Science flights since first light was
recorded on its April 1, 2011 commissioning flight.
We report on the in-flight performance and operation of the receiver that -
in various flight configurations, with three different detector channels -
observed in several science-defined frequency windows between 1.25 and 2.5 THz.
The receiver optics was verified to be diffraction-limited as designed, with
nominal efficiencies; receiver sensitivities are state-of-the-art, with
excellent system stability. The modular design allows for the continuous
integration of latest technologies; we briefly discuss additional channels
under development and ongoing improvements for Cycle 1 observations.
GREAT is a principal investigator instrument, developed by a consortium of
four German research institutes, available to the SOFIA users on a
collaborative basis
Shear yielding of amorphous glassy solids: Effect of temperature and strain rate
We study shear yielding and steady state flow of glassy materials with
molecular dynamics simulations of two standard models: amorphous polymers and
bidisperse Lennard-Jones glasses. For a fixed strain rate, the maximum shear
yield stress and the steady state flow stress in simple shear both drop
linearly with increasing temperature. The dependence on strain rate can be
described by a either a logarithm or a power-law added to a constant. In marked
contrast to predictions of traditional thermal activation models, the rate
dependence is nearly independent of temperature. The relation to more recent
models of plastic deformation and glassy rheology is discussed, and the
dynamics of particles and stress in small regions is examined in light of these
findings
Self-similar chain conformations in polymer gels
We use molecular dynamics simulations to study the swelling of randomly
end-cross-linked polymer networks in good solvent conditions. We find that the
equilibrium degree of swelling saturates at Q_eq = N_e**(3/5) for mean strand
lengths N_s exceeding the melt entanglement length N_e. The internal structure
of the network strands in the swollen state is characterized by a new exponent
nu=0.72. Our findings are in contradiction to de Gennes' c*-theorem, which
predicts Q_eq proportional N_s**(4/5) and nu=0.588. We present a simple Flory
argument for a self-similar structure of mutually interpenetrating network
strands, which yields nu=7/10 and otherwise recovers the classical Flory-Rehner
theory. In particular, Q_eq = N_e**(3/5), if N_e is used as effective strand
length.Comment: 4 pages, RevTex, 3 Figure
Optical and structural properties of sol-gel derived materials embedded in porous anodic alumina
Structure composing a xerogel, doped with lanthanide ions (erbium, terbium and europium), embedded in porous anodic alumina (PAA) have been fabricated and their optical and electrical characterisitics have been studied. Erbium photoluminescence at 1.53 µm from titania xerogel/PAA was found to increase with the number of xerogel layers and erbium concnetration for the excitation wavelength 532 nm, matching the area of transparency of both titania xerogel and PAA. Visible green and red electroluminescence was observed for terbium- and europium-doped IN2O3 and SnO2 xerogels embedded in porous anodic alumina. The improvement of the electrical properties of the xerogel/PAA cell is discussed, taking into account the observed ability of conducting In2O3:Sn (ITO) nanoparticles to penetrate into the anodic alumina pores
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