29,506 research outputs found
CO adsorption on (111) and (100) surfaces of the Pt sub 3 Ti alloy. Evidence for parallel binding and strong activation of CO
The CO adsorption on a 40 atom cluster model of the (111) surface and a 36 atom cluster model of the (100) surface of the Pt3Ti alloy was studied. Parallel binding to high coordinate sites associated with Ti and low CO bond scission barriers are predicted for both surfaces. The binding of CO to Pt sites occurs in an upright orientation. These orientations are a consequence of the nature of the CO pi donation interactions with the surface. On the Ti sites the orbitals donate to the nearly empty Ti 3d band and the antibonding counterpart orbitals are empty. On the Pt sites, however, they are in the filled Pt 5d region of the alloy band, which causes CO to bond in a vertical orientation by 5 delta donation from the carbon end
Report of the sensor cooler technology panel
The Sensor Cooler Technology Panel identified three major areas in which technology development must be supported in order to meet the system performance requirements for the Astrotech 21 mission set science objectives. They are: long life vibration free refrigerators; mechanical refrigeration for 2 K to 5 K; and flight testing of emerging prototype refrigerators. A development strategy and schedule were recommended for each of the three areas
Turbulent Supernova Shock Waves and the Sterile Neutrino Signature in Megaton Water Detectors
The signatures of sterile neutrinos in the supernova neutrino signal in
megaton water Cerenkov detectors are studied. Time dependent modulation of the
neutrino signal emerging from the sharp changes in the oscillation probability
due to shock waves is shown to be a smoking gun for the existence of sterile
neutrinos. These modulations and indeed the entire neutrino oscillation signal
is found to be different for the case with just three active neutrinos and the
cases where there are additional sterile species mixed with the active
neutrinos. The effect of turbulence is taken into account and it is found that
the effect of the shock waves, while modifed, remain significant and
measurable. Supernova neutrino signals in water detectors can therefore give
unambiguous proof for the existence of sterile neutrinos, the sensitivity
extending beyond that for terrestial neutrino experiments. In addition the time
dependent modulations in the signal due to shock waves can be used to trace the
evolution of the shock wave inside the supernova.Comment: 28 pages, 11 figure
Comparison of methods for estimating continuous distributions of relaxation times
The nonparametric estimation of the distribution of relaxation times approach
is not as frequently used in the analysis of dispersed response of dielectric
or conductive materials as are other immittance data analysis methods based on
parametric curve fitting techniques. Nevertheless, such distributions can yield
important information about the physical processes present in measured
material. In this letter, we apply two quite different numerical inversion
methods to estimate the distribution of relaxation times for glassy \lila\
dielectric frequency-response data at 225 \kelvin. Both methods yield unique
distributions that agree very closely with the actual exact one accurately
calculated from the corrected bulk-dispersion Kohlrausch model established
independently by means of parametric data fit using the corrected modulus
formalism method. The obtained distributions are also greatly superior to those
estimated using approximate functions equations given in the literature.Comment: 4 pages and 4 figure
Recommended from our members
The Corrosion of Carbon Black Anodes In Alkaline Electrolyte: III. The Effect Of Graphitization on the Corrosion Resistance of Furnace Blacks
Oxygen Isotopic Imaging of Refractory Inclusions from the Miller Range (MIL) 090019 CO3 Chondrite: A Perovskite Perspective
Calcium-Aluminum-rich Inclusions (CAIs) in primitive meteorites are the first solids to condense in the Solar System. The oxygen isotopic compositions recorded in various mineral components of CAIs provide clues about their origins and post-formation histories, recording processes such as condensation, melting, nebular alteration, and fluidrock reactions on the parent body. MIL 090019 is similar to some rare carbonaceous chondrites such as Acfer 094, DOM 08004/6 and ALH 77303 that contain high abundances of a variety of refractory inclusions. This provides an opportunity to study the oxygen isotopic record of different types of refractory inclusions within the same meteorite. We analyzed CAIs specifically targeting primary minerals that are direct nebular condensates, such as corundum and perovskite, with the goal of gaining insights into the O isotopic composition of the nebular gas(es) from which these CAIs condensed. As MIL 090019 is a classified as CO3.1, it shows some signs of thermal metamorphism, compared to the more primitive CO3 meteorites (e.g., DOM 08004/06). A second goal of this study is to search for evidence of nebular processes in phases such as perovskite and melilite that are susceptible to parent body alteration to varying degrees. We analyzed the oxygen isotopic compositions of various CAIs from the MIL 090019 CO3 carbonaceous chondrite by ion imaging using the NanoSIMS 50L (Nano Secondary Ion Mass Spectrometer) at JSC following methods described in. An advantage of ion imaging over traditional spot analyses is that it provides spatial context to the oxygen isotopic data. This work builds on previously reported oxygen isotopic composition of two other CAIs (CAI-44 and CAI-E2) from the same meteorite thin section
Behavior in normal and reduced gravity of an enclosed liquid/gas system with nonuniform heating from above
The temperature and velocity fields have been investigated for a single-phase gas system and a two-layer gas-and-liquid system enclosed in a circular cylinder being heated suddenly and nonuniformly from above. The transient response of the gas, liquid, and container walls was modelled numerically in normal and reduced gravity (10 to the -5 g). Verification of the model was accomplished via flow visualization experiments in 10 cm high by 10 cm diameter plexiglass cylinders
- …