Characterizing the chemical pathways for water formation -- A deep search for hydrogen peroxide

In 2011, hydrogen peroxide (HOOH) was observed for the first time outside the solar system (Bergman et al., A&A, 2011, 531, L8). This detection appeared a posteriori quite natural, as HOOH is an intermediate product in the formation of water on the surface of dust grains. Following up on this detection, we present a search for HOOH in a diverse sample of sources in different environments, including low-mass protostars and regions with very high column densities, such as Infrared Dark Clouds (IRDCs). We do not detect the molecule in any other source than Oph A, and derive 3$\sigma$ upper limits for the abundance of HOOH relative to H$_2$ lower than in Oph A for most sources. This result sheds a different light on our understanding of the detection of HOOH in Oph A, and shifts the puzzle to why this source seems to be special. Therefore we rediscuss the detection of HOOH in Oph A, as well as the implications of the low abundance of HOOH, and its similarity with the case of O$_2$. Our chemical models show that the production of HOOH is extremely sensitive to the temperature, and favored only in the range 20$-$30 K. The relatively high abundance of HOOH observed in Oph A suggests that the bulk of the material lies at a temperature in the range 20$-$30 K.Comment: 18 pages, 3 figures, invited refereed paper at the Faraday Discussion 16

Massive Infrared-Quiet Dense Cores: Unveiling the Initial Conditions of High-Mass Star Formation

As Pr. Th. Henning said at the conference, cold precursors of high-mass stars are now "hot topics". We here propose some observational criteria to identify massive infrared-quiet dense cores which can host the high-mass analogs of Class 0 protostars and pre-stellar condensations. We also show how far-infrared to millimeter imaging surveys of entire complexes forming OB stars are starting to unveil the initial conditions of high-mass star formation

Physical conditions in the Protoplanetary Nebula CRL 618 derived from observations of vibrationally excited HCCCN

We used the Effelsberg 100m and IRAM 30m telescopes to observe vibrationally excited cyanoacetylene (HCCCN) in several rotational transitions toward the proto-planetary nebula CRL618. Lines from 9 different vibrationally excited states with energies ranging up to 1600 K above ground were detected. The lines show P Cygni profiles indicating that the HCCCN emission originates from an expanding and accelerating molecular envelope. The HCCCN rotational temperature varies with velocity, peaks at 520 K, 3 km/s blue-shifted from the systemic velocity and decreases with higher blueshift of the gas. The column density of the absorbing HCCCN is 3-6 x 1E17 cm^2. We modeled spectra based on spherical models of the expanding envelope which provide an excellent fit to the observations, and discuss the implications of the models. Additionally, lines from 13C substituted cyanoacetylene were observed. They can be used to constrain the 12C/13C ratio in this source to 10+-2.Comment: 27 pages, 9 figures, to appear in Ap

Detection of a branched alkyl molecule in the interstellar medium: iso-propyl cyanide

The largest non-cyclic molecules detected in the interstellar medium (ISM) are organic with a straight-chain carbon backbone. We report an interstellar detection of a branched alkyl molecule, iso-propyl cyanide (i-C3H7CN), with an abundance 0.4 times that of its straight-chain structural isomer. This detection suggests that branched carbon-chain molecules may be generally abundant in the ISM. Our astrochemical model indicates that both isomers are produced within or upon dust grain ice mantles through the addition of molecular radicals, albeit via differing reaction pathways. The production of iso-propyl cyanide appears to require the addition of a functional group to a non-terminal carbon in the chain. Its detection therefore bodes well for the presence in the ISM of amino acids, for which such side-chain structure is a key characteristic.Comment: This is the author's version of the work. It is posted here by permission of the AAAS for non-commercial use. The definitive version was published in Science 345, 1584 (2014), doi:10.1126/science.125667

Complex organic molecules in the interstellar medium: IRAM 30 m line survey of Sagittarius B2(N) and (M)

The discovery of amino acids in meteorites and the detection of glycine in samples returned from a comet to Earth suggest that the interstellar chemistry is capable of producing such complex organic molecules. Our goal is to investigate the degree of chemical complexity that can be reached in the ISM. We performed an unbiased, spectral line survey toward Sgr B2(N) and (M) with the IRAM 30m telescope in the 3mm window. The spectra were analyzed with a simple radiative transfer model that assumes LTE but takes optical depth effects into account. About 3675 and 945 spectral lines with a peak signal-to-noise ratio higher than 4 are detected toward N and M, i.e. about 102 and 26 lines per GHz, respectively. This represents an increase by about a factor of 2 over previous surveys of Sgr B2. About 70% and 47% of the lines detected toward N and M are identified and assigned to 56 and 46 distinct molecules as well as to 66 and 54 less abundant isotopologues of these molecules, respectively. We also report the detection of transitions from 59 and 24 catalog entries corresponding to vibrationally or torsionally excited states of some of these molecules, respectively. Excitation temperatures and column densities were derived for each species but should be used with caution. Among the detected molecules, aminoacetonitrile, n-propyl cyanide, and ethyl formate were reported for the first time in space based on this survey, as were 5 rare isotopologues of vinyl cyanide, cyanoacetylene, and hydrogen cyanide. We also report the detection of transitions from within 12 new vib. or tors. excited states of known molecules. Although the large number of unidentified lines may still allow future identification of new molecules, we expect most of these lines to belong to vib. or tors. excited states or to rare isotopologues of known molecules for which spectroscopic predictions are currently missing. (abridged)Comment: Accepted for publication in A&A. 266 pages (39 pages of text), 111 tables, 8 figure