408 research outputs found
Self-steepening of light pulses
Self-steepening of light pulses due to propagation in medium with intensity-dependent index of refractio
Cold guided beams of water isotopologs
Electrostatic velocity filtering and guiding is an established technique to
produce high fluxes of cold polar molecules. In this paper we clarify different
aspects of this technique by comparing experiments to detailed calculations. In
the experiment, we produce cold guided beams of the three water isotopologs
H2O, D2O and HDO. Their different rotational constants and orientations of
electric dipole moments lead to remarkably different Stark shift properties,
despite the molecules being very similar in a chemical sense. Therefore, the
signals of the guided water isotopologs differ on an absolute scale and also
exhibit characteristic electrode voltage dependencies. We find excellent
agreement between the relative guided fractions and voltage dependencies of the
investigated isotopologs and predictions made by our theoretical model of
electrostatic velocity filtering.Comment: 14 pages, 13 figures; small changes to the text, updated reference
The Hyperfine Molecular Hubbard Hamiltonian
An ultracold gas of heteronuclear alkali dimer molecules with hyperfine
structure loaded into a one-dimensional optical lattice is investigated. The
\emph{Hyperfine Molecular Hubbard Hamiltonian} (HMHH), an effective low-energy
lattice Hamiltonian, is derived from first principles. The large permanent
electric dipole moment of these molecules gives rise to long range
dipole-dipole forces in a DC electric field and allows for transitions between
rotational states in an AC microwave field. Additionally, a strong magnetic
field can be used to control the hyperfine degrees of freedom independently of
the rotational degrees of freedom. By tuning the angle between the DC electric
and magnetic fields and the strength of the AC field it is possible to control
the number of internal states involved in the dynamics as well as the degree of
correlation between the spatial and internal degrees of freedom. The HMHH's
unique features have direct experimental consequences such as quantum
dephasing, tunable complexity, and the dependence of the phase diagram on the
molecular state
Electrostatic extraction of cold molecules from a cryogenic reservoir
We present a method which delivers a continuous, high-density beam of slow
and internally cold polar molecules. In our source, warm molecules are first
cooled by collisions with a cryogenic helium buffer gas. Cold molecules are
then extracted by means of an electrostatic quadrupole guide. For ND the
source produces fluxes up to molecules/s with
peak densities up to molecules/cm. For
HCO the population of rovibrational states is monitored by depletion
spectroscopy, resulting in single-state populations up to .Comment: 4 pages, 4 figures, changes to the text, updated figures and
reference
Surface temperature measurements using a thin film thermal array
A thin film device was designed and fabricated to measure surface temperatures. An array of eight integrated thermal sensors are mounted on a 0.002 inch (0.05 mm) Kapton film and multiplexed to obtain an area thermal measurement. The device was tested on a flat plate airfoil and demonstrated a temperature variation of 0.55 C maximum and 0.05 C minimum compared to embedded thermocouples. Future improvements are also discussed
On spin-rotation contribution to nuclear spin conversion in C_{3v}-symmetry molecules. Application to CH_3F
The symmetrized contribution of E-type spin-rotation interaction to
conversion between spin modifications of E- and A_1-types in molecules with
C_{3v}-symmetry is considered. Using the high-J descending of collisional
broadening for accidental rotational resonances between these spin
modifications, it was possible to co-ordinate the theoretical description of
the conversion with (updated) experimental data for two carbon-substituted
isotopes of fluoromethane. As a result, both E-type spin-rotation constants are
obtained. They are roughly one and a half times more than the corresponding
constants for (deutero)methane.Comment: 13 pages with single-spacing, REVTeX, no figures, accepted for
publication in <J. Phys. B
State-to-State Differential and Relative Integral Cross Sections for Rotationally Inelastic Scattering of H2O by Hydrogen
State-to-state differential cross sections (DCSs) for rotationally inelastic
scattering of H2O by H2 have been measured at 71.2 meV (574 cm-1) and 44.8 meV
(361 cm-1) collision energy using crossed molecular beams combined with
velocity map imaging. A molecular beam containing variable compositions of the
(J = 0, 1, 2) rotational states of hydrogen collides with a molecular beam of
argon seeded with water vapor that is cooled by supersonic expansion to its
lowest para or ortho rotational levels (JKaKc= 000 and 101, respectively).
Angular speed distributions of fully specified rotationally excited final
states are obtained using velocity map imaging. Relative integral cross
sections are obtained by integrating the DCSs taken with the same experimental
conditions. Experimental state-specific DCSs are compared with predictions from
fully quantum scattering calculations on the most complete H2O-H2 potential
energy surface. Comparison of relative total cross sections and state-specific
DCSs show excellent agreement with theory in almost all detailsComment: 46 page
Star Formation in M51 Triggered by Galaxy Interaction
We have mapped the inner 360'' regions of M51 in the 158micron [CII] line at
55'' spatial resolution using the Far-infrared Imaging Fabry-Perot
Interferometer (FIFI) on the Kuiper Airborne Observatory (KAO). The emission is
peaked at the nucleus, but is detectable over the entire region mapped, which
covers much of the optical disk of the galaxy. There are also two strong
secondary peaks at ~43% to 70% of the nuclear value located roughly 120'' to
the north-east, and south-west of the nucleus. These secondary peaks are at the
same distance from the nucleus as the corotation radius of the density wave
pattern. The density wave also terminates at this location, and the outlying
spiral structure is attributed to material clumping due to the interaction
between M51 and NGC5195. This orbit crowding results in cloud-cloud collisions,
stimulating star formation, that we see as enhanced [CII] line emission. The
[CII] emission at the peaks originates mainly from photodissociation regions
(PDRs) formed on the surfaces of molecular clouds that are exposed to OB
starlight, so that these [CII] peaks trace star formation peaks in M51. The
total mass of [CII] emitting photodissociated gas is ~2.6x10^{8} M_{sun}, or
about 2% of the molecular gas as estimated from its CO(1-0) line emission. At
the peak [CII] positions, the PDR gas mass to total gas mass fraction is
somewhat higher, 3-17%, and at the secondary peaks the mass fraction of the
[CII] emitting photodissociated gas can be as high as 72% of the molecular
mass.... (continued)Comment: 14 pages, 6 figures, Accepted in ApJ (for higher resolution figures
contact the author
Theory of nuclear spin conversion in ethylene
First theoretical analysis of the nuclear spin conversion in ethylene
molecules (13^CCH4) has been performed. The conversion rate was found equal
approx. 3x10^{-4} 1/s*Torr, which is in qualitative agreement with the recently
obtained experimental value. It was shown that the ortho-para mixing in 13^CCH4
is dominated by the spin-rotation coupling. Mixing of only two pairs of
ortho-para levels were found to contribute significantly to the spin
conversion.Comment: 20 pages, 5 eps figure
Theory of x-ray absorption by laser-aligned symmetric-top molecules
We devise a theory of x-ray absorption by symmetric-top molecules which are
aligned by an intense optical laser. Initially, the density matrix of the
system is composed of the electronic ground state of the molecules and a
thermal ensemble of rigid-rotor eigenstates. We formulate equations of motion
of the two-color (laser plus x rays) rotational-electronic problem. The
interaction with the laser is assumed to be nonresonant; it is described by an
electric dipole polarizability tensor. X-ray absorption is approximated as a
one-photon process. It is shown that the equations can be separated such that
the interaction with the laser can be treated independently of the x rays. The
laser-only density matrix is propagated numerically. After each time step, the
x-ray absorption is calculated. We apply our theory to study adiabatic
alignment of bromine molecules (Br2). The required dynamic polarizabilities are
determined using the ab initio linear response methods coupled-cluster singles
(CCS), second-order approximate coupled-cluster singles and doubles (CC2), and
coupled-cluster singles and doubles (CCSD). For the description of x-ray
absorption on the sigma_g 1s --> sigma_u 4p resonance, a parameter-free
two-level model is used for the electronic structure of the molecules. Our
theory opens up novel perspectives for the quantum control of x-ray radiation.Comment: 14 pages, 4 figures, 1 table, RevTeX4, revise
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