Non-local interactions in hydrodynamic turbulence at high Reynolds numbers: the slow emergence of scaling laws

We analyze the data stemming from a forced incompressible hydrodynamic simulation on a grid of 2048^3 regularly spaced points, with a Taylor Reynolds number of Re~1300. The forcing is given by the Taylor-Green flow, which shares similarities with the flow in several laboratory experiments, and the computation is run for ten turnover times in the turbulent steady state. At this Reynolds number the anisotropic large scale flow pattern, the inertial range, the bottleneck, and the dissipative range are clearly visible, thus providing a good test case for the study of turbulence as it appears in nature. Triadic interactions, the locality of energy fluxes, and structure functions of the velocity increments are computed. A comparison with runs at lower Reynolds numbers is performed, and shows the emergence of scaling laws for the relative amplitude of local and non-local interactions in spectral space. The scalings of the Kolmogorov constant, and of skewness and flatness of velocity increments, performed as well and are consistent with previous experimental results. Furthermore, the accumulation of energy in the small-scales associated with the bottleneck seems to occur on a span of wavenumbers that is independent of the Reynolds number, possibly ruling out an inertial range explanation for it. Finally, intermittency exponents seem to depart from standard models at high Re, leaving the interpretation of intermittency an open problem.Comment: 8 pages, 8 figure

Control of the MKQA tuning and aperture kickers of the LHC

The large hadron collider (LHC) at CERN has been equipped with four fast pulsed kicker magnets in RA43 situated at point 4 which are part of the measurement system for the tune and the dynamic aperture of the LHC beam (Beam 1 and Beam 2). For the tune measurement 'Q', the magnets will excite oscillations in part of the beam. This is achieved by means of a generator producing a 5 µs base half-sine pulse of 1.2 kA [1] amplitude, superimposed with a 3rd harmonic to produce a 2 µs flat top. A kick repetition rate of 2 Hz will be possible. To measure the dynamic aperture 'A' of the LHC at different beam energies, the same magnets will also be driven by a more powerful generator which produces a 43 µs base half-sine current pulse of 3.8 kA. For the 'A' mode a thyristor is used as switching element inside the generator. A final third mode named 'AC dipole' will rely on the beam being excited coherently at a frequency close but outside its Eigen-frequencies by an oscillating dipole field. The beam is expected to oscillate at the exciter frequency of 3 kHz with a phase shift of π/2. The 'AC dipole' will use two 18 kW audio amplifiers capable of driving the magnets at 1 kHz(rms) around 3 kHz or between 2.7 kHz and 4 kHz. The complete system uses supervisory control implemented with Siemens PLC technology with added Siemens PROFIsafe safety feature to treat the various interlocks that have been introduced in the circuits and to assu re a safe functioning and provide 'LOCAL' and 'REMOTE' control (via CCC) of the complete installation

Large scale flow effects, energy transfer, and self-similarity on turbulence

The effect of large scales on the statistics and dynamics of turbulent fluctuations is studied using data from high resolution direct numerical simulations. Three different kinds of forcing, and spatial resolutions ranging from 256^3 to 1024^3, are being used. The study is carried out by investigating the nonlinear triadic interactions in Fourier space, transfer functions, structure functions, and probability density functions. Our results show that the large scale flow plays an important role in the development and the statistical properties of the small scale turbulence. The role of helicity is also investigated. We discuss the link between these findings and intermittency, deviations from universality, and possible origins of the bottleneck effect. Finally, we briefly describe the consequences of our results for the subgrid modeling of turbulent flows

Spin-polarized oxygen hole states in cation deficient La(1-x)CaxMnO(3+delta)

When holes are doped into a Mott-Hubbard type insulator, like lightly doped manganites of the La(1-x)CaxMnO3 family, the cooperative Jahn-Teller distortions and the appearance of orbital ordering require an arrangement of Mn(3+)/Mn(4+) for the establishment of the insulating canted antiferromagnetic (for x<=0.1), or of the insulating ferromagnetic (for 0.1<x<= 0.2) ground state. In the present work we provide NMR evidence about a novel and at the same time puzzling effect in La(1-x)CaxMnO(3+delta) systems with cation deficience. We show that in the low Ca-doping regime, these systems exhibit a very strong hyperfine field at certain La nuclear sites, which is not present in the stoichiometric compounds. Comparison of our NMR results with recent x-ray absorption data at the Mn K edge, suggests the formation of a spin-polarized hole arrangement on the 2p oxygen orbitals as the origin of this effect.Comment: 10 pages, 4 Figures, submitted to PR

A new application of solvent extraction to separate copper from extreme acid mine drainage producing solutions for electrochemical and biological recovery processes

Over the last decade, AMD waters have gained more attention as a potential source of metals due to the emerging need to recover or recycle metals from secondary resources. Metals recovery supports sustainability and the development of a circular economy with benefits for resource conservation and the environment. In this study, five extractants (Acorga M5640, LIX 54, LIX 622, LIX 622 N, and LIX 864) diluted (15% (v/v)) in Shell GTL with 2.5% (v/v) octanol were compared and evaluated for Cu recovery from an extreme AMD sample (5.3 +/- 0.3 g/L Cu) collected at the inactive Sao Domingos Mine in the Iberian Pyrite Belt of Portugal. Of the five extractants, Acorga M5640 showed the best selective efficiency. Further tests showed that 30% (v/v) of this extractant was able to selectively extract approximate to 96.0% of the Cu from the AMD in one extraction step and all of the remaining Cu (to below detection) in three steps. Among the different stripping agents tested, 2 M sulfuric acid was the most efficient, with approximate to 99% of the Cu stripped, and the recyclability of the organic phase was confirmed in five successive cycles of extraction and stripping. Furthermore, contact time tests revealed that the extraction kinetics allows the transfer of approximate to 97% of the Cu in 15 min, and aqueous to organic phase ratios tests demonstrated a maximum loading capacity of approximate to 16 g/L Cu in the organic phase. Raising the concentration of Cu in the stripping solution (2 M sulfuric acid) to approximate to 46 g/L through successive striping steps showed the potential to recover elemental Cu using traditional electrowinning. Finally, a biological approach for Cu recovery from the stripping solution was evaluated by adding the supernatant of a sulfate-reducing bacteria culture to make different molar ratios of biogenic sulfide to copper; ratios over 1.75 resulted in precipitation of more than 95% of the Cu as covellite nanoparticles.info:eu-repo/semantics/publishedVersio

3-CMC, 4-CMC, and 4-BMC Human Metabolic Profiling: New Major Pathways to Document Consumption of Methcathinone Analogues?

Abstract Synthetic cathinones represent one of the largest and most abused new psychoactive substance classes, and have been involved in numerous intoxications and fatalities worldwide. Methcathinone analogues like 3-methylmethcathinone (3-MMC), 3-chloromethcathinone (3-CMC), and 4-CMC currently constitute most of synthetic cathinone seizures in Europe. Documenting their consumption in clinical/forensic casework is therefore essential to tackle this trend. Targeting metabolite markers is a go-to to document consumption in analytical toxicology, and metabolite profling is crucial to support investigations. We sought to identify 3-CMC, 4-CMC, and 4-bromomethcathinone (4-BMC) human metabolites. The substances were incubated with human hepatocytes; incubates were screened by liquid chromatography-high-resolution tandem mass spectrometry and data were mined with Compound Discoverer (Themo Scientifc). 3-CMC-positive blood, urine, and oral fuid and 4-CMCpositive urine and saliva from clinical/forensic casework were analyzed. Analyses were supported by metabolite predictions with GLORYx freeware. Twelve, ten, and ten metabolites were identifed for 3-CMC, 4-CMC, and 4-BMC, respectively, with similar transformations occurring for the three cathinones. Major reactions included ketoreduction and N-demethylation. Surprisingly, predominant metabolites were produced by combination of N-demethylation and ω-carboxylation (main metabolite in 3-CMC-positive urine), and combination of β-ketoreduction, oxidative deamination, and O-glucuronidation (main metabolite in 4-CMC-positive urine). These latter metabolites were detected in negative-ionization mode only and their non-conjugated form was not detected after glucuronide hydrolysis; this metabolic pathway was never reported for any methcathinone analogue susceptible to undergo the same transformations. These results support the need for comprehensive screening strategies in metabolite identifcation studies, to avoid overlooking signifcant metabolites and major markers of consumptio