On the possibility of spontaneous currents in mesoscopie systems

It is shown that a mesoscopic metallic system can exhibit a phase transition to a low temperature state with a spontaneous orbital current if it is sufficiently free of elastic defect scattering. The interaction among the electrons, which is the reason of the phase transition, is of the magnetic origin and it leads to an ordered state of the orbital magnetic moments

Manipulating nonequilibrium magnetism through superconductors

Electrostatic control of the magnetization of a normal mesoscopic conductor is analyzed in a hybrid superconductor-normal-superconductor system. This effect stems from the interplay between the non-equilibrium condition in the normal region and the Zeeman splitting of the quasiparticle density of states of the superconductor subjected to a static in-plane magnetic field. Unexpected spin-dependent effects such as magnetization suppression, diamagnetic-like response of the susceptibility as well as spin-polarized current generation are the most remarkable features presented. The impact of scattering events is evaluated and let us show that this effect is compatible with realistic material properties and fabrication techniques.Comment: 5 pages, 4 figure

Vortex lattices in a stirred Bose-Einstein condensate

We stir with a focused laser beam a Bose-Einstein condensate of $^{87}$Rb atoms confined in a magnetic trap. We observe the formation of a single vortex for a stirring frequency exceeding a critical value. At larger rotation frequencies we produce states of the condensate for which up to eleven vortices are simultaneously present. We present measurements of the decay of a vortex array once the stirring laser beam is removed

Current-Carrying Ground States in Mesoscopic and Macroscopic Systems

We extend a theorem of Bloch, which concerns the net orbital current carried by an interacting electron system in equilibrium, to include mesoscopic effects. We obtain a rigorous upper bound to the allowed ground-state current in a ring or disc, for an interacting electron system in the presence of static but otherwise arbitrary electric and magnetic fields. We also investigate the effects of spin-orbit and current-current interactions on the upper bound. Current-current interactions, caused by the magnetic field produced at a point r by a moving electron at r, are found to reduce the upper bound by an amount that is determined by the self-inductance of the system. A solvable model of an electron system that includes current-current interactions is shown to realize our upper bound, and the upper bound is compared with measurements of the persistent current in a single ring.Comment: 7 pager, Revtex, 1 figure available from [email protected]

Thermal expansion, heat capacity and magnetostriction of RAl3_3 (R = Tm, Yb, Lu) single crystals

We present thermal expansion and longitudinal magnetostriction data for cubic RAl3 (R = Tm, Yb, Lu) single crystals. The thermal expansion coefficient for YbAl3 is consistent with an intermediate valence of the Yb ion, whereas the data for TmAl3 show crystal electric field contributions and have strong magnetic field dependencies. de Haas-van Alphen-like oscillations were observed in the magnetostriction data of YbAl3 and LuAl3, several new extreme orbits were measured and their effective masses were estimated. Zero and 140 kOe specific heat data taken on both LuAl3 and TmAl3 for T < 200 K allow for the determination of a CEF splitting scheme for TmAl3

Superconductivity in the SU(N) Anderson Lattice at U=\infty

We present a mean-field study of superconductivity in a generalized N-channel cubic Anderson lattice at U=\infty taking into account the effect of a nearest-neighbor attraction J. The condition U=\infty is implemented within the slave-boson formalism considering the slave bosons to be condensed. We consider the $f$-level occupancy ranging from the mixed valence regime to the Kondo limit and study the dependence of the critical temperature on the various model parameters for each of three possible Cooper pairing symmetries (extended s, d-wave and p-wave pairing) and find interesting crossovers. It is found that the d- and p- wave order parameters have, in general, very similar critical temperatures. The extended s-wave pairing seems to be relatively more stable for electronic densities per channel close to one and for large values of the superconducting interaction J.Comment: Seven Figures; one appendix. Accepted for publication in Phys. Rev.

Comparison of metal-based nanoparticles and nanowires: Solubility, reactivity, bioavailability and cellular toxicity

While the toxicity of metal-based nanoparticles (NP) has been investigated in an increasing number of studies, little is known about metal-based fibrous materials, so-called nanowires (NWs). Within the present study, the physico-chemical properties of particulate and fibrous nanomaterials based on Cu, CuO, Ni, and Ag as well as TiO$_{2}$ and CeO$_{2}$ NP were characterized and compared with respect to abiotic metal ion release in different physiologically relevant media as well as acellular reactivity. While none of the materials was soluble at neutral pH in artificial alveolar fluid (AAF), Cu, CuO, and Ni-based materials displayed distinct dissolution under the acidic conditions found in artificial lysosomal fluids (ALF and PSF). Subsequently, four different cell lines were applied to compare cytotoxicity as well as intracellular metal ion release in the cytoplasm and nucleus. Both cytotoxicity and bioavailability reflected the acellular dissolution rates in physiological lysosomal media (pH 4.5); only Ag-based materials showed no or very low acellular solubility, but pronounced intracellular bioavailability and cytotoxicity, leading to particularly high concentrations in the nucleus. In conclusion, in spite of some quantitative differences, the intracellular bioavailability as well as toxicity is mostly driven by the respective metal and is less modulated by the shape of the respective NP or NW

Possibility of long-range order in clean mesoscopic cylinders

A microscopic Hamiltonian of the magnetostatic interaction is discussed. This long-range interaction can play an important role in mesoscopic systems leading to an ordered ground state. The self-consistent mean field approximation of the magnetostatic interaction is performed to give an effective Hamiltonian from which the spontaneous, self-sustaining currents can be obtained. To go beyond the mean field approximation the mean square fluctuation of the total momentum is calculated and its influence on self-sustaining currents in mesoscopic cylinders with quasi-1D and quasi-2D conduction is considered. Then, by the use of the microscopic Hamiltonian of the magnetostatic interaction for a set of stacked rings, the problem of long-range order is discussed. The temperature $T^{*}$ below which the system is in an ordered state is determined.Comment: 14 pages, REVTeX, 5 figures, in print in Phys. Rev.

Electron Dephasing in Mesoscopic Metal Wires

The low-temperature behavior of the electron phase coherence time, $\tau_{\phi}$, in mesoscopic metal wires has been a subject of controversy recently. Whereas theory predicts that $\tau_{\phi}(T)$ in narrow wires should increase as $T^{-2/3}$ as the temperature $T$ is lowered, many samples exhibit a saturation of $\tau_{\phi}$ below about 1 K. We review here the experiments we have performed recently to address this issue. In particular we emphasize that in sufficiently pure Ag and Au samples we observe no saturation of $\tau_{\phi}$ down to our base temperature of 40 mK. In addition, the measured magnitude of $\tau_{\phi}$ is in excellent quantitative agreement with the prediction of the perturbative theory of Altshuler, Aronov and Khmelnitskii. We discuss possible explanations why saturation of $\tau_{\phi}$ is observed in many other samples measured in our laboratory and elsewhere, and answer the criticisms raised recently by Mohanty and Webb regarding our work.Comment: 14 pages, 3 figures; to appear in proceedings of conference "Fundamental Problems of Mesoscopic Physics", Granada, Spain, 6-11 September, 200

Online-Überwachung eines Fermentationsprozesses mit Reflektometrischer Interferenzspektroskopie

Die prozessnahe online-Überwachung von biotechnologischen Prozessen gewinnt zunehmend an Bedeutung. Dabei werden von der Industrie vermehrt schnelle und genaue Analysenmethoden gefordert, um Kultivierungsbedingungen optimieren und die Fermentationsdauer reduzieren zu können. Bisher werden meist nur allgemeine Paramter wie Druck, Temperatur oder pH-Wert online verfolgt. Eine produktspezifische Analytik erfolgt größtenteils offline. D. h. die Proben werden manuell gezogen und nachfolgend in einem Labor analysiert. Eine solche Prozedur ist fast immer sehr arbeitsaufwändig und teuer. Problematisch kann auch die zeitliche Verzögerung zwischen Fermentationsprozess und Analysenergebnis sein. Insbesondere bei Batch-Fermentationen kann es bei Überproduktion zu Neben- und Abbauprodukten kommen. Wünschenswert ist deshalb eine zeitnahe, möglichst prozessintegrierte Anayltik, um gezielt den Fermentationprozess steuern zu können. In unserer Arbeitsgruppe wurde ein optischer Biosensor entwickelt, der eine produktspezifische, schnelle online-Überwachung eines Fermentationsprozesses erlaubt. Modellhaft wurde dabei die Produktion des Antibiotikums Vancomycin während einer Fermentation verfolgt. Die Wirkungsweise des Vancomycins beruht auf einer spezifischen Bindung an Mukopeptidvorstufen, die auf die Sequenz D-Alanin-D-Alanin enden. Um eine spezifische Detektion von Vancomycin zu erreichen wurden entsprechende Peptide kovalent auf ein Glasssubstrat immobilisiert und die Wechselwirkung zwischen der Oberfläche und Vancomycin mittels Reflektometrischer Interferenzspektroskopie (RIfS) verfolgt