Notes on magnetohydrodynamics, part ii

Simple waves and covariant formulation related to magnetohydrodynamics and derivation of equations for one-dimensional wave propagation and Riemann invariants for fast and slow wave

Some reactions of phosphorus compounds as studied by 31p nmr techniques

The solution chemistry of some simple phosphorus halides has been investigated in sulphuric acid, oleums, and halo-substituted sulphuric acids by (^31) p n.m.r. spectroscopy. Solution of phosphorus (III) compounds was accompanied by oxidation to the phosphorus (V) state. The phosphorus (V) species so formed as well as those derived directly from phosphorus (V) halides and oxyhalides were stable over measurable periods of time. Solvolysis of phosphorus (V) – halogen bonds occurred in all the solvents, with some complications arising in the halo-substituted acids where halogen exchange was observed. Oxidation of some phosphorus (III) halides by halogens produced phosphorus (V) - halo species which were stabilized by solution in these highly acidic solvents. The (^31) p n.m.r. solution spectrum of various phosphorus (V) - iodine species have been recorded for the first time with the help of a pulsed Fourier Transform instrument capable of studying reacting systems. The solution chemistry of a series of phenyl organophosphoryl compounds in these acid solvents has also been investigated by (^31) P n.m.r. Protonation of the phosphoryl group takes place in all of the solvents, as well as sulphonation of the phenyl ring in 25% and 65% oleum, and to a lesser extent in ClHSO (_3). Mixed halo and organohalo phosphorus (V) compounds such as [PCl (_N) Br (_4-n)] (^+) A (^-), R (_N) PX (_5-n), [R (_n) PX (_4-n)] (^+) A (^-), where X = Cl or Br and A (^-) is an anion, dissolve in 25% oleum with the formation of stable phosphonium cations. An investigation of the solution chemistry of phenoxyhalophosphoranes indicates that the stable species in the system are the non halo containing (PhO) (_4) p (^+) cation and (PhO) (_5) P, neither of which show acceptor properties towards pyridine or chloride ions. A limited investigation of the Lewis acid properties of PI (_3) towards pyridines and the Lewis base properties of PI (_3) towards BBr (_3) and BIr (_3) suggests that coordination complexes are formed in both systems. Oxidation of PI (_3) has been attempted by means of halogens and other halogen-containing oxidizing agents. No direct evidence for the formation of phosphorus (V)-iodine species was obtained, although reactions with SbCl (_5) and PCl (_5) produced unstable compounds which decomposed at low temperature liberating iodine

Photonic qubits, qutrits and ququads accurately prepared and delivered on demand

Reliable encoding of information in quantum systems is crucial to all approaches to quantum information processing or communication. This applies in particular to photons used in linear optics quantum computing (LOQC), which is scalable provided a deterministic single-photon emission and preparation is available. Here, we show that narrowband photons deterministically emitted from an atom-cavity system fulfill these requirements. Within their 500 ns coherence time, we demonstrate a subdivision into d time bins of various amplitudes and phases, which we use for encoding arbitrary qu-d-its. The latter is done deterministically with a fidelity >95% for qubits, verified using a newly developed time-resolved quantum-homodyne method.Comment: 5 pages, 4 figure

Media(ted) fabrications: How the science-media symbiosis helped ‘sell’ cord banking

This paper considers the problematic role of the science–media symbiosis in the dissemination of misleading and emotionally manipulative information regarding services offered by CordBank, New Zealand's only umbilical cord blood banking facility. As this case study illustrates, the growing reliance of health and science reporters on the knowledge capital of medical specialists, biogenetic researchers, and scientists potentially enhances the ability of ‘expert’ sources to set the agenda for media representations of emerging medical and scientific developments, and may undermine the editorial independence of journalists and editors, many of whom in this case failed to critically evaluate deeply problematic claims regarding the current and future benefits of cord banking. Heavy reliance on established media frames of anecdotal personalization and technoboosterism also reinforced a proscience journalistic culture in which claims by key sources were uncritically reiterated and amplified, with journalistic assessments of the value of cord banking emphasizing potential benefits for individual consumers. It is argued that use of these media frames potentially detracts from due consideration of the broader social, ethical, legal, and health implications of emerging biomedical developments, along with the professional, personal, and increasingly also financial interests at stake in their public promotion, given the growing commercialization of biogenetic technologies

Proton configurations in the hydrogen bonds of KH2PO4 as seen by resonant x-ray diffraction

KH2PO4 (KDP) belongs to the class of hydrogen-bonded ferroelectrics, whose paraelectric to ferroelectric phase transition is driven by the ordering of the protons in the hydrogen bonds. We demonstrate that forbidden reflections of KDP, when measured at an x-ray absorption edge, are highly sensitive to the asymmetry of proton configurations. The change of average symmetry caused by the "freezing" of the protons during the phase transition is clearly evidenced. In the paraelectric phase, we identify in the resonant spectra of the forbidden reflections a contribution related to the transient proton configurations in the hydrogen bonds, which violates the high average symmetry of the sites of the resonant atoms. The analysis of the temperature dependence reveals a change of relative probabilities of the different proton configurations. They follow the Arrhenius law, and the activation energies of polar and Slater configurations are 18.6 and 7.3 meV, respectively

The Prehistoric Fishers and Gatherers of the Northern and Western Coasts of the Arabian Sea

This chapter is a review of the prehistory of the fisher-gatherers who settled along the coasts of the Arabian Sea and the Gulf of Oman. Previous research and studies have been centred mainly on the western coasts of the Indian Ocean. They have presented and discussed the general patterns and chronological frame of the coastal human adaptation since the early Holocene, and the recurrent presence of shell middens located close to mangrove environments. More recent research has been focussed on the northern shores of the Arabian Sea. From this region we have new evidence of the presence of fisher-gatherers communities that seasonally settled along the ancient coastline and islands of south-western Sindh and Las Bela (Balochistan) since the end of the eighth millennium BP indicating that early navigation already took place in that period. According to the archaeological evidence, the subsistence activities of these human groups were varied though seasonally based mainly on fishing and shellfish gathering. Broadly speaking marine and mangrove resources were widespread exploited along the two coasts of the Arabian Sea during favourable, well-defined periods of coastal adaptation following the varied environmental conditions and sea-level changes that took place since the beginning of the Holocene

Designing avionics for lasers & optoelectronics

Unlike imagery-based Earth observation (EO) which has become very widely and cheaply available, gravity sensing EO has not yet emerged from its fundamental science roots. The challenge therefore is to develop gravity sensing instruments that can replicate the success of widespread imagery based EO. There are three main gravity sensing mechanisms under investigation: laser ranging (e.g., GRACE-FO [1]); atom interferometers, which measure gravitation perturbations to the wavefunctions of individual atoms; and ‘relativistic geodesy’ which uses atomic clocks to measure the gravitational curvature of spacetime. All three of these measurement systems use stabilised lasers as their main enabling technology. However traditional laboratory laser systems struggle to meet the robustness, reliability, or low size, weight, and power (SWaP) requirements for use in space. A demonstrator was build that adapted telecommunications industry COTS components, and software radio FPGA/DSP techniques, to develop a new all-fibre space-qualified stabilised laser systems for geodesy that have equivalent performance to laboratory systems. This instrument was used to develop a 780 nm laser system that is stabilised to the Rubidium D2 line - the stabilised laser most commonly required by the quantum and atomic sensing field achieving sufficiently high laser performance for the laser system to be immediately useful for quantum applications (stability: 1-10 kHz, accuracy: 1 MHz); and in an ultra-compact package that has the potential to be used in space (1 litre, 0.5 kg, 10 W) [2]. This paper reports on the current student work that advances the instrument further towards a flight payload – and key avionics design considerations for future researchers. This takes lessons learnt from the ESA ESEO software radio payload in utilising ECSS design practices [3] to fabricate a robust and modular avionics back-end board that can operate with numerous front-end laser or opto-electronics configurations for different quantum applications. The new board consists of a single PCB containing circuitry for TT&C reporting of power supply and voltage conditioning, the current and temperature electronics needed to control a diode laser on orbit, interfaces for photo detectors and opto-electronics, and a high-speed analogue- to-digital conversion network centred around a FPGA. As an example, digital signal processing performed frequency-modulated spectroscopy on a warm Rubidium vapour using an all-fibre optical arrangement

Methane Mitigation:Methods to Reduce Emissions, on the Path to the Paris Agreement

The atmospheric methane burden is increasing rapidly, contrary to pathways compatible with the goals of the 2015 United Nations Framework Convention on Climate Change Paris Agreement. Urgent action is required to bring methane back to a pathway more in line with the Paris goals. Emission reduction from “tractable” (easier to mitigate) anthropogenic sources such as the fossil fuel industries and landfills is being much facilitated by technical advances in the past decade, which have radically improved our ability to locate, identify, quantify, and reduce emissions. Measures to reduce emissions from “intractable” (harder to mitigate) anthropogenic sources such as agriculture and biomass burning have received less attention and are also becoming more feasible, including removal from elevated-methane ambient air near to sources. The wider effort to use microbiological and dietary intervention to reduce emissions from cattle (and humans) is not addressed in detail in this essentially geophysical review. Though they cannot replace the need to reach “net-zero” emissions of CO2, significant reductions in the methane burden will ease the timescales needed to reach required CO2 reduction targets for any particular future temperature limit. There is no single magic bullet, but implementation of a wide array of mitigation and emission reduction strategies could substantially cut the global methane burden, at a cost that is relatively low compared to the parallel and necessary measures to reduce CO2, and thereby reduce the atmospheric methane burden back toward pathways consistent with the goals of the Paris Agreement