Thermal decomposition of single hydroxychlorides of nickel, copper and cobalto

The thermal decomposition reactions of Ni(OH)Cl.l½H20 in still air and in nitrogen and β-CO2(OH)3Cl and γ-Cu2(OH)3Cl in nitrogen atmosphere, have been studied by DTA and TG analysis, and the intermediates and final products have been characterized by x-ray diffraction and infrared spectroscop. The thermal evolution ot the above indicated compounds under dynamic vacuum conditions has be en studied with the aid of an x-ray high teaperature diffraction chamber. They reveals that in these conditions, the pure metallic nickel, copper and cobalt can be obtained at comparative low temperature. The infrared spectra of thése hydroxychlorides have been tentatively assigned

Paleoliquefaction in the Bajo Segura basin (eastern Betic Cordillera)

The Bajo Segura basin, in the eastern Betic Cordillera, displays a seismic activity characterized by small-magnitude earthquakes (1.5-4.5 mb), with some occasional moderate to high-magnitude events (> 5.0 mb). These earthquakes are produced by the activity of blind faults without surface ruptures. For this reason, the detection of paleoearthquakes in the geological record is limited to indirect evidence of paleoseismicity, mainly liquefaction features. Moreover, such evidence is abundant in the historical record of the 1829 Torrevieja earthquake, in some of its aftershocks and in the 1919 Jacarilla earthquake. In this study several layers of Holocene seismites previously described in the basin were analyzed, and correlated with various radiometric 14C datings. This analysis enabled a recurrence period of approx. 1000 yr to be established for the moderate to high-magnitude earthquakes in the Bajo Segura basin

Modeling Star counts in the Monoceros stream and the Galactic anti-centre

There is a continued debate as to the form of the outer disc of the Milky Way galaxy, which has important implications for its formation. Stars are known to exist at a galacto-centric distance of at least 20 kpc. However, there is much debate as to whether these stars can be explained as being part of the disc or whether another extra galactic structure, the so called Monoceros ring/stream, is required. To examine the outer disc of the Galaxy toward the anti-centre to determine whether the star counts can be explained by the thin and thick discs alone. Using Sloan star counts and extracting the late F and early G dwarfs it is possible to directly determine the density of stars out to a galacto-centric distance of about 25 kpc. These are then compared with a simple flared disc model. A flared disc model is shown to reproduce the counts along the line of sights examined, if the thick disc does not have a sharp cut off. The flare starts at a Galacto-centric radius of 16 kpc and has a scale length of 4.5+/-1.5 kpc. Whilst the interpretation of the counts in terms of a ring/stream cannot be definitely discounted, it does not appear to be necessary, at least along the lines of sight examined towards the anti centre.Comment: 11 pages, 4 figures, accepted to be published in A&

Study of the thermal behavior of the aluminium dust stabilized with gypsum

[ES]El polvo de aluminio (pAl) es un residuo peligroso procedente de la metalurgia secundaría del aluminio. Con objeto de reducir la reactividad del mismo, en el CENIM se ha desarrollado un proceso de estabilización/solidificación mediante su fraguado con yeso. En este trabajo se presenta el estudio del comportamiento térmico del pAl estabilizado con el yeso, con el fin de establecer la influencia del residuo en las reacciones de hidratación/deshidratación del yeso durante el proceso del fraguado, a saber: deshidratación parcial del sulfato calcico dihidrato, deshidratación del hemihidrato, deshidratación del hidróxido de aluminio y transformación de anhidrita soluble en anhidrita insoluble. Asimismo se ha estudiado la cinética asociada a cada una de las reacciones anteriormente mencionadas mediante Calorimetría Diferencial de Barrido.[EN]The aluminium dust is a hazardous waste from the secondary aluminium remelting industry. A stabilization/solidification process was developed at CENIM with the aim of decreasing its reactivity. Gypsum was used as a binder material. Tliis work summarizes the study of the thermal behavior of the aluminium dust stabilized with gypsum, in order to establish the influence of the residue in the reactions of hydration/dehydration of the gypsum during the hardening process, namely: partial dehydration of calcium sulphate dihydrate, dehydration of calcium sulphate hemi'hydrate, dehydration of aluminium hydroxide and anhydrite soluble/anhydrite insoluble transformation. The activation energy associated to all those reactions was determined by Differential Scanning Calorimetry.Los autores agradecen a la Consejería de Educación de la Comunidad de Madrid la financiación del proyecto (07M/0136/2000) y a la empresa Recuperación y Reciclaje Román por el apoyo a esta investigación.Peer reviewe

Validation Study of the Use of Matlab/Simulink Synchronous-Machine Block for Accurate Power-Plant Stability Studies

This paper presents results of the validity study of the use of MATLAB/Simulink synchronous-machine block for power-system stability studies. Firstly, the waveforms of the theoretical synchronous-generator short-circuit currents are described. Thereafter, the comparison between the currents obtained through the simulation model in the sudden short-circuit test, are compared to the theoretical ones. Finally, the factory tests of two commercial generating units are compared to the response of the synchronous generator simulation block during sudden short-circuit, set with the same real data, with satisfactory results. This results show the validity of the use of this generator block for power plant simulation

Google Scholar Metrics evolution: an analysis according to languages

The final publication is available at Springer via http://dx.doi.org/10.1007/s11192-013-1164-8In November 2012 the Google Scholar Metrics (GSM) journal rankings were updated, making it possible to compare bibliometric indicators in the ten languages indexed—and their stability—with the April 2012 version. The h-index and h-5 median of 1,000 journals were analysed, comparing their averages, maximum and minimum values and the correlation coefficient within rankings. The bibliometric figures grew significantly. In just seven and a half months the h-index of the journals increased by 15 % and the median h-index by 17 %. This growth was observed for all the bibliometric indicators analysed and for practically every journal. However, we found significant differences in growth rates depending on the language in which the journal is published. Moreover, the journal rankings seem to be stable between April and November, reinforcing the credibility of the data held by Google Scholar and the reliability of the GSM journal rankings, despite the uncontrolled growth of Google Scholar. Based on the findings of this study we suggest, firstly, that Google should upgrade its rankings at least semi-annually and, secondly, that the results should be displayed in each ranking proportionally to the number of journals indexed by language.Orduña Malea, E.; Delgado López-Cózar, E. (2014). Google Scholar Metrics evolution: an analysis according to languages. Scientometrics. 98(3):2353-2367. doi:10.1007/s11192-013-1164-8S23532367983Aguillo, & Isidro, F. (2012). Is Google Scholar useful for bibliometrics? A webometric analysis. Scientometrics, 91(2), 343–351.Brewington, B. E., & Cybenko, G. (2000). How dynamic is the Web? Computer Networks, 33(1–6), 257–276.Chen, X. (2010). Google Scholar’s dramatic coverage improvement five years after debut. Serials Review, 36(4), 221–226.Cho, Y. & Garcia-Molina, H. (2000). The evolution of the web and implications for an incremental crawler. Proceedings of the 26th International Conference on very large data bases, 200–209.Costas, R., & Bordons, M. (2007). The h-index: advantages, limitations and its relation with other bibliometric indicators at the micro level. Journal of Informetrics, 1(3), 193–203.de Winter, J. C. F., Zadpoor, A. A., & Dodou, D. (2013). The expansion of Google Scholar versus Web of Science: a longitudinal study. Scientometrics. doi: 10.1007/s11192-013-1089-2 .Delgado López-Cózar, E., & Cabezas-Clavijo, A. (2012). Google Scholar Metrics: an unreliable tool for assessing scientific journals. El profesional de la información, 21(4), 419–427.Delgado López-Cózar, E., & Cabezas-Clavijo, A. (2013). Ranking journals: could Google Scholar metrics be an alternative to journal citation reports and Scimago journal ranks. Learned publishing, 26(2), 101–114.Fetterly, D., Manasse, M., Najork, M. & Wiener, J. (2003). A large scale study of the evolution of web pages. Proceedings of the Twelfth International Conference on World Wide Web, 669–678.Harzing, A.-W. (2013). A preliminary test of Google Scholar as a source for citation data: a longitudinal study of Nobel prize winners. Scientometrics, 94(3), 1057–1075.Jacsó, P. (2012). Google Scholar Metrics for Publications—The software and content feature of a new open access bibliometric service. Online Information Review, 36(4), 604–619.Koehler, W. (2002). Web page change and persistence-4-year longitudinal web study. Journal of the American Society for Information Science and Technology, 53(2), 162–171.Koehler, W (2004). A longitudinal study of Web pages continued a consideration of document persistence. Information Research, 9(2). http://informationr.net/ir/9-2/paper174.html . Accessed 1 Sep 2013.Kousha, K., & Thelwall, M. (2007). Google Scholar Citations and Google Web/URL citations: a multidiscipline exploratory analysis. Journal of the American Society for Information Science and Technology, 58(7), 1055–1065.Leydesdorff, L. (2012). World shares of publications of the USA, EU-27, and China compared and predicted using the new Web of Science interface versus Scopus. El profesional de la información, 21(1), 43–49.Neuhaus, C., Neuhaus, E., Asher, A., & Wrede, C. (2006). The depth and breadth of Google Scholar: An empirical study. Libraries and the Academy, 6(2), 127–141.Orduña-Malea, E., Serrano-Cobos, J., & Lloret-Romero, N. (2009). Las universidades públicas españolas en Google Scholar: presencia y evolución de su publicación académica web. El profesional de la información, 18(5), 493–500.Orduña-Malea, E., Serrano-Cobos, J., Ontalba-Ruipérez, J.-A., & Lloret-Romero, N. (2010). Presencia y visibilidad web de las universidades públicas españolas. Revista española de documentación científica, 33(2), 246–278.Ortega, J. L., Aguillo, I. F., & Prieto, J. A. (2006). Longitudinal study of contents and elements in the scientific Web environment. Journal of Information Science, 32(4), 344–351.Payne, N., & Thelwall, M. (2007). A longitudinal study of academic webs: growth and stabilization. Scientometrics, 71(3), 523–539

Nanoparticles doped with methyl jasmonate: foliar application to Monastrell vines under two watering regimes. An alternative to improve grape volatile composition?

Financial support was given by the Ministerio de Ciencia, Innovación y Universidades for projects RTI2018‐096549‐B‐I00 and RTI‐2018‐095794‐A‐C22. EP Pérez‐Álvarez thanks the Ministerio de Ciencia, Innovación y Universidades for her Juan de la Cierva‐Incorporación postdoctoral contract (IJC2019‐040502‐I). GBRR also acknowledges the Junta de Andalucía for her postdoctoral contract within the PAIDI 2020 program (DOC_01383).Background: Elicitors induce defense mechanisms, triggering the synthesis of secondary metabolites. Irrigation has implications for a more sustainable viticulture and for grape composition. The aim was to investigate the influence on grape aroma composition during 2019 and 2020 of the foliar application of amorphous calcium phosphate (ACP) nanoparticles and ACP doped with methyl jasmonate (ACP-MeJ), as an elicitor, with rainfed or regulated deficit irrigation (RDI) grapevines. Results: In both growing seasons, nearly all terpenoids, C13 norisoprenoids, benzenoid compounds and alcohols increased with ACP-MeJ under the RDI regimen. In 2019, under the rainfed regime, ACP treatment increased limonene, p-cymene, α-terpineol, 1,1,6-trimethyl-1,2-dihydronaphthalene (TDN), 2-ethyl-1-hexanol, (E,E)-2,4-heptadienal, and MeJ concentration in comparison with control grapes. In 2020, the rainfed regime treated with ACP-MeJ only increased the nonanoic acid content. Grape volatile compounds were most influenced by season and watering status whereas the foliar application mainly affected the terpenoids. Conclusion: A RDI regime combined with the elicitor ACP-MeJ application could improve the synthesis of certain important volatile compounds, such as p-cymene, linalool, α-terpineol, geranyl acetone, β-ionone, 2-phenylethanol, benzyl alcohol, and nonanoic acid in Monastrell grapes. © 2023 The Authors. Journal of The Science of Food and Agriculture published by John Wiley & Sons Ltd on behalf of Society of Chemical Industry.Ministerio de Ciencia, Innovación y Universidades RTI2018‐096549‐B‐I00, RTI‐2018‐095794‐A‐C22, IJC2019‐040502‐I MCIUJunta de Andalucía DOC_0138

Application of Elicitors, as Conventional and Nano Forms, in Viticulture: Effects on Phenolic, Aromatic and Nitrogen Composition of Tempranillo Wines

The phenolic, aromatic and nitrogen composition of a wine determines its organoleptic profile and quality. Elicitors have been used as a tool to stimulate the plant’s defense systems, favoring the synthesis of secondary metabolites. In this pioneering study, the elicitor methyl jasmonate in conventional form (MeJ) and in nanoparticle form (ACP-MeJ), with a concentration ten times lower, was applied in a Tempranillo vineyard over two seasons. The phenolic, nitrogen and volatile composition and the sensory properties of the MeJ-based wines were determined. The results showed that the effects of foliar applications of MeJ modify the wine composition. Thus, although the total concentration of most of the groups of phenolic compounds was not altered, several compounds, such as petunidin-3-glucoside, quercetin-3-glucoside, epigallocatechin and most of the stilbenes, increased, in both years, in the treated wines. Amino acids were influenced differently in each of the years studied, and volatile compounds generally did not improve in the treated wines. However, the ACP-MeJ wines were the best rated by the tasters, highlighting their equilibrium on the taste and their genuineness and odor quality. Therefore, foliar applications of ACP-MeJ can be considered a useful tool to improve wine quality.Spanish Government RTI2018-096549-B-I00 RTI-2018-095794-A-C2

The cosmic evolution of the spatially-resolved star formation rate and stellar mass of the CALIFA survey

We investigate the cosmic evolution of the absolute and specific star formation rate (SFR, sSFR) of galaxies as derived from a spatially-resolved study of the stellar populations in a set of 366 nearby galaxies from the CALIFA survey. The analysis combines GALEX and SDSS images with the 4000 break, H_beta, and [MgFe] indices measured from the datacubes, to constrain parametric models for the SFH, which are then used to study the cosmic evolution of the star formation rate density (SFRD), the sSFR, the main sequence of star formation (MSSF), and the stellar mass density (SMD). A delayed-tau model, provides the best results, in good agreement with those obtained from cosmological surveys. Our main results from this model are: a) The time since the onset of the star formation is larger in the inner regions than in the outer ones, while tau is similar or smaller in the inner than in the outer regions. b) The sSFR declines rapidly as the Universe evolves, and faster for early than for late type galaxies, and for the inner than for the outer regions of galaxies. c) SFRD and SMD agree well with results from cosmological surveys. At z< 0.5, most star formation takes place in the outer regions of late spiral galaxies, while at z>2 the inner regions of the progenitors of the current E and S0 are the major contributors to SFRD. d) The inner regions of galaxies are the major contributor to SMD at z> 0.5, growing their mass faster than the outer regions, with a lookback time at 50% SMD of 9 and 6 Gyr for the inner and outer regions. e) The MSSF follows a power-law at high redshift, with the slope evolving with time, but always being sub-linear. f) In agreement with galaxy surveys at different redshifts, the average SFH of CALIFA galaxies indicates that galaxies grow their mass mainly in a mode that is well represented by a delayed-tau model, with the peak at z~2 and an e-folding time of 3.9 Gyr.Comment: 23 pages, 16 figures, 6 tables, accepted for publication in Astronomy & Astrophysics. *Abridged abstract

Different Dietary Approaches, Non-Alcoholic Fatty Liver Disease and Cardiovascular Disease: A Literature Review

Non-alcoholic fatty liver disease (NAFLD) is the first cause of chronic liver disease and is also associated with other harmful entities such as obesity, metabolic syndrome, dyslipidemia, and diabetes. NAFLD is a significant public health concern worldwide, impacting individuals of all ages, and its prevalence is projected to increase in the near future due to its connection with obesity. Intrinsic (genetics) and external (lifestyle) factors may also modulate NAFLD, and, in turn, may partly explain the observed relationship between NAFLD and cardiovascular disease (CVD). Although many drugs are been tested to treat NAFLD, to date, no drug has indication to specifically treat this disorder. Thus, the current management of NAFLD relies on lifestyle modifications and specifically on weight loss, physical activity, and the intake of a healthy diet. In the present narrative review, we will discuss the effects of certain dietary patterns on NAFLD incidence and progression