Unbounded randomness certification using sequences of measurements

Unpredictability, or randomness, of the outcomes of measurements made on an entangled state can be certified provided that the statistics violate a Bell inequality. In the standard Bell scenario where each party performs a single measurement on its share of the system, only a finite amount of randomness, of at most $4 log_2 d$ bits, can be certified from a pair of entangled particles of dimension $d$. Our work shows that this fundamental limitation can be overcome using sequences of (nonprojective) measurements on the same system. More precisely, we prove that one can certify any amount of random bits from a pair of qubits in a pure state as the resource, even if it is arbitrarily weakly entangled. In addition, this certification is achieved by near-maximal violation of a particular Bell inequality for each measurement in the sequence.Comment: 4 + 5 pages (1 + 3 images), published versio

Real Time Control of EC Heating & Current Drive Systems on TCV

The ability to control, in real time, the electron cyclotron heating & current drive systems for the control of MHD instabilities is particularly important for large tokamaks operating at high performance. Several algorithms have been developed and tested on TCV to explore possible control techniques, first in simple experiments to control the plasma current and elongation and subsequently in experiments to control the sawtooth instability and profile parameters. A summary of these experiments are presented in this paper together with the application of the break-in-slope technique as a possible real time calculation of the location of EC deposition

Seasonal variations in air concentrations of 27 organochlorine pesticides (OCPs) and 25 current-use pesticides (CUPs) across three agricultural areas of South Africa

For decades pesticides have been used in agriculture, however, the occurrence of legacy organochlorine pesticides (OCPs) and current-use pesticides (CUPs) is poorly understood in Africa. This study investigates air concentrations of OCPs and CUPs in three South African agricultural areas, their spatial/seasonal variations and mixture profiles. Between 2017 and 2018, 54 polyurethane foam-disks passive air-samplers (PUF-PAS) were positioned in three agricultural areas of the Western Cape, producing mainly apples, table grapes and wheat. Within areas, 25 CUPs were measured at two sites (farm and village), and 27 OCPs at one site (farm). Kruskal-Wallis tests investigated area differences in OCPs concentrations, and linear mixed-effect models studied differences in CUPs concentrations between areas, sites and sampling rounds. In total, 20 OCPs and 16 CUPs were detected. A median of 16 OCPs and 10 CUPs were detected per sample, making a total of 11 OCPs and 24 CUPs combinations. Eight OCPs (trans-chlordane, o,p'-/p,p'-dichlorodiphenyldichloroethylene (DDE)/dichlorodiphenyltrichloroethane (DDT), endosulfan sulfate, γ-hexachlorocyclohexane and mirex) and two CUPs (carbaryl and chlorpyrifos) were quantified in all samples. p,p'-DDE (median 0.14 ng/m(3)) and chlorpyrifos (median 0.70 ng/m(3)) showed the highest concentrations throughout the study. Several OCPs and CUPs showed different concentrations between areas and seasons, although CUPs concentrations did not differ between sites. OCPs ratios suggest ongoing chlordane use in the region, while DDT and endosulfan contamination result from past-use. Our study revealed spatial and seasonal variations of different OCPs and CUPs combinations detected in air. Further studies are needed to investigate the potential cumulative or synergistic risks of the detected pesticides

Unbounded randomness certification using sequences of measurements

Unpredictability, or randomness, of the outcomes of measurements made on an entangled state can be certified provided that the statistics violate a Bell inequality. In the standard Bell scenario where each party performs a single measurement on its share of the system, only a finite amount of randomness, of at most 4logd bits, can be certified from a pair of entangled particles of dimension d. Our work shows that this fundamental limitation can be overcome using sequences of (nonprojective) measurements on the same system. More precisely, we prove that one can certify any amount of random bits from a pair of qubits in a pure state as the resource, even if it is arbitrarily weakly entangled. In addition, this certification is achieved by near-maximal violation of a particular Bell inequality for each measurement in the sequence

Multiple EC power deposition locations tracking by break-in-slope analysis in TCV plasmas

Modulation of the amplitude of externally injected electron cyclotron (EC) power is a frequent method used to determine the radial power deposition profile in fusion plasmas. There are many tools to analyze the plasma response to the power modulations under quasi-stationary conditions. This paper focuses on the unique ability of the break-in-slope (BIS) method to retrieve a quasi-instantaneous estimate of the power deposition profile at each power step in the modulation, an outcome particularly relevant to track the power deposition location under non-stationary conditions. Here, the BIS analysis method is applied to the signals of a fast and high radial resolution wire-chamber soft x-ray camera in the Tokamak a Configuration Variable (TCV) where the plasma magnetic configuration and thus the EC resonance location are varied during the plasma discharge. As a step to validate this technique before real-time control experiments, the time-varying EC power deposition location of a single beam is successfully monitored by off-line BIS analysis. Simultaneous tracking of deposition locations of two EC beams gives promising results

Electron Bernstein Wave Core Deposition via O-X-B Double Mode Conversion in TCV

In the first results of electron Bernstein wave heating (EBWH) via O-X-B double mode conversion in a medium aspect ratio tokamak performed in TCV, the total power absorption efficiency was typically 60% and the deposition was made off-axis to avoid the central sawteeth perturbation that would prevent a clear detection of the deposition location. Central power deposition is however needed to maximize the global EBWH effects. Therefore, initial experiments have been started to optimize central deposition using an equatorial rather than poloidally oblique launch. A toroidal field scan provided promising central deposition results within a small database, in preparation for dedicated central high power deposition. The deposition location in presence of strong sawteeth could be determined from the slope break of soft X-ray traces at the EC power switch-ON times, in conditions where usual methods failed. Further analysis of these discharges will be presented. In particular, the difference between the experimental results and the non-relativistic calculations of deposition locations appears more significant than in the earlier off-axis deposition experiments, which provides a good opportunity for the simulation of relativistic ray propagation effects

Suppressing Dimer Formation by Increasing Conformational Freedom in Multi-Carbazole Thermally Activated Delayed Fluorescence Emitters

Ideal emitters for organic light-emitting diodes (OLEDs) are capable of efficiently harvesting non-emissive triplet states, have high colour stabilities, and possess high photoluminescence quantum yields (PLQYs). Maintaining colour stability and PLQY is particularly challenging for multi-carbazole thermally activated delayed fluorescence (TADF) materials that form persistent dimers due to intermolecular interactions of their extended aromatic systems (with altered electronic states). Addressing this challenge, three new emitters are presented, which demonstrate that, somewhat counterintuitively, sterically uncrowded acceptor units can suppress these undesirable interactions. They do so by allowing the surrounding carbazole donors to be arranged with lower dihedral angles, which in turn limits their availability for dimerization. A new pyrazine-centered emitter 4CzPyz is contrasted directly with the cyanopyridine and terephthalonitrile analogues, 4CzCNPy and 4CzTPN respectively. The pyrazine derivative demonstrates enhanced colour stability in the solid-state compared to the cyanopyridine and terephthalonitrile acceptors, which we assign to its absence of intermolecular face-to-face aromatic interactions. This suppression of dimer formation is shared by two cyanopyrazine emitters 2Cz2CNPyz and 3CzCNPyz, each of which feature reduced steric pressure and flatter Cz-Pyz dihedral angles than non-heterocyclic analogues. Flatter dihedral angles consequently lead to C–H bonds of the Cz donors extending outwards at angles that prevent the stacking required for dimerization. This expanded understanding of dimer formation in TADF materials will guide future efforts to maintain colour stability in higher performance TADF materials by curbing the prevalence of face-to-face aromatic interactions