Silica-clay complexes

The present invention relates to intercalated clay compositions wherein the interlayers of said clay have been intercalated with three-dimensional silicon oxide pillars whereby the pillars comprise at least two silicon atom layers parallel to the clay interlayers. These materials have useful catalytic and adsorbent properties

Silica intercalated crystalline zirconium phosphate-type materials

The present invention relates to intercalated crystalline zirconium phosphate-types compositions wherein the interlayers of said composition have been intercalated with three-dimensional silicon oxide pillars whereby the pillars comprise at least two silicon atom layers parallel to the clay interlayers

Pressure and linear heat capacity in the superconducting state of thoriated UBe13

Even well below Tc, the heavy-fermion superconductor (U,Th)Be13 has a large linear term in its specific heat. We show that under uniaxial pressure, the linear heat capacity increases in magnitude by more than a factor of two. The change is reversible and suggests that the linear term is an intrinsic property of the material. In addition, we find no evidence of hysteresis or of latent heat in the low-temperature and low-pressure portion of the phase diagram, showing that all transitions in this region are second order.Comment: 5 pages, 4 figure

Weak-Localization in Chaotic Versus Non-Chaotic Cavities: A Striking Difference in the Line Shape

We report experimental evidence that chaotic and non-chaotic scattering through ballistic cavities display distinct signatures in quantum transport. In the case of non-chaotic cavities, we observe a linear decrease in the average resistance with magnetic field which contrasts markedly with a Lorentzian behavior for a chaotic cavity. This difference in line-shape of the weak-localization peak is related to the differing distribution of areas enclosed by electron trajectories. In addition, periodic oscillations are observed which are probably associated with the Aharonov-Bohm effect through a periodic orbit within the cavities.Comment: 4 pages revtex + 4 figures on request; amc.hub.94.

Parameter mismatches,variable delay times and synchronization in time-delayed systems

We investigate synchronization between two unidirectionally linearly coupled chaotic non-identical time-delayed systems and show that parameter mismatches are of crucial importance to achieve synchronization. We establish that independent of the relation between the delay time in the coupled systems and the coupling delay time, only retarded synchronization with the coupling delay time is obtained. We show that with parameter mismatch or without it neither complete nor anticipating synchronization occurs. We derive existence and stability conditions for the retarded synchronization manifold. We demonstrate our approach using examples of the Ikeda and Mackey-Glass models. Also for the first time we investigate chaos synchronization in time-delayed systems with variable delay time and find both existence and sufficient stability conditions for the retarded synchronization manifold with the coupling delay lag time. Also for the first time we consider synchronization between two unidirectionally coupled chaotic multi-feedback Ikeda systems and derive existence and stability conditions for the different anticipating, lag, and complete synchronization regimes.Comment: 12 page

Intrinsic decoherence and classical-quantum correspondence in two coupled delta-kicked rotors

We show that classical-quantum correspondence of center of mass motion in two coupled delta-kicked rotors can be obtained from intrinsic decoherence of the system itself which occurs due to the entanglement of the center of mass motion to the internal degree of freedom without coupling to external environment

DC Josephson Effect in SNS Junctions of Anisotropic Superconductors

A formula for the Josephson current between two superconductors with anisotropic pairing symmetries is derived based on the mean-field theory of superconductivity. Zero-energy states formed at the junction interfaces is one of basic phenomena in anisotropic superconductor junctions. In the obtained formula, effects of the zero-energy states on the Josephson current are taken into account through the Andreev reflection coefficients of a quasiparticle. In low temperature regimes, the formula can describe an anomaly in the Josephson current which is a direct consequence of the exsitence of zero-energy states. It is possible to apply the formula to junctions consist of superconductors with spin-singlet Cooper pairs and those with spin-triplet Cooper pairs

Scaling properties of the magnetic-field-induced specific heat of superconducting UBe

We report on measurements of the low-temperature specific heat Cp(T, B) of the unconventional superconductor UBe13 in magnetic fields up to 7 T. At B≈2 T, a substantial change in the magnetic-field dependence of the temperature derivative of the magnetic-field induced contribution to the electronic specific heat CH(T, B), resulting from the flow of supercurrents around the vortices, is observed, suggesting a crossover between two different regions in the superconducting phase diagram of UBe13. For fields B >2 T, CH(T, B) exhibits a scaling behavior with respect to TB-1/2, which provides substantial evidence for the existence of point nodes in the quasiparticle excitation spectrum of the superconductor

Magnetic Field Effects on Neutron Diffraction in the Antiferromagnetic Phase of UPt3UPt_3

We discuss possible magnetic structures in UPt$_3$ based on our analysis of elastic neutron-scattering experiments in high magnetic fields at temperatures $T<T_N$. The existing experimental data can be explained by a single-{\bf q} antiferromagnetic structure with three independent domains. For modest in-plane spin-orbit interactions, the Zeeman coupling between the antiferromagnetic order parameter and the magnetic field induces a rotation of the magnetic moments, but not an adjustment of the propagation vector of the magnetic order. A triple-{\bf q} magnetic structure is also consistent with neutron experiments, but in general leads to a non-uniform magnetization in the crystal. New experiments could decide between these structures.Comment: 5 figures included in the tex

Effects of ß-Lactam Antibiotics and Fluoroquinolones on Human Gut Microbiota in Relation to Clostridium difficile Associated Diarrhea

Clostridium difficile infections are an emerging health problem in the modern hospital environment. Severe alterations of the gut microbiome with loss of resistance to colonization against C. difficile are thought to be the major trigger, but there is no clear concept of how C. difficile infection evolves and which microbiological factors are involved. We sequenced 16S rRNA amplicons generated from DNA and RNA/cDNA of fecal samples from three groups of individuals by FLX technology: (i) healthy controls (no antibiotic therapy); (ii) individuals receiving antibiotic therapy (Ampicillin/Sulbactam, cephalosporins, and fluoroquinolones with subsequent development of C. difficile infection or (iii) individuals receiving antibiotic therapy without C. difficile infection. We compared the effects of the three different antibiotic classes on the intestinal microbiome and the effects of alterations of the gut microbiome on C. difficile infection at the DNA (total microbiota) and rRNA (potentially active) levels. A comparison of antibiotic classes showed significant differences at DNA level, but not at RNA level. Among individuals that developed or did not develop a C. difficile infection under antibiotics we found no significant differences. We identified single species that were up- or down regulated in individuals receiving antibiotics who developed the infection compared to non-infected individuals. We found no significant differences in the global composition of the transcriptionally active gut microbiome associated with C. difficile infections. We suggest that up- and down regulation of specific bacterial species may be involved in colonization resistance against C. difficile providing a potential therapeutic approach through specific manipulation of the intestinal microbiome