Organic ambipolar semiconductors for TFT applications

In the last years we have devoted some effort to the search of new high-mobility semiconductors with ambipolar performances, good processability and environmental stability. Our approach, which is one of the most widely used, consists in the combination of donor and acceptor moieties in the conjugated skeleton, which allows fine tuning of the frontier molecular orbitals. For OTFT applications, low-lying HOMOs are essential to resist air oxidation and thus increase device stability. However, if the HOMO energy is too low, the resulting barrier to hole injection may compromise the transistor performance. Thus, a delicate balance between these two effects is needed. In particular, we have combined naphthaleneimide-derived moieties as electron accepting groups with electron-rich oligothiophene fragments. In these materials, we have found that the presence of ambipolar transport in these planar molecules can be understood on the basis of three interrelated properties: (i) the absence of skeletal distortions allows closer intermolecular pi-pi stacking and enhanced intramolecular pi-conjugation, (ii) increased pi-conjugation raises the HOMO energy, which approaches the Fermi level of common used electrodes; and (iii) more planar structures translate into lower Marcus reorganization energies. However, one of the limitations of these types of semiconductors is the presence of a molecular dipole moment, which forces the molecules to pack with pairwise intermolecular interactions orienting the naphthaleneimide cores in opposite directions, decreasing in some cases molecular orbitals overlapping. In recent contributions, we have devoted our efforts to analyze the effect of molecular interactions, through chemical modifications in order to induce parallel and antiparallel molecular packing, on the electronic properties of ambipolar semiconductors.Universidad de Málaga. Campus de Excelencia Internacional Andalucía Tech

Understanding organic materials performance in field-effect transistors

Comunicación oralIn the last years, much of our effort has been devoted to the search and study of new high-mobility semiconductors for organic thin film transistors. The approach used for the materials design has been two-fold: (i) the combination of donor and acceptor moieties in the pi-conjugated skeleton, which allows fine tuning of the frontier molecular orbitals, being this necessary for achieving electron/hole or ambipolar transport and ambient stability; and (ii) rational selection of the type and positioning of specific solubilizing substituents ensuring processability, which is essential to make these materials scalable to industry. However, material processability should be attained minimizing a negative effect on charge transport. Therefore, proper energy levels, planar molecular conformations, close intermolecular pi-pi stacking and adequate thin film crystallinity need to be maintained upon alkyl substitution. In this communication, several examples of molecular and polymeric materials are shown. A rational design, guided by experimental and theoretical evidences, has prompted modifications on their conjugated skeletons, donor/acceptor subunits ratio and/or selection of proper alkyl solubilizing chains, which induce noticeable changes in their electronic performances. The main aim of these studies is the basic understanding of charge transport in organic materials. For this end, we will use Raman spectroscopy and DFT quantum-chemical calculations as important tools for materials characterization.Universidad de Málaga. Campus de Excelencia Internacional Andalucía Tech

Effects of clinical experience in the nursing student attitudes toward people with psychiatric disabilities

Indexación: Scopus; Scielo.En la formación del estudiante de pregrado de Enfermería se hace fundamental la elección de experiencias de aprendizaje significativas. Objetivo: Determinar el efecto de la experiencia clínica en servicios de psiquiatría, en las actitudes de estudiantes de Enfermería hacia las personas con discapacidad psiquiátrica. Material y método: Diseño cuasi experimental de pre y postest. La muestra incluyó un total de 84 estudiantes de Enfermería de tercer año de dos universidades de Santiago de Chile. El total de la muestra completó la "Escala de Actitudes hacia las Personas con Discapacidad" (EAPD) forma G. Se consideró como intervención las estrategias usadas en las asignaturas clínicas de enfermería psiquiátrica en ambas universidades. Se realizó prueba t de student para muestras relacionadas. Resultados: Se encontró diferencia estadísticamente significativa (p< 0,05) en el postest, lo que está relacionado con las experiencias de aprendizaje que consideran el contacto con personas con discapacidad psiquiátrica, en diferentes dispositivos de la red de psiquiatría y el acompañamiento docente directo. Conclusión: Estos hallazgos validan la importancia de la elección de experiencias clínicas, en los currículos de formación de Enfermería, como instancias que disminuyen las actitudes negativas como la estigmatización.The choice of meaningful learning experiences becomes essential in basic Nursing education programs. The purpose of this study is to determine the effect of clinical experience in psychiatric services in Nursing students' attitudes towards people with mental illnesses. A quasi-experimental design method of pre-test and post-test was used. The sample was made up of 84 third-year-nursing students from two universities in Santiago, Chile. All of the participants completed the Scale of Attitudes Toward Disabled Persons (SADP)-G. The strategies used in subjects of psychiatric nursing at both universities were regarded as intervention. Student t test for related samples was performed. Results: Respondents reported statistically significant difference (p <0.05) in the post test, which is associated with learning experiences that consider contact with people with mental illness in any of the different psychiatry network nodes and direct educational support. Conclusion: Validate the importance of including the clinical experience in the nursing training curriculum as a way of reducing negative attitudes of Nursing students, such as stigmatization, towards people with mental illnesses.https://scielo.conicyt.cl/scielo.php?script=sci_arttext&pid=S0717-95532017000300125&lng=en&nrm=iso&tlng=e

An analysis of the evolution of hydrometeorological extremes in newspapers: the case of Catalonia, 1982&ndash;2006

This contribution analyzes the evolution of perception of certain natural hazards over the past 25 years in a Mediterranean region. Articles from newspapers have been used as indicator. To this end a specific Spanish journal has been considered and an ACCESS database has been created with the summarized information from each news item. The database includes data such as the location of each specific article in the newspaper, its length, the number of pictures and figures, the headlines and a summary of the published information, including all the instrumental data. The study focused on hydrometeorological extremes, mainly floods and droughts, in the northeast of the Iberian Peninsula. The number of headlines per event, trends and other data have been analyzed and compared with "measured" information, in order to identify any bias that could lead to an erroneous perception of the phenomenon. The SPI index (a drought index based on standardized accumulated precipitation) has been calculated for the entire region, and has been used for the drought analysis, while a geodatabase implemented on a GIS built for all the floods recorded in Catalonia since 1900 (INUNGAMA) has been used to analyze flood evolution. Results from a questionnaire about the impact of natural hazards in two specific places have been also used to discuss the various perceptions between rural and urban settings. Results show a better correlation between the news about drought or water scarcity and SPI than between news on floods in Catalonia and the INUNGAMA database. A positive trend has been found for non-catastrophic floods, which is explained by decrease of the perception thresholds, the increase of population density in the most flood-prone areas and changes in land use

Primeval very low-mass stars and brown dwarfs - IV. New L subdwarfs, Gaia astrometry, population properties, and a blue brown dwarf binary

30 pages, 23 figuresWe present 27 new L subdwarfs and classify five of them as esdL and 22 as sdL. Our L subdwarf candidates were selected with the UKIRT Infrared Deep Sky Survey and Sloan Digital Sky Survey. Spectroscopic follow-up was carried out primarily with the OSIRIS spectrograph on the Gran Telescopio Canarias. Some of these new objects were followed up with the X-shooter instrument on the Very Large Telescope. We studied the photometric properties of the population of known L subdwarfs using colour-spectral type diagrams and colour-colour diagrams, by comparison with L dwarfs and main-sequence stars, and identified new colour spaces for L subdwarf selection/study in current and future surveys. We further discussed the brown dwarf transition-zone and the observational stellar/substellar boundary. We found that about one-third of 66 known L subdwarfs are substellar objects, with two-thirds being very low-mass stars. We also present the Hertzsprung-Russell diagrams, spectral type-absolute magnitude corrections, and tangential velocities of 20 known L subdwarfs observed by the Gaia astrometry satellite. One of our L subdwarf candidates, ULAS J233227.03+123452.0, is a mildly metal-poor spectroscopic binary brown dwarf: a ~L6p dwarf and a ~T4p dwarf. This binary is likely a thick disc member according to its kinematics.Peer reviewedFinal Accepted Versio

Exploring pig trade patterns to inform the design of risk-based disease surveillance and control strategies

An understanding of the patterns of animal contact networks provides essential information for the design of risk-based animal disease surveillance and control strategies. This study characterises pig movements throughout England and Wales between 2009 and 2013 with a view to characterising spatial and temporal patterns, network topology and trade communities. Data were extracted from the Animal and Plant Health Agency (APHA)’s RADAR (Rapid Analysis and Detection of Animal-related Risks) database, and analysed using descriptive and network approaches. A total of 61,937,855 pigs were moved through 872,493 movements of batches in England and Wales during the 5-year study period. Results show that the network exhibited scale-free and small-world topologies, indicating the potential for diseases to quickly spread within the pig industry. The findings also provide suggestions for how risk-based surveillance strategies could be optimised in the country by taking account of highly connected holdings, geographical regions and time periods with the greatest number of movements and pigs moved, as these are likely to be at higher risk for disease introduction. This study is also the first attempt to identify trade communities in the country, information which could be used to facilitate the pig trade and maintain disease-free status across the country in the event of an outbreak