1,064 research outputs found
Contribution to fusion research from IAEA coordinated research projects and joint experiments
The paper presents objectives and activities of IAEA Coordinated Research Projects 'Conceptual development of steady-state compact fusion neutron sources' and 'Utilisation of a network of small magnetic confinement fusion devices for mainstream fusion research'. The background and main projects of the CRP on FNS are described in detail, as this is a new activity at IAEA. Recent activities of the second CRP, which continues activities of previous CRPs, are overviewed
Formation of convective cells in the scrape-off layer of the CASTOR tokamak
Understanding of the scrape-off layer (SOL) physics in tokamaks requires
diagnostics with sufficient temporal and spatial resolution. This contribution
describes results of experiments performed in the SOL of the CASTOR tokamak
(R=40 cm, a = 6 cm) by means of a ring of 124 Langmuir probes surrounding the
whole poloidal cross section. The individual probes measure either the ion
saturation current of the floating potential with the spatial resolution up to
3 mm. Experiments are performed in a particular magnetic configuration,
characterized by a long parallel connection length in the SOL, L_par ~q2piR. We
report on measurements in discharges, where the edge electric field is modified
by inserting a biased electrode into the edge plasma. In particular, a complex
picture is observed, if the biased electrode is located inside the SOL. The
poloidal distribution of the floating potential appears to be strongly
non-uniform at biasing. The peaks of potential are observed at particular
poloidal angles. This is interpreted as formation of a biased flux tube, which
emanates from the electrode along the magnetic field lines and snakes q times
around the torus. The resulting electric field in the SOL is 2-dimensional,
having the radial as well as the poloidal component. It is demonstrated that
the poloidal electric field E_pol convects the edge plasma radially due to the
E_pol x B_T drift either inward or outward depending on its sign. The
convective particle flux is by two orders of magnitude larger than the
fluctuation-induced one and consequently dominates.Comment: 12th International Congress on Plasma Physics, 25-29 October 2004,
Nice (France
Error estimates for solid-state density-functional theory predictions: an overview by means of the ground-state elemental crystals
Predictions of observable properties by density-functional theory
calculations (DFT) are used increasingly often in experimental condensed-matter
physics and materials engineering as data. These predictions are used to
analyze recent measurements, or to plan future experiments. Increasingly more
experimental scientists in these fields therefore face the natural question:
what is the expected error for such an ab initio prediction? Information and
experience about this question is scattered over two decades of literature. The
present review aims to summarize and quantify this implicit knowledge. This
leads to a practical protocol that allows any scientist - experimental or
theoretical - to determine justifiable error estimates for many basic property
predictions, without having to perform additional DFT calculations. A central
role is played by a large and diverse test set of crystalline solids,
containing all ground-state elemental crystals (except most lanthanides). For
several properties of each crystal, the difference between DFT results and
experimental values is assessed. We discuss trends in these deviations and
review explanations suggested in the literature. A prerequisite for such an
error analysis is that different implementations of the same first-principles
formalism provide the same predictions. Therefore, the reproducibility of
predictions across several mainstream methods and codes is discussed too. A
quality factor Delta expresses the spread in predictions from two distinct DFT
implementations by a single number. To compare the PAW method to the highly
accurate APW+lo approach, a code assessment of VASP and GPAW with respect to
WIEN2k yields Delta values of 1.9 and 3.3 meV/atom, respectively. These
differences are an order of magnitude smaller than the typical difference with
experiment, and therefore predictions by APW+lo and PAW are for practical
purposes identical.Comment: 27 pages, 20 figures, supplementary material available (v5 contains
updated supplementary material
High resolution effect-directed analysis of steroid hormone (ant)agonists in surface and wastewater quality monitoring
Monitoring of chemical water quality is extremely challenging due to the large variety of compounds and the presence of biologically active compounds with unknown chemical identity. Previously, we developed a high resolution Effect-Directed Analysis (EDA) platform that combines liquid chromatography with high resolution mass spectrometry and parallel bioassay detection. In this study, the platform is combined with CALUX bioassays for (anti)androgenic, estrogenic and glucocorticoid activities, and the performance of the platform is evaluated. It appeared to render very repeatable results, with high recoveries of spiked compounds and high consistency between the mass spectrometric and bioassay results. Application of the platform to wastewater treatment plant effluent and surface water samples led to the identification of several compounds contributing to the measured activities. Eventually, a workflow is proposed for the application of the platform in a routine monitoring context. The workflow divides the platform into four phases, of which one to all can be performed depending on the research question and the results obtained. This allows one to make a balance between the effort put into the platform and the certainty and depth by which active compounds will be identified. The EDA platform is a valuable tool to identify unknown bioactive compounds, both in an academic setting as in the context of legislative, governmental or routine monitoring
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