Selective hydrogenation of acetophenone with supported Pd and Rh catalysts in water, organic solvents, and CO2-dissolved expanded liquids

Solvent effects were investigated for selective hydrogenation of acetophenone (AP) with commercial 5% Pd/Al2O3 and 5% Pd/C catalysts using polar and nonpolar solvents. The rate of AP hydrogenation varied with the solvents used in different ways depending on the catalysts used. The highest AP conversion was achieved with water for the two catalysts and the AP conversion was correlated with hydrogen-bond-acceptance (HBA) capability (beta) for Pd/Al2O3 and hydrogen-bond-donation (HBD) capability (alpha) for Pd/C. These trends were the same as the corresponding solvent effects obtained previously with Rh/ Al2O3 and Rh/C catalysts, respectively (Green Chem., 2015, 17, 1877-1883). The influence of solvents on the rate of AP hydrogenation depends on the support materials and not on the metal species. Furthermore, AP hydrogenation was conducted with the four supported noble metal catalysts in different solvents pressurized by CO2 (CO2-dissolved expanded solvents). The influence of CO2 pressurization on the rate of reaction, the product selectivity, and the catalyst life was investigated to know whether or not CO2 molecules could function as a reaction promoter in heterogeneous AP hydrogenation reactions with supported Pd and Rh catalysts in different solvents

EMPRESS. XI. SDSS and JWST Search for Local and z~4-5 Extremely Metal-Poor Galaxies (EMPGs): Clustering and Chemical Properties of Local EMPGs

We search for local extremely metal-poor galaxies (EMPGs), selecting photometric candidates by broadband color excess and machine-learning techniques with the SDSS photometric data. After removing stellar contaminants by shallow spectroscopy with Seimei and Nayuta telescopes, we confirm that three candidates are EMPGs with 0.05--0.1 $Z_\odot$ by deep Magellan/MagE spectroscopy for faint {\sc[Oiii]}$\lambda$4363 lines. Using a statistical sample consisting of 105 spectroscopically-confirmed EMPGs taken from our study and the literature, we calculate cross-correlation function (CCF) of the EMPGs and all SDSS galaxies to quantify environments of EMPGs. Comparing another CCF of all SDSS galaxies and comparison SDSS galaxies in the same stellar mass range ($10^{7.0}-10^{8.4} M_\odot$), we find no significant ($>1\sigma$) difference between these two CCFs. We also compare mass-metallicity relations (MZRs) of the EMPGs and those of galaxies at $z\sim$ 0--4 with a steady chemical evolution model and find that the EMPG MZR is comparable with the model prediction on average. These clustering and chemical properties of EMPGs are explained by a scenario of stochastic metal-poor gas accretion on metal-rich galaxies showing metal-poor star formation. Extending the broadband color-excess technique to a high-$z$ EMPG search, we select 17 candidates of $z\sim$ 4--5 EMPGs with the deep ($\simeq30$ mag) near-infrared JWST/NIRCam images obtained by ERO and ERS programs. We find galaxy candidates with negligible {\sc[Oiii]}$\lambda\lambda$4959,5007 emission weaker than the local EMPGs and known high-$z$ galaxies, suggesting that some of these candidates may fall in 0--0.01 $Z_\odot$, which potentially break the lowest metallicity limit known to date

EMPRESS. II. Highly Fe-Enriched Metal-poor Galaxies with ∼1.0\sim 1.0 (Fe/O)⊙_\odot and 0.020.02 (O/H)⊙_\odot : Possible Traces of Super Massive (>300M⊙>300 M_{\odot}) Stars in Early Galaxies

We present element abundance ratios and ionizing radiation of local young low-mass (~$10^{6}$ M_sun) extremely metal poor galaxies (EMPGs) with a 2% solar oxygen abundance (O/H)_sun and a high specific star-formation rate (sSFR~300 Gyr$^{-1}$), and other (extremely) metal poor galaxies, which are compiled from Extremely Metal-Poor Representatives Explored by the Subaru Survey (EMPRESS) and the literature. Weak emission lines such as [FeIII]4658 and HeII4686 are detected in very deep optical spectra of the EMPGs taken with 8m-class telescopes including Keck and Subaru (Kojima et al. 2019, Izotov et al. 2018), enabling us to derive element abundance ratios with photoionization models. We find that neon- and argon-to-oxygen ratios are comparable to those of known local dwarf galaxies, and that the nitrogen-to-oxygen abundance ratios (N/O) are lower than 20% (N/O)_sun consistent with the low oxygen abundance. However, the iron-to-oxygen abundance ratios (Fe/O) of the EMPGs are generally high; the EMPGs with the 2%-solar oxygen abundance show high Fe/O ratios of ~90-140% (Fe/O)_sun, which are unlikely explained by suggested scenarios of Type Ia supernova iron productions, iron's dust depletion, and metal-poor gas inflow onto previously metal-riched galaxies with solar abundances. Moreover, these EMPGs have very high HeII4686/H$\beta$ ratios of ~1/40, which are not reproduced by existing models of high-mass X-ray binaries whose progenitor stellar masses are less than 120 M_sun. Comparing stellar-nucleosynthesis and photoionization models with a comprehensive sample of EMPGs identified by this and previous EMPG studies, we propose that both the high Fe/O ratios and the high HeII4686/H$\beta$ ratios are explained by the past existence of super massive ($>$300 M_sun) stars, which may evolve into intermediate-mass black holes ($\gtrsim$100 M_sun).Comment: ApJ in press. 23 pages, 7 Figures, 6 Table

Extremely Metal-Poor Representatives Explored by the Subaru Survey (EMPRESS). I. A Successful Machine Learning Selection of Metal-Poor Galaxies and the Discovery of a Galaxy with M*<10^6 M_sun and 0.016 Z_sun

We have initiated a new survey for local extremely metal-poor galaxies (EMPGs) with Subaru/Hyper Suprime-Cam (HSC) large-area (~500 deg^2) optical images reaching a 5 sigma limit of ~26 magnitude, about 100 times deeper than the Sloan Digital Sky Survey (SDSS). To select Z/Z_sun<0.1 EMPGs from ~40 million sources detected in the Subaru images, we first develop a machine-learning (ML) classifier based on a deep neural network algorithm with a training data set consisting of optical photometry of galaxy, star, and QSO models. We test our ML classifier with SDSS objects having spectroscopic metallicity measurements, and confirm that our ML classifier accomplishes 86%-completeness and 46%-purity EMPG classifications with photometric data. Applying our ML classifier to the photometric data of the Subaru sources as well as faint SDSS objects with no spectroscopic data, we obtain 27 and 86 EMPG candidates from the Subaru and SDSS photometric data, respectively. We conduct optical follow-up spectroscopy for 10 out of our EMPG candidates with Magellan/LDSS-3+MagE, Keck/DEIMOS, and Subaru/FOCAS, and find that the 10 EMPG candidates are star-forming galaxies at z=0.007-0.03 with large H_beta equivalent widths of 104-265 A, stellar masses of log(M*/M_sun)=5.0-7.1, and high specific star-formation rates of ~300 Gyr^{-1}, which are similar to those of early galaxies at z>6 reported recently. We spectroscopically confirm that 3 out of 10 candidates are truly EMPGs with Z/Z_sun<0.1, one of which is HSC J1631+4426, the most metal-poor galaxy with Z/Z_sun=0.016 reported ever.Comment: 30 pages, 26 figures, and 8 tables; (Revision: metallicities changed due to the use of a more pricise dust correction method, but conclusion does not change, Minor: a table, some figures, and sentences are added for a clear explanation.

First Data Release of the Hyper Suprime-Cam Subaru Strategic Program

The Hyper Suprime-Cam Subaru Strategic Program (HSC-SSP) is a three-layered imaging survey aimed at addressing some of the most outstanding questions in astronomy today, including the nature of dark matter and dark energy. The survey has been awarded 300 nights of observing time at the Subaru Telescope and it started in March 2014. This paper presents the first public data release of HSC-SSP. This release includes data taken in the first 1.7 years of observations (61.5 nights) and each of the Wide, Deep, and UltraDeep layers covers about 108, 26, and 4 square degrees down to depths of i~26.4, ~26.5, and ~27.0 mag, respectively (5sigma for point sources). All the layers are observed in five broad bands (grizy), and the Deep and UltraDeep layers are observed in narrow bands as well. We achieve an impressive image quality of 0.6 arcsec in the i-band in the Wide layer. We show that we achieve 1-2 per cent PSF photometry (rms) both internally and externally (against Pan-STARRS1), and ~10 mas and 40 mas internal and external astrometric accuracy, respectively. Both the calibrated images and catalogs are made available to the community through dedicated user interfaces and database servers. In addition to the pipeline products, we also provide value-added products such as photometric redshifts and a collection of public spectroscopic redshifts. Detailed descriptions of all the data can be found online. The data release website is https://hsc-release.mtk.nao.ac.jp/.Comment: 34 pages, 20 figures, 7 tables, moderate revision, accepted for publication in PAS

Noncontact Sterilization using Some Commercial Products

This paper studied noncontact sterilization for Escherichia coli JM 109 using some commercial products. In the tested some commercial products, Prepared SUSHI WASABI in tube (S & B Fooda Inc., Japan), Tokusen Karashi (House Foods Corp., Japan), Kometouban (S.T. Corp., Japan), Komebitsusensei (Arromic Co.,Ltd., Japan), Youso de kurin randori (HOYU Co.,Ltd., Japan) were found to have noncontact sterilization activity. This activity seems to be due to volatile substances

EMPRESS. III. Morphology, Stellar Population, and Dynamics of Extremely Metal Poor Galaxies (EMPGs): Are EMPGs Local Analogs of High-zz Young Galaxies?

We present the morphology and stellar population of 27 extremely metal poor galaxies (EMPGs) at $z\sim0$ with metallicities of 0.01--0.1 Z$_{\odot}$. We conduct multi-component surface brightness (SB) profile fitting for the deep Subaru/HSC $i$-band images of the EMPGs with the {\sc Galfit} software, carefully removing the SB contributions of tails. We find that the EMPGs with a median stellar mass of $\log(M_{*}/{\rm M}_{\odot})=6.0$ have a median S{\'e}rsic index of $n=1.1$ and a median effective radius of $r_{\rm e}=200$ pc, suggesting that typical EMPGs have very compact disk. We compare the EMPGs with $z\sim6$ galaxies and local galaxies on the size-mass ($r_{\rm e}$-$M_*$) diagram, and identify that the majority of the EMPGs have a $r_{\rm e}$-$M_*$ relation similar to $z\sim0$ star-forming galaxies rather than $z\sim6$ galaxies. Not every EMPG is a local analog of high-$z$ young galaxies in the $r_{\rm e}$-$M_*$ relation. A spectrum of one pair of EMPG and tail, so far available, indicates that the tail is dynamically related to the EMPG with a median velocity difference of $\Delta V=101\pm32$ km s$^{-1}$. This moderately-large $\Delta V$ cannot be explained by the dynamics of the tail, but likely by the infall on the tail. For the first time, we may identify the metal-poor star-forming system just now infalling into the tail.Comment: ApJ in Pres

EMPRESS. IX. Extremely Metal-Poor Galaxies are Very Gas-Rich Dispersion-Dominated Systems: Will JWST Witness Gaseous Turbulent High-z Primordial Galaxies?

We present kinematics of 6 local extremely metal-poor galaxies (EMPGs) with low metallicities ($0.016-0.098\ Z_{\odot}$) and low stellar masses ($10^{4.7}-10^{7.6} M_{\odot}$). Taking deep medium-high resolution ($R\sim7500$) integral-field spectra with 8.2-m Subaru, we resolve the small inner velocity gradients and dispersions of the EMPGs with H$\alpha$ emission. Carefully masking out sub-structures originated by inflow and/or outflow, we fit 3-dimensional disk models to the observed H$\alpha$ flux, velocity, and velocity-dispersion maps. All the EMPGs show rotational velocities ($v_{\rm rot}$) of 5--23 km s$^{-1}$ smaller than the velocity dispersions ($\sigma_{0}$) of 17--31 km s$^{-1}$, indicating dispersion-dominated ($v_{\rm rot}/\sigma_{0}=0.29-0.80<1$) systems affected by inflow and/or outflow. Except for two EMPGs with large uncertainties, we find that the EMPGs have very large gas-mass fractions of $f_{\rm gas}\simeq 0.9-1.0$. Comparing our results with other H$\alpha$ kinematics studies, we find that $v_{\rm rot}/\sigma_{0}$ decreases and $f_{\rm gas}$ increases with decreasing metallicity, decreasing stellar mass, and increasing specific star-formation rate. We also find that simulated high-$z$ ($z\sim 7$) forming galaxies have gas fractions and dynamics similar to the observed EMPGs. Our EMPG observations and the simulations suggest that primordial galaxies are gas-rich dispersion-dominated systems, which would be identified by the forthcoming James Webb Space Telescope (JWST) observations at $z\sim 7$.Comment: Submitted to ApJ; After revisio

The Hyper Suprime-Cam SSP survey: Overview and survey design

Hyper Suprime-Cam (HSC) is a wide-field imaging camera on the prime focus of the 8.2-m Subaru telescope on the summit of Mauna Kea in Hawaii. A team of scientists from Japan, Taiwan, and Princeton University is using HSC to carry out a 300-night multi-band imaging survey of the high-latitude sky. The survey includes three layers: the Wide layer will cover 1400 deg2 in five broad bands (grizy), with a 5 σ point-source depth of r ≈ 26. The Deep layer covers a total of 26 deg2 in four fields, going roughly a magnitude fainter, while the UltraDeep layer goes almost a magnitude fainter still in two pointings of HSC (a total of 3.5 deg2). Here we describe the instrument, the science goals of the survey, and the survey strategy and data processing. This paper serves as an introduction to a special issue of the Publications of the Astronomical Society of Japan, which includes a large number of technical and scientific papers describing results from the early phases of this survey