Corrigendum: Three spatially separate records confirm the presence of and provide a range extension for the giant pangolin Smutsia gigantea in Kenya (Oryx (2022) DOI: 10.1017/S0030605322000126)

In the original publication of this article, the list of authors was incomplete, with only the following authors listed: Tommy Sandri, Claire Okell, Stuart Nixon, Naomi Matthews, Fred Omengo, James Mathenge, Stephen Ndambuki, Daniel W.S. Challender and Bradley Cain. The correct author list is: Tommy Sandri, Claire Okell, Stuart Nixon, Naomi Matthews, Fred Omengo, James Mathenge, Stephen Ndambuki, Daniel W.S. Challender, Richard Chepkwony, Patrick Omondi, Shadrack Ngene and Bradley Cain The article has been updated to include the correct author details and add the ORCID iD of Shadrack Ngene

Nurses' perceptions of aids and obstacles to the provision of optimal end of life care in ICU

Contains fulltext : 172380.pdf (publisher's version ) (Open Access

Technical Note: Large overestimation of pCO2 calculated from pH and alkalinity in acidic, organic-rich freshwaters

© 2015 Author(s). Inland waters have been recognized as a significant source of carbon dioxide (CO 2 ) to the atmosphere at the global scale. Fluxes of CO 2 between aquatic systems and the atmosphere are calculated from the gas transfer velocity and the water-air gradient of the partial pressure of CO 2 (pCO 2 ). Currently, direct measurements of water pCO 2 remain scarce in freshwaters, and most published pCO 2 data are calculated from temperature, pH and total alkalinity (TA). Here, we compare calculated (pH and TA) and measured (equilibrator and headspace) water pCO 2 in a large array of temperate and tropical freshwaters. The 761 data points cover a wide range of values for TA (0 to 14 200 μmol L -1 ), pH (3.94 to 9.17), measured pCO 2 (36 to 23 000 ppmv), and dissolved organic carbon (DOC) (29 to 3970 μmol L -1 ). Calculated pCO 2 were >10% higher than measured pCO 2 in 60% of the samples (with a median overestimation of calculated pCO 2 compared to measured pCO 2 of 2560 ppmv) and were >100% higher in the 25% most organic-rich and acidic samples (with a median overestimation of 9080 ppmv). We suggest these large overestimations of calculated pCO 2 with respect to measured pCO 2 are due to the combination of two cumulative effects: (1) a more significant contribution of organic acids anions to TA in waters with low carbonate alkalinity and high DOC concentrations; (2) a lower buffering capacity of the carbonate system at low pH, which increases the sensitivity of calculated pCO 2 to TA in acidic and organic-rich waters. No empirical relationship could be derived from our data set in order to correct calculated pCO 2 for this bias. Owing to the widespread distribution of acidic, organic-rich freshwaters, we conclude that regional and global estimates of CO 2 outgassing from freshwaters based on pH and TA data only are most likely overestimated, although the magnitude of the overestimation needs further quantitative analysis. Direct measurements of pCO 2 are recommended in inland waters in general, and in particular in acidic, poorly buffered freshwaters.status: publishe

Globally significant greenhouse-gas emissions from African inland waters

Carbon dioxide emissions to the atmosphere from inland waters-streams, rivers, lakes and reservoirs-are nearly equivalent to ocean and land sinks globally. Inland waters can be an important source of methane and nitrous oxide emissions as well, but emissions are poorly quantified, especially in Africa. Here we report dissolved carbon dioxide, methane and nitrous oxide concentrations from 12 rivers in sub-Saharan Africa, including seasonally resolved sampling at 39 sites, acquired between 2006 and 2014. Fluxes were calculated from published gas transfer velocities, and upscaled to the area of all sub-Saharan African rivers using available spatial data sets. Carbon dioxide-equivalent emissions from river channels alone were about 0.4 Pg carbon per year, equivalent to two-thirds of the overall net carbon land sink previously reported for Africa. Including emissions from wetlands of the Congo river increases the total carbon dioxide-equivalent greenhouse-gas emissions to about 0.9 Pg carbon per year, equivalent to about one quarter of the global ocean and terrestrial combined carbon sink. Riverine carbon dioxide and methane emissions increase with wetland extent and upland biomass. We therefore suggest that future changes in wetland and upland cover could strongly affect greenhouse-gas emissions from African inland waters