102 research outputs found
Structure of self-organized Fe clusters grown on Au(111) analyzed by Grazing Incidence X-Ray Diffraction
We report a detailed investigation of the first stages of the growth of
self-organized Fe clusters on the reconstructed Au(111) surface by grazing
incidence X-ray diffraction. Below one monolayer coverage, the Fe clusters are
in "local epitaxy" whereas the subsequent layers adopt first a strained fcc
lattice and then a partly relaxed bcc(110) phase in a Kurdjumov-Sachs epitaxial
relationship. The structural evolution is discussed in relation with the
magnetic properties of the Fe clusters.Comment: 7 pages, 6 figures, submitted to Physical Review B September 200
Localized Magnetic States of Fe, Co, and Ni Impurities on Alkali Metal Films
X-ray absorption spectroscopy (XAS) and x-ray magnetic circular dichroism
(XMCD) have been used to study transition metal impurities on K and Na films.
The multiplet structure of the XAS spectra indicates that Fe, Co, and Ni have
localized atomic ground states with predominantly d7, d8, and d9 character,
respectively. XMCD shows that the localized impurity states possess large,
atomiclike, magnetic orbital moments that are progressively quenched as
clusters are formed. Ni impurities on Na films are found to be nonmagnetic,
with a strongly increased d10 character of the impurity state. The results show
that the high magnetic moments of transition metals in alkali hosts originate
from electron localization
Intricacies of the Co spin state in SrCoIrO: an x-ray absorption and magnetic circular dichroism study
We report on a combined soft x-ray absorption and magnetic circular dichroism
(XMCD) study at the Co- on the hybrid 3/5 solid state oxide
SrCoIrO with the KNiF structure. Our data
indicate unambiguously a pure high spin state for the Co
(3) ions with a significant unquenched orbital moment
despite the sizeable elongation of the CoO octahedra. Using quantitative
model calculations based on parameters consistent with our spectra, we have
investigated the stability of this high spin state with respect to the
competing low spin and intermediate spin states.Comment: 7 pages, 4 figure
Electronic tuneability of a structurally rigid surface intermetallic and Kondo lattice: CePt / Pt(111)
We present an extensive study of structure, composition, electronic and
magnetic properties of Ce--Pt surface intermetallic phases on Pt(111) as a
function of their thickness. The sequence of structural phases appearing in low
energy electron diffraction (LEED) may invariably be attributed to a single
underlying intermetallic atomic lattice. Findings from both microscopic and
spectroscopic methods, respectively, prove compatible with CePt formation
when their characteristic probing depth is adequately taken into account. The
intermetallic film thickness serves as an effective tuning parameter which
brings about characteristic variations of the Cerium valence and related
properties. Soft x-ray absorption (XAS) and magnetic circular dichroism (XMCD)
prove well suited to trace the changing Ce valence and to assess relevant
aspects of Kondo physics in the CePt surface intermetallic. We find
characteristic Kondo scales of the order of 10 K and evidence for
considerable magnetic Kondo screening of the local Ce moments.
CePt/Pt(111) and related systems therefore appear to be promising
candidates for further studies of low-dimensional Kondo lattices at surfaces.Comment: 14 pages, 11 figure
Oscillatory magnetic anisotropy in one-dimensional atomic wires
One-dimensional Co atomic wires grown on Pt(997) have been investigated by x-ray magnetic circular dichroism. Strong changes of the magnetic properties are observed as the system evolves from 1D- to 2D-like. The easy axis of magnetization, the magnetic anisotropy energy, and the coercive field oscillate as a function of the transverse width of the wires, in agreement with theoretical predictions for 1D metal systems
Two distinct pathways can control expression of the gene encoding the Drosophila antimicrobial peptide metchnikowin
Metchnikowin is a recently discovered proline-rich peptide from Drosophila with antibacterial and antifungal properties. Like most other antimicrobial peptides from insects, its expression is immune-inducible. Here we present evidence that induction of metchnikowin gene expression can be mediated either by the TOLL pathway or by the imd gene product. We show that the gene remains inducible in Toll-deficient mutants, in which the antifungal response is blocked, as well as in imd mutants, which fail to mount an antibacterial response. However, in Toll-deficient;imd double mutants, metchnikowin gene expression can no longer be detected after immune challenge. Our results suggest that expression of this peptide with dual activity can be triggered by signals generated by either bacterial or fungal infection. Cloning of the metchnikowin gene revealed the presence in the 5' flanking region of several putative cis-regulatory motifs characterized in the promoters of insect immune genes: namely, Rel sites, GATA motifs, interferon consensus response elements and NF-IL6 response elements. Establishment of transgenic fly lines in which the GFP reporter gene was placed under the control of 1.5 kb of metchnikowin gene upstream sequences indicates that this fragment is able to confer full immune inducibility and tissue specificity of expression on the transgene
Magnetic Coupling and Single-Ion Anisotropy in Surface-Supported Mn-based Metal-Organic Networks
The electronic and magnetic properties of Mn coordinated to
1,2,4,5-tetracyanobenzene (TCNB) in the Mn-TCNB 2D metal-ligand networks have
been investigated by combining scanning tunneling microscopy and X-ray magnetic
circular dichroism (XMCD) performed at low temperature (3 K). When formed on
Au(111) and Ag(111) substrates the Mn-TCNB networks display similar geometric
structures. Magnetization curves reveal ferromagnetic (FM) coupling of the Mn
sites with similar single-ion anisotropy energies, but different coupling
constants. Low-temperature XMCD spectra show that the local environment of the
Mn centers differs appreciably for the two substrates. Multiplet structure
calculations were used to derive the corresponding ligand field parameters
confirming an in-plane uniaxial anisotropy. The observed interatomic coupling
is discussed in terms of superexchange as well as substrate-mediated magnetic
interactions.Comment: J. Phys. Chem. C 201
Field-regulated switching of the magnetization of Co-porphyrin on graphene
Differentmagnetic couplingmechanisms have been identified for a fewmonolayers of Co-porphyrin molecules
deposited on a graphene-covered Ni(111) single crystal. A relatively strong antiferromagnetic coupling of the
first molecular layer via graphene to the Ni crystal in comparison to a weaker intermolecular coupling gives
rise to a complex field-dependent response of this hybrid system. By continuously increasing the magnetic field
strength, the net magnetization of the molecular system switches from antiparallel to parallel to the field direction
at 2.5 T. Utilizing x-ray absorption spectroscopy and x-ray magnetic circular dichroism, the element-specific
magnetization and field dependence was probed. The nature of the magnetic couplings is identified by means of
density functional theory and orbital-dependent susceptibilities
Tissue-specific inducible expression of antimicrobial peptide genes in Drosophila surface epithelia
The production of antimicrobial peptides is an important aspect of host defense in multicellular organisms. In Drosophila, seven antimicrobial peptides with different spectra of activities are synthesized by the fat body during the immune response and secreted into the hemolymph. Using GFP reporter transgenes, we show here that all seven Drosophila antimicrobial peptides can be induced in surface epithelia in a tissue-specific manner. The imd gene plays a critical role in the activation of this local response to infection. In particular, drosomycin expression, which is regulated by the Toll pathway during the systemic response, is regulated by imd in the respiratory tract, thus demonstrating the existence of distinct regulatory mechanisms for local and systemic induction of antimicrobial peptide genes in Drosophila
Uniform magnetic properties for an ultrahigh-density lattice of noninteracting Co nanostructures
We report on the magnetic properties of two-dimensional Co nanoparticles arranged in macroscopically phase-coherent superlattices created by self-assembly on Au(788). Our particles have a density of 26 Tera/in(2) (1 Tera=10(12)), are monodomain, and have uniaxial out-of-plane anisotropy. The distribution of the magnetic anisotropy energies has a half width at half maximum of 17%, a factor of 2 more narrow than the best results reported for superlattices of three-dimensional nanoparticles. Our data show the absence of magnetic interactions between the particles. Co/Au(788) thus constitutes an ideal model system to explore the ultimate density limit of magnetic recording
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