448 research outputs found

    Blame as Consolation: Rehabilitating the Iambic in Horace\u27s Post-Actian Symposia

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    Throughout his literary career, Horace is very careful in addressing political subjects within his poetry, especially the divisive subject of the Roman civil war, a conflict that was still painfully fresh in the national memory. One of the earliest instances in which the Roman civil war is directly addressed occurs in Epode 9, a sympotic poem addressed to Maecenas sometime during or immediately after the Battle of Actium. This poem appears in a body of work which is loosely modeled after the Greek iambic tradition, a poetic genre which is generally characterized as blame poetry. However, the mythical origins of the genre suggest that the original function of the genre was not blame, but consolation. In Epode 9, Horace presents an iambic poem which combines the blame and consolation functions associated with the iambic genre. There are only two other poems in the Horatian corpus which address civil war in a sympotic setting, namely Ode 1.37 and Ode 2.7. While they appear in a work set apart from the Epodes, both of these odes seem to contain certain stylistic and structural restatements of Epode 9, suggesting that Horace may have had this epode in mind when he was writing these later odes. The purpose of this paper is to assess the evolution of Horace\u27s response to the Roman civil war across these three pieces of political symposia by comparing the functions of lyric and iambic, and analyzing the sympotic setting that enhances the goal of consolation in each poem

    The Role of Covalent Functionalization in the Thermal Stability and Decomposition of Hybrid Layered Hydroxides

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    The room temperature synthesis of two Co-based hybrid layered hydroxides containing the same organic ligand (suberate [Sub]), one connected through purely electrostatic interactions (CoAl layered double hydroxide [LDH]), and the other covalently functionalized (α-CoII simonkolleite phase) has been carried out. The magnetic properties exhibit an acute difference in the magnetization temperatures (from ≈10 K for the CoAl-LDH to ≈55 K for the α-CoII). Moreover, the role of the covalent functionalization in the thermal stability and the decomposition has been investigated by a forefront characterization tool consisting of thermogravimetric analysis coupled with gas chromatography and mass spectrometry (TG-GC-MS). The LDH exhibits a higher thermal stability of ≈50 ÂșC with broad mass loss steps, whereas the water molecules interact stronger with the α-CoII(Sub) hybrid, suggesting a higher confinement in the interlayer space. Interestingly, at higher temperatures (>400 ÂșC), the α-CoII(Sub) gives rise to the selective formation of cycloheptanone, in contrast to the LDH phase leading to different carbonyl containing compounds. These findings offer new fundamental insights into the thermal behavior of hybrid materials based on layered hydroxides, highlighting the important role of covalent functionalization in its properties

    Resolving the Nature of the LMC Microlensing Event LMC-5

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    We present the results from an analysis of Hubble Space Telescope High Resolution Camera data for the Large Magellanic Cloud microlensing event MACHO-LMC-5. By determining the parallax and proper motion of this object we find that the lens is an M dwarf star at a distance of 578(+65/-53)pc with a proper motion of 21.39 +/- 0.04 mas/yr. Based on the kinematics and location of this star it more likely to be part of the Galactic thick disk than thin disk population. We confirm that the microlensing event LMC-5 is a jerk-parallax event.Comment: 4 pages, 1 figure, Accepted ApJL, minor change

    A Reanalysis of theUltraviolet Extinction from Interstellar Dust in the Large Magellanic Cloud

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    We have reanalyzed the Large Magellanic Cloud's (LMC) ultraviolet (UV) extinction using data from the IUE final archive. Our new analysis takes advantage of the improved signal--to--noise of the IUE NEWSIPS reduction, the exclusion of stars with very low reddening, the careful selection of well matched comparison stars, and an analysis of the effects of Galactic foreground dust. Differences between the average extinction curves of the 30 Dor region and the rest of the LMC are reduced compared to previous studies. We find that there is a group of stars with very weak 2175 Ang. bumps that lie in or near the region occupied by the supergiant shell, LMC 2, on the southeast side of 30 Dor. The average extinction curves inside and outside LMC 2 show a very significant difference in 2175 Ang. bump strength, but their far--UV extinctions are similar. While it is unclear whether or not the extinction outside the LMC 2 region can be fit with the relation of Cardelli, Clayton and Mathis (CCM), sightlines near LMC 2 cannot be fit with CCM due to their weak 2175 Ang. bumps. While the extinction properties seen in the LMC lie within the range of properties seen in the Galaxy, the correlations of UV extinction properties with environment seen in the Galaxy do not appear to hold in the LMC.Comment: 29 pages, 10 figures, to be published in Ap

    The Missing Link in the Magnetism of Hybrid Cobalt Layered Hydroxides: The Odd-Even Effect of the Organic Spacer

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    A dramatic change in the magnetic behaviour, which solely depends on the parity of the organic linker molecules, has been found in a family of layered Co-II hydroxides covalently functionalized with dicarboxylic molecules. These layered hybrid materials have been synthesized at room temperature using a one-pot procedure through the epoxide route. While hybrids connected by odd alkyl chains exhibit coercive fields (H-c) below ca. 3500 Oe and show spontaneous magnetization at temperatures (T-M) below 20 K, hybrids functionalized with even alkyl chains behave as hard magnets with H(c)5500 Oe and display a T-M higher than 55 K. This intriguing behaviour was studied by density functional theory with the incorporation of a Hubbard term (DFT+U) calculations, unveiling the structural subtleties underlying this observation. Indeed, the different molecular orientation exhibited by the even/odd alkyl chains, and the orientation of the covalently linked carboxylic groups modify the intensity of the magnetic coupling of both octahedral and tetrahedral in-plane sublattices, thus strongly affecting the magnetic properties of the hybrid. These findings offer an outstanding level of tuning in the molecular design of hybrid magnetic materials based on layered hydroxides

    Dust and Stellar Populations in the Large Magellanic Cloud

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    We present an analysis of line-of-sight extinction measurements obtained using data from the Magellanic Clouds Photometric Survey, which provides 4-filter photometry for millions of stars in the Large Magellanic Cloud. We find that visual extinctions are typically larger by several tenths of a magnitude for stars with effective temperatures > 12000 K, than for stars with effective temperatures between 5500 K and 6500 K. Several repercussions of this population-dependent extinction are discussed. In particular, LMC distance measurements that utilize old stellar populations (such as red clump stars), but use extinctions derived from OB stars, may be biased low. Population-dependent extinction affects the interpretation of color-magnitude diagrams and results in an effective absorption law that is steeper than that intrinsic to the dust for unresolved stellar systems. We further explore the relation between the stellar populations and dust by comparing our extinction map to the 100mu image of the region and identifying potential heating sources of the dust. We conclude that 100mu flux should be used with caution as a star formation tracer, particularly for studies of star formation within galaxies. Finally, we reproduce the observed extinction variation between the hot and cold stellar populations with a simple model of the distribution of the stars and dust where the scaleheight of the cooler stars is >> than that of the dust (which is twice that of the OB stars). (Abridged Abstract)Comment: Accepted for publication in AJ (scheduled for Dec. 1999). 31 pgs (including Figures

    Toward understanding the dynamics of land change in Latin America : potential utility of a resilience approach for building archetypes of landsystems change

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    Rocha, Juan C. Stockholm University. Stockholm Resilience Centre. Stockholm, Suecia.Baraibar, Matilda M. Stockholm University. Department of Economic History and International Relations. Stockholm, Suecia.Deutsch, Lisa. Stockholm University. Stockholm Resilience Centre. Stockholm, Suecia.Bremond, Ariane de. University of Bern. Centre for Development and Environment. Bern, Suiza.Oestreicher, Jordan S. Universidade de BrasĂ­lia. Centro de Desenvolvimento SustentĂĄvel. Distrito Federal, Brasil.Rositano, Florencia. Universidad de Buenos Aires. Facultad de AgronomĂ­a. Departamento de ProducciĂłn Vegetal. CĂĄtedra de Cerealicultura. Buenos Aires, Argentina.Gelabert, Cecilia Corina. Universidad de Buenos Aires. Facultad de AgronomĂ­a. Departamento de EconomĂ­a, Desarrollo y Planeamiento AgrĂ­cola. CĂĄtedra de Sistemas Agroalimentarios. Buenos Aires, Argentina.e17, 82 p.Climate change, financial shocks, and fluctuations in international trade are some of the reasons why resilience is increasingly invoked in discussions about land-use policy. However, resilience assessments come with the challenge of operationalization, upscaling their conclusions while considering the context-specific nature of land-use dynamics and the common lack of long-term data. We revisit the approach of system archetypes for identifying resilience surrogates and apply it to land-use systems using seven case studies spread across Latin America. The approach relies on expert knowledge and literature-based characterizations of key processes and patterns of land-use change synthesized in a data template. These narrative accounts are then used to guide development of causal networks, from which potential surrogates for resilience are identified. This initial test of the method shows that deforestation, international trade, technological improvements, and conservation initiatives are key drivers of land-use change, and that rural migration, leasing and land pricing, conflicts in property rights, and international spillovers are common causal pathways that underlie land-use transitions. Our study demonstrates how archetypes can help to differentiate what is generic from context dependant. They help identify common causal pathways and leverage points across cases to further elucidate how policies work and where, as well as what policy lessons might transfer across heterogeneous settings

    Room temperature synthesis of lanthanum phosphates with controlled nanotexture as host for Ln(III) through the Epoxide Route

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    Herein, the Epoxide Route, a one-pot room temperature alkalinization method based on the reaction between a nucleophile and an epoxide, has been employed to synthesize LaPO4 in the form of a Rhabdophane phase. The intrinsic features of this synthetic approach allow the reaction to be followed by pH monitoring, making possible the identification of the different precipitation steps involved in the formation of the solid. Once demonstrated the effectiveness of this chemical methodology, the size and shape of the LaPO4 particles were controlled by varying the identity and proportion of the organic co-solvents employed to perform the reaction. By these means, crystalline particles with dumbbell, urchin and needle shapes were obtained, with sizes that ranged from less than 200 nm to more than 5 Όm. Finally, luminescent materials in the form of a LnPO4 Rhabdophane structure were easily obtained by the incorporation of EuIII along the whole composition range. Additionally, photophysical characterization of selected samples was performed, with a promising outcome. The results presented in this work pave the way to obtaining a wide variety of luminescent materials with sizes and morphologies adjustable on demand, by using a simple and reliable synthetic approach
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