396 research outputs found
Ab initio investigation of VOSeO3, a spin gap system with coupled spin dimers
Motivated by an early experimental study of VOSeO3, which suggested that it
is a quasi-2D system of weakly coupled spin dimers with a small spin gap, we
have investigated the electronic structure of this material via
density-functional calculations. These ab initio results indicate that the
system is better thought of as an alternating spin-1/2 chain with moderate
interchain interactions, an analog of (VO)2P2O7. The potential interest of this
system for studies in high magnetic field given the presumably small value of
the spin gap is emphasized.Comment: 4 pages, 5 figure
Lattice Distortion and Magnetic Ground State of YTiO and LaTiO
Effects of lattice distortion on the magnetic ground state of YTiO and
LaiO are investigated on the basis accurate tight-binding parametrization
of the electronic structure extracted from the local-density
approximation. The complexity of these compounds is related with the fact that
the -level splitting, caused by lattice distortions, is comparable with
the energies of superexchange and spin-orbit interactions. Therefore, all these
interactions are equally important and should be treated on an equal footing.
The Hartree-Fock approximation fails to provide a coherent description
simultaneously for YTiO and LaTiO, and it is essential to go beyond.Comment: 4 pages, 3 figures (good quality figures are available via e-mail
Theoretical search for Chevrel phase based thermoelectric materials
We investigate the thermoelectric properties of some semiconducting Chevrel
phases. Band structure calculations are used to compute thermopowers and to
estimate of the effects of alloying and disorder on carrier mobility. Alloying
on the Mo site with transition metals like Re, Ru or Tc to reach a
semiconducting composition causes large changes in the electronic structure at
the Fermi level. Such alloys are expected to have low carrier mobilities.
Filling with transition metals was also found to be incompatible with high
thermoelectric performance based on the calculated electronic structures.
Filling with Zn, Cu, and especially with Li was found to be favorable. The
calculated electronic structures of these filled Chevrel phases are consistent
with low scattering of carriers by defects associated with the filling. We
expect good mobility and high thermopower in materials with the composition
close to (Li,Cu)MoSe, particularly when Li-rich, and recommend this
system for experimental investigation.Comment: 4 two-column pages, 4 embedded ps figure
First- principle calculations of magnetic interactions in correlated systems
We present a novel approach to calculate the effective exchange interaction
parameters based on the realistic electronic structure of correlated magnetic
crystals in local approach with the frequency dependent self energy. The analog
of ``local force theorem'' in the density functional theory is proven for
highly correlated systems. The expressions for effective exchange parameters,
Dzialoshinskii- Moriya interaction, and magnetic anisotropy are derived. The
first-principle calculations of magnetic excitation spectrum for ferromagnetic
iron, with the local correlation effects from the numerically exact QMC-scheme
is presented.Comment: 17 pages, 3 Postscript figure
Violation of the Wiedemann-Franz Law in a Large-N Solution of the t-J Model
We show that the Wiedemann-Franz law, which holds for Landau Fermi liquids,
breaks down in a large-n treatment of the t-J model. The calculated ratio of
the in-plane thermal and electrical conductivities agrees quantitatively with
experiments on the normal state of the electron-doped Pr_{2-x}Ce_xCuO_4 (x =
0.15) cuprate superconductor. The violation of the Wiedemann-Franz law in the
uniform phase contrasts with other properties of the phase that are Fermi
liquid like.Comment: 4 pages, 2 figures. Typos corrected, one added reference, revised
discussion of experiment on 214 cuprate material (x = 0.06
Halogen-mediated exchange in the coupled-tetrahedra quantum spin systems Cu2Te2O5X2 (X=Br,Cl)
Motivated by recent discussion on possible quantum critical behavior in the
coupled Cu-tetrahedra system Cu2Te2O5Br2, we present a comparative ab initio
study of the electronic properties of Cu2Te2O5Br2 and the isostructural
Cu2Te2O5Cl2.
A detailed investigation of the copper-copper interaction pathes reveals that
the halogen-ions play an important role in the inter-tetrahedral couplings via
X_4-rings (X=Br, Cl).
We find that, contrary to initial indications, both systems show a similar
electronic behavior with long range exchange pathes mediated by the X_4-rings.Comment: 5 pages, 7 figure
Interlayer tunneling spectroscopy of BiSrCaCuO: a look from inside on the doping phase diagram of high superconductors
A systematic, doping dependent interlayer tunneling spectroscopy of Bi2212
high superconductor is presented. An improved resolution made it possible
to simultaneously trace the superconducting gap (SG) and the normal state
pseudo-gap (PG) in a close vicinity of and to analyze closing of the PG
at . The obtained doping phase diagram exhibits a critical doping point
for appearance of the PG and a characteristic crossing of the SG and the PG
close to the optimal doping. This points towards coexistence of two different
and competing order parameters in Bi2212. Experimental data indicate that the
SG can form a combined (large) gap with the PG at and that the
interlayer tunneling becomes progressively incoherent with decreasing doping.Comment: 5 pages, 5 figure
Problem of a quantum particle in a random potential on a line revisited
The density of states for a particle moving in a random potential with a
Gaussian correlator is calculated exactly using the functional integral
technique. It is achieved by expressing the functional degrees of freedom in
terms of the spectral variables and the parameters of isospectral
transformations of the potential. These transformations are given explicitly by
the flows of the Korteweg-de Vries hierarchy which deform the potential leaving
all its spectral properties invariant. Making use of conservation laws reduces
the initial Feynman integral to a combination of quadratures which can be
readily calculated. Different formulations of the problem are analyzed.Comment: 11 pages, RevTex, preprint ANU-RSPhySE-20994 (comment added
Effect of bilayer coupling on tunneling conductance of double-layer high T_c cuprates
Physical effects of bilayer coupling on the tunneling spectroscopy of high
T cuprates are investigated. The bilayer coupling separates the bonding
and antibonding bands and leads to a splitting of the coherence peaks in the
tunneling differential conductance. However, the coherence peak of the bonding
band is strongly suppressed and broadened by the particle-hole asymmetry in the
density of states and finite quasiparticle life-time, and is difficult to
resolve by experiments. This gives a qualitative account why the bilayer
splitting of the coherence peaks was not clearly observed in tunneling
measurements of double-layer high-T oxides.Comment: 4 pages, 3 figures, to be published in PR
Photoemission spectra of : a theoretical analysis
Recent angle resolved photoemission (ARPES) results for the insulating
cuprate have provided the first experimental data
which can be directly compared to the (theoretically) well--studied problem of
a single hole propagating in an antiferromagnet. The ARPES results reported a
small bandwidth, providing evidence for the existence of strong correlations in
the cuprates. However, in the same experiment some discrepancies with the
familiar 2D model were also observed. Here we discuss a comparison
between the ARPES results and the quasiparticle dispersion of both (i) the
Hamiltonian and (ii) the three--band Hubbard model in the
strong--coupling limit. Both model Hamiltonians show that the experimentally
observed one--hole band structure can be approximately reproduced using
reasonable values for , or the direct oxygen hopping amplitude .Comment: 11 pages, RevTex version 3.0, 3 postscript figures, LaTeX file and
figures have been uuencoded
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