1,755 research outputs found
Stability of Landau-Ginzburg branes
We evaluate the ideas of Pi-stability at the Landau-Ginzburg point in moduli
space of compact Calabi-Yau manifolds, using matrix factorizations to B-model
the topological D-brane category. The standard requirement of unitarity at the
IR fixed point is argued to lead to a notion of "R-stability" for matrix
factorizations of quasi-homogeneous LG potentials. The D0-brane on the quintic
at the Landau-Ginzburg point is not obviously unstable. Aiming to relate
R-stability to a moduli space problem, we then study the action of the gauge
group of similarity transformations on matrix factorizations. We define a naive
moment map-like flow on the gauge orbits and use it to study boundary flows in
several examples. Gauge transformations of non-zero degree play an interesting
role for brane-antibrane annihilation. We also give a careful exposition of the
grading of the Landau-Ginzburg category of B-branes, and prove an index theorem
for matrix factorizations.Comment: 46 pages, LaTeX, summary adde
Semiorthogonal decompositions of derived categories of equivariant coherent sheaves
Let X be an algebraic variety with an action of an algebraic group G. Suppose
X has a full exceptional collection of sheaves, and these sheaves are invariant
under the action of the group. We construct a semiorthogonal decomposition of
bounded derived category of G-equivariant coherent sheaves on X into
components, equivalent to derived categories of twisted representations of the
group. If the group is finite or reductive over the algebraically closed field
of zero characteristic, this gives a full exceptional collection in the derived
equivariant category. We apply our results to particular varieties such as
projective spaces, quadrics, Grassmanians and Del Pezzo surfaces.Comment: 28 pages, uses XY-pi
Structure of 2-Methyl-5,6,7-triphenyl-6,7-dihydropyrazolo[2,3-\u3cem\u3ea\u3c/em\u3e]pyrimidine
C25H21N3, Mr = 363.46, monoclinic, P21/n, a = 9.245 (2), b = 23.502 (5), c = 9.340 (2) Γ
, Ξ²= 103.50(3)Β°, V=1973.3(2) Γ
3, Z=4, Dx= 1.220 (2) g cm-3, Ξ» (Mo KΞ± )= 0.71069 Γ
, ΞΌ = 0.068 cm-1, F(000) = 768, T= 292 K, R = 0.091 for 1442 unique observed reflections. The dihydropyrimidine ring adopts a distorted sofa conformation. The aryl substituents on the saturated C atoms have an axial orientation
Π‘ΠΈΠ½ΡΠ΅Π· ΡΠ° N-Π°Π»ΠΊΡΠ»ΡΠ²Π°Π½Π½Ρ Π΄ΡΠ΅ΡΠΈΠ» 4,7-Π΄ΠΈΠ³ΡΠ΄ΡΠΎΠ°Π·ΠΎΠ»ΠΎ[1,5-a]ΠΏΡΡΠΈΠΌΡΠ΄ΠΈΠ½-5,6-Π΄ΠΈΠΊΠ°ΡΠ±ΠΎΠΊΡΠΈΠ»Π°ΡΡΠ²
It has been shown that the ternary condensation of oxaloacetic ester (diethyl 2-oxosuccinate), aromatic aldehydesΒ and 3-amino-1,2,4-triazole or 5-aminotetrazole in dimethylformamide results in formation of the corresponding diethyl 7-aryl-4,7-dihydroazolo[1,5-a]pyrimidin-5,6-dicarboxylates. By 1H NMR spectroscopy (according to the data of the chemical shifts of C(2)H-protons for the corresponding N(4)H- and N(4)-methylderivatives ofΒ 7-phenyl-4,7-dihydro[1,2,4]triazolo[1,5-a]pyrimidin-5,6-dicarboxylate) it has been found that alkylation of 4,7-dihydro[1,2,4]azolo[1,5-a]pyrimidin-5,6-dicarboxylates in the acetonitrileβsaturated water alkali system leads selectively to formation of N(4)-alkyl derivatives. Both the starting compounds obtained and their N(4)-methylsubstitutedΒ analogues together with relative diethyl 4-aryl-3,4-dihydropyrimidin-2(1H)-on-5,6-dicarboxylates, 6-unsubstitutedΒ 4-aryl-3,4-dihydropyrimidin-2(1H)-on-5-dicarboxylates and the derivatives of 6-COR-7-aryl-4,7-dihydro[1,2,4] triazolo[1,5-a]pyrimidines are the promising objects for studying benzyl C(7)-functionalization of 4,7-dihydroazoloΒ 1,5-a]pyrimidines, as well as of reactions associated with the presence of double C=C-bonds activated by twoΒ electron withdrawing groups. Obtaining of the key N(4)H- and N(4)Me-derivatives of 7-phenyl-4,7-dihydro[1,2,4]Β triazolo- and tetrazolo[1,5-a]pyrimidin-5,6-dicarboxylates also opens the way to the research of biological propertiesΒ of the compounds of this class. It is noteworthy that being a three-component one the reaction studied, without any doubts, are appropriate for the synthesis of the derivatives of 7-aryl-4,7-dihydro[1,2,4]triazolo- andΒ tetrazolo[1,5-a]pyrimidines containing two electron withdrawing substituents in positions 5 and 6.ΠΠΎΠΊΠ°Π·Π°Π½ΠΎ, ΡΡΠΎ ΡΡΠ΅Ρ
ΠΊΠΎΠΌΠΏΠΎΠ½Π΅Π½ΡΠ½Π°Ρ ΠΊΠΎΠ½Π΄Π΅Π½ΡΠ°ΡΠΈΡ ΡΠ°Π²Π΅Π»Π΅Π²ΠΎΡΠΊΡΡΡΠ½ΠΎΠ³ΠΎ ΡΡΠΈΡΠ° (Π΄ΠΈΡΡΠΈΠ» 2-ΠΎΠΊΡΠΎΡΡΠΊΡΠΈΠ½Π°ΡΠ°),Β Π°ΡΠΎΠΌΠ°ΡΠΈΡΠ΅ΡΠΊΠΈΡ
Π°Π»ΡΠ΄Π΅Π³ΠΈΠ΄ΠΎΠ² ΠΈ 3-Π°ΠΌΠΈΠ½ΠΎ-1,2,4-ΡΡΠΈΠ°Π·ΠΎΠ»Π° ΠΈΠ»ΠΈ 5-Π°ΠΌΠΈΠ½ΠΎΡΠ΅ΡΡΠ°Π·ΠΎΠ»Π° Π² Π΄ΠΈΠΌΠ΅ΡΠΈΠ»ΡΠΎΡΠΌΠ°ΠΌΠΈΠ΄Π΅ ΠΏΡΠΈΠ²ΠΎΠ΄ΠΈΡ ΠΊ ΠΎΠ±ΡΠ°Π·ΠΎΠ²Π°Π½ΠΈΡ ΡΠΎΠΎΡΠ²Π΅ΡΡΡΠ²ΡΡΡΠΈΡ
Π΄ΠΈΡΡΠΈΠ» 7-Π°ΡΠΈΠ»-4,7-Π΄ΠΈΠ³ΠΈΠ΄ΡΠΎΠ°Π·ΠΎΠ»ΠΎ[1,5-a]ΠΏΠΈΡΠΈΠΌΠΈΠ΄ΠΈΠ½-5,6-Π΄ΠΈΠΊΠ°ΡΠ±ΠΎΠΊΡΠΈΠ»Π°ΡΠΎΠ². Π‘ ΠΏΠΎΠΌΠΎΡΡΡ 1Π Π―ΠΠ -ΡΠΏΠ΅ΠΊΡΡΠΎΡΠΊΠΎΠΏΠΈΠΈ (ΠΏΠΎ Π΄Π°Π½Π½ΡΠΌ Ρ
ΠΈΠΌΠΈΡΠ΅ΡΠΊΠΈΡ
ΡΠ΄Π²ΠΈΠ³ΠΎΠ² ΡΠΈΠ³Π½Π°Π»ΠΎΠ² ΠΏΡΠΎΡΠΎΠ½ΠΎΠ² Π‘(2)HΒ Π΄Π»Ρ ΡΠΎΠΎΡΠ²Π΅ΡΡΡΠ²ΡΡΡΠΈΡ
N(4)H- ΠΈ N(4)ΠΠ΅-ΠΏΡΠΎΠΈΠ·Π²ΠΎΠ΄Π½ΡΡ
Π΄ΠΈΡΡΠΈΠ» 7-ΡΠ΅Π½ΠΈΠ»-4,7-Π΄ΠΈΠ³ΠΈΠ΄ΡΠΎ[1,2,4]ΡΡΠΈΠ°Π·ΠΎΠ»ΠΎ[1,5-a]Β ΠΏΠΈΡΠΈΠΌΠΈΠ΄ΠΈΠ½-5,6-Π΄ΠΈΠΊΠ°ΡΠ±ΠΎΠΊΡΠΈΠ»Π°ΡΠ°) ΡΡΡΠ°Π½ΠΎΠ²Π»Π΅Π½ΠΎ, ΡΡΠΎ Π°Π»ΠΊΠΈΠ»ΠΈΡΠΎΠ²Π°Π½ΠΈΠ΅ 7-Π°ΡΠΈΠ»-4,7-Π΄ΠΈΠ³ΠΈΠ΄ΡΠΎΠ°Π·ΠΎΠ»ΠΎ[1,5-a]ΠΏΠΈΡΠΈΠΌΠΈΠ΄ΠΈΠ½-5,6-Π΄ΠΈΠΊΠ°ΡΠ±ΠΎΠΊΡΠΈΠ»Π°ΡΠΎΠ² Π² ΡΠΈΡΡΠ΅ΠΌΠ΅ Π°ΡΠ΅ΡΠΎΠ½ΠΈΡΡΠΈΠ»-Π½Π°ΡΡΡΠ΅Π½Π½Π°Ρ Π²ΠΎΠ΄Π½Π°Ρ ΡΠ΅Π»ΠΎΡΡ ΡΠ΅Π»Π΅ΠΊΡΠΈΠ²Π½ΠΎ ΠΏΡΠΈΠ²ΠΎΠ΄ΠΈΡ ΠΊ ΠΎΠ±ΡΠ°Π·ΠΎΠ²Π°Π½ΠΈΡ N(4)-Π°Π»ΠΊΠΈΠ»ΠΏΡΠΎΠΈΠ·Π²ΠΎΠ΄Π½ΡΡ
. ΠΠ°ΠΊ ΠΏΠΎΠ»ΡΡΠ΅Π½Π½ΡΠ΅ ΠΈΡΡ
ΠΎΠ΄Π½ΡΠ΅ ΡΠΎΠ΅Π΄ΠΈΠ½Π΅Π½ΠΈΡ, ΡΠ°ΠΊ ΠΈ ΠΈΡ
N(4)-ΠΌΠ΅ΡΠΈΠ»Π·Π°ΠΌΠ΅ΡΠ΅Π½Π½ΡΠ΅ Π°Π½Π°Π»ΠΎΠ³ΠΈ Π½Π°ΡΡΠ΄Ρ Ρ ΡΠΎΠ΄ΡΡΠ²Π΅Π½Π½ΡΠΌΠΈ Π΄ΠΈΡΡΠΈΠ» 4-Π°ΡΠΈΠ»-3,4-Π΄ΠΈΠ³ΠΈΠ΄ΡΠΎΠΏΠΈΡΠΈΠΌΠΈΠ΄ΠΈΠ½-2(1Π)-ΠΎΠ½-5,6-Π΄ΠΈΠΊΠ°ΡΠ±ΠΎΠΊΡΠΈΠ»Π°ΡΠ°ΠΌΠΈ, 6-Π½Π΅Π·Π°ΠΌΠ΅ΡΠ΅Π½Π½ΡΠΌΠΈ ΡΡΠΈΠ» 4-Π°ΡΠΈΠ»-3,4-Π΄ΠΈΠ³ΠΈΠ΄ΡΠΎΠΏΠΈΡΠΈΠΌΠΈΠ΄ΠΈΠ½-2(1Π)-ΠΎΠ½-5-ΠΊΠ°ΡΠ±ΠΎΠΊΡΠΈΠ»Π°ΡΠ°ΠΌΠΈ ΠΈΒ ΠΏΡΠΎΠΈΠ·Π²ΠΎΠ΄Π½ΡΠΌΠΈ 6-COR-7-Π°ΡΠΈΠ»-4,7-Π΄ΠΈΠ³ΠΈΠ΄ΡΠΎ[1,2,4]ΡΡΠΈΠ°Π·ΠΎΠ»ΠΎ[1,5-a]ΠΏΠΈΡΠΈΠΌΠΈΠ΄ΠΈΠ½ΠΎΠ² ΡΠ²Π»ΡΡΡΡΡ ΠΏΠ΅ΡΡΠΏΠ΅ΠΊΡΠΈΠ²Π½ΡΠΌΠΈ ΠΎΠ±ΡΠ΅ΠΊΡΠ°ΠΌΠΈ Π΄Π»Ρ ΠΈΠ·ΡΡΠ΅Π½ΠΈΡ Π±Π΅Π½Π·ΠΈΠ»ΡΠ½ΠΎΠΉ Π‘(7)-ΡΡΠ½ΠΊΡΠΈΠΎΠ½Π°Π»ΠΈΠ·Π°ΡΠΈΠΈ 4,7-Π΄ΠΈΠ³ΠΈΠ΄ΡΠΎΠ°Π·ΠΎΠ»ΠΎ[1,5-a]ΠΏΠΈΡΠΈΠΌΠΈΠ΄ΠΈΠ½ΠΎΠ², Π° ΡΠ°ΠΊΠΆΠ΅ ΡΠ΅Π°ΠΊΡΠΈΠΉ, ΡΠ²ΡΠ·Π°Π½Π½ΡΡ
Ρ Π½Π°Π»ΠΈΡΠΈΠ΅ΠΌ Π΄Π²ΠΎΠΉΠ½ΠΎΠΉ C=C-ΡΠ²ΡΠ·ΠΈ, Π°ΠΊΡΠΈΠ²ΠΈΡΠΎΠ²Π°Π½Π½ΠΎΠΉ Π΄Π²ΡΠΌΡ Π°ΠΊΡΠ΅ΠΏΡΠΎΡΠ½ΡΠΌΠΈ Π³ΡΡΠΏΠΏΠ°ΠΌΠΈ. ΠΠΎΠ»ΡΡΠ΅Π½ΠΈΠ΅ ΠΊΠ»ΡΡΠ΅Π²ΡΡ
N(4)H- ΠΈ N(4)ΠΠ΅-ΠΏΡΠΎΠΈΠ·Π²ΠΎΠ΄Π½ΡΡ
7-ΡΠ΅Π½ΠΈΠ»-4,7-Π΄ΠΈΠ³ΠΈΠ΄ΡΠΎ[1,2,4]ΡΡΠΈΠ°Π·ΠΎΠ»ΠΎ- ΠΈ ΡΠ΅ΡΡΠ°Π·ΠΎΠ»ΠΎ[1,5-a]ΠΏΠΈΡΠΈΠΌΠΈΠ΄ΠΈΠ½-5,6-Π΄ΠΈΠΊΠ°ΡΠ±ΠΎΠΊΡΠΈΠ»Π°ΡΠΎΠ² ΡΠ°ΠΊΠΆΠ΅ ΠΎΡΠΊΡΡΠ²Π°Π΅Ρ ΠΏΡΡΡ ΠΊ Π±ΠΈΠΎΠ»ΠΎΠ³ΠΈΡΠ΅ΡΠΊΠΈΠΌ ΠΈΡΡΠ»Π΅Π΄ΠΎΠ²Π°Π½ΠΈΡΠΌΒ ΡΠΎΠ΅Π΄ΠΈΠ½Π΅Π½ΠΈΠΉ ΡΡΠΎΠ³ΠΎ ΠΊΠ»Π°ΡΡΠ°. ΠΠ°ΠΌΠ΅ΡΠΈΠΌ, ΡΡΠΎ ΠΈΡΡΠ»Π΅Π΄ΠΎΠ²Π°Π½Π½Π°Ρ ΡΠ΅Π°ΠΊΡΠΈΡ, ΡΠ²Π»ΡΡΡΡ ΡΡΠ΅Ρ
ΠΊΠΎΠΌΠΏΠΎΠ½Π΅Π½ΡΠ½ΠΎΠΉ, Π±Π΅Π·ΡΡΠ»ΠΎΠ²Π½ΠΎ ΠΏΠΎΠ΄Ρ
ΠΎΠ΄ΠΈΡ Π΄Π»Ρ ΡΠΈΠ½ΡΠ΅Π·Π° ΠΈ ΠΈΡΡΠ»Π΅Π΄ΠΎΠ²Π°Π½ΠΈΡ ΠΊΠΎΠΌΠ±ΠΈΠ½Π°ΡΠΎΡΠ½ΡΡ
Π±ΠΈΠ±Π»ΠΈΠΎΡΠ΅ΠΊ ΠΏΡΠΎΠΈΠ·Π²ΠΎΠ΄Π½ΡΡ
7-Π°ΡΠΈΠ»-4,7-Π΄ΠΈΠ³ΠΈΠ΄ΡΠΎ[1,2,4]ΡΡΠΈΠ°Π·ΠΎΠ»ΠΎ- ΠΈ ΡΠ΅ΡΡΠ°Π·ΠΎΠ»ΠΎ[1,5-a]ΠΏΠΈΡΠΈΠΌΠΈΠ΄ΠΈΠ½ΠΎΠ², ΡΠΎΠ΄Π΅ΡΠΆΠ°ΡΠΈΡ
Π΄Π²Π° ΡΠ»Π΅ΠΊΡΡΠΎΠ½ΠΎΠ°ΠΊΡΠ΅ΠΏΡΠΎΡΠ½ΡΡ
Π·Π°ΠΌΠ΅ΡΡΠΈΡΠ΅Π»Ρ Π² ΠΏΠΎΠ»ΠΎΠΆΠ΅Π½ΠΈΡΡ
5 ΠΈ 6.ΠΠΎΠΊΠ°Π·Π°Π½ΠΎ, ΡΠΎ ΡΡΠΈΠΊΠΎΠΌΠΏΠΎΠ½Π΅Π½ΡΠ½Π° ΠΊΠΎΠ½Π΄Π΅Π½ΡΠ°ΡΡΡ ΡΠ°Π²Π»Π΅Π²ΠΎΠΎΡΡΠΎΠ²ΠΎΠ³ΠΎ Π΅ΡΡΠ΅ΡΡ (Π΄ΡΠ΅ΡΠΈΠ» 2-ΠΎΠΊΡΠΎΡΡΠΊΡΠΈΠ½Π°ΡΡ), Π°ΡΠΎΠΌΠ°ΡΠΈΡΠ½ΠΈΡ
Π°Π»ΡΠ΄Π΅Π³ΡΠ΄ΡΠ² ΡΠ° 3-Π°ΠΌΡΠ½ΠΎ-1,2,4-ΡΡΠΈΠ°Π·ΠΎΠ»Ρ Π°Π±ΠΎ 5-Π°ΠΌΡΠ½ΠΎΡΠ΅ΡΡΠ°Π·ΠΎΠ»Ρ Π² Π΄ΠΈΠΌΠ΅ΡΠΈΠ»ΡΠΎΡΠΌΠ°ΠΌΡΠ΄Ρ ΠΏΡΠΈΠ·Π²ΠΎΠ΄ΠΈΡΡΒ Π΄ΠΎ ΡΡΠ²ΠΎΡΠ΅Π½Π½Ρ Π²ΡΠ΄ΠΏΠΎΠ²ΡΠ΄Π½ΠΈΡ
Π΄ΡΠ΅ΡΠΈΠ» 4,7-Π΄ΠΈΠ³ΡΠ΄ΡΠΎΠ°Π·ΠΎΠ»ΠΎ[1,5-a]ΠΏΡΡΠΈΠΌΡΠ΄ΠΈΠ½-5,6-Π΄ΠΈΠΊΠ°ΡΠ±ΠΎΠΊΡΠΈΠ»Π°ΡΡΠ². ΠΠ° Π΄ΠΎΠΏΠΎΠΌΠΎΠ³ΠΎΡΒ 1Π Π―ΠΠ -ΡΠΏΠ΅ΠΊΡΡΠΎΡΠΊΠΎΠΏΡΡ (Π·Π° Π΄Π°Π½ΠΈΠΌΠΈ ΠΏΡΠΎ Ρ
ΡΠΌΡΡΠ½Ρ Π·ΡΡΠ²ΠΈ ΡΠΈΠ³Π½Π°Π»ΡΠ² ΠΏΡΠΎΡΠΎΠ½ΡΠ² Π‘(2)Π Π΄Π»Ρ Π²ΡΠ΄ΠΏΠΎΠ²ΡΠ΄Π½ΠΈΡ
N(4)H- ΡΠ°Β N(4)Me-ΠΏΠΎΡ
ΡΠ΄Π½ΠΈΡ
Π΄ΡΠ΅ΡΠΈΠ» 7-ΡΠ΅Π½ΡΠ»-4,7-Π΄ΠΈΠ³ΡΠ΄ΡΠΎ[1,2,4]ΡΡΠΈΠ°Π·ΠΎΠ»ΠΎ[1,5-a]ΠΏΡΡΠΈΠΌΡΠ΄ΠΈΠ½-5,6-Π΄ΠΈΠΊΠ°ΡΠ±ΠΎΠΊΡΠΈΠ»Π°ΡΡΠ²) Π²ΡΡΠ°-Π½ΠΎΠ²Π»Π΅Π½ΠΎ, ΡΠΎ Π°Π»ΠΊΡΠ»ΡΠ²Π°Π½Π½Ρ 4,7-Π΄ΠΈΠ³ΡΠ΄ΡΠΎΠ°Π·ΠΎΠ»ΠΎ[1,5-a]ΠΏΡΡΠΈΠΌΡΠ΄ΠΈΠ½-5,6-Π΄ΠΈΠΊΠ°ΡΠ±ΠΎΠΊΡΠΈΠ»Π°ΡΡΠ² Ρ ΡΠΈΡΡΠ΅ΠΌΡ Π°ΡΠ΅ΡΠΎΠ½ΡΡΡΠΈΠ»Π½Π°ΡΠΈΡΠ΅Π½ΠΈΠΉ Π²ΠΎΠ΄Π½ΠΈΠΉ Π»ΡΠ³ ΡΠ΅Π»Π΅ΠΊΡΠΈΠ²Π½ΠΎ ΠΏΡΠΈΠ·Π²ΠΎΠ΄ΠΈΡΡ Π΄ΠΎ ΡΡΠ²ΠΎΡΠ΅Π½Π½Ρ N(4)-Π°Π»ΠΊΡΠ»ΠΏΠΎΡ
ΡΠ΄Π½ΠΈΡ
. Π―ΠΊ ΠΎΡΡΠΈΠΌΠ°Π½Ρ Π²ΠΈΡ
ΡΠ΄Π½ΡΒ ΡΠΏΠΎΠ»ΡΠΊΠΈ, ΡΠ°ΠΊ Ρ ΡΡ
Π½Ρ N(4)-ΠΌΠ΅ΡΠΈΠ»Π·Π°ΠΌΡΡΠ΅Π½Ρ Π°Π½Π°Π»ΠΎΠ³ΠΈ ΠΏΠΎΡΡΠ΄ Π·Ρ ΡΠΏΠΎΡΡΠ΄Π½Π΅Π½ΠΈΠΌΠΈ Π΄ΡΠ΅ΡΠΈΠ» 4-Π°ΡΠΈΠ»-3,4-Π΄ΠΈΠ³ΡΠ΄ΡΠΎΠΏΡΡΠΈΠΌΡΠ΄ΠΈΠ½-2(1Π)-ΠΎΠ½-5,6-Π΄ΠΈΠΊΠ°ΡΠ±ΠΎΠΊΡΠΈΠ»Π°ΡΠ°ΠΌΠΈ, 6-Π½Π΅Π·Π°ΠΌΡΡΠ΅Π½ΠΈΠΌΠΈ Π΅ΡΠΈΠ» 4-Π°ΡΠΈΠ»-3,4-Π΄ΠΈΠ³ΡΠ΄ΡΠΎΠΏΡΡΠΈΠΌΡΠ΄ΠΈΠ½-2(1Π)-ΠΎΠ½-5-ΠΊΠ°ΡΠ±ΠΎΠΊΡΠΈΠ»Π°ΡΠ°ΠΌΠΈ ΡΠ° ΠΏΠΎΡ
ΡΠ΄Π½ΠΈΠΌΠΈ 6-COR-7-Π°ΡΠΈΠ»-4,7-Π΄ΠΈΠ³ΡΠ΄ΡΠΎ[1,2,4]ΡΡΠΈΠ°Π·ΠΎΠ»ΠΎ[1,5-a]ΠΏΡΡΠΈΠΌΡΠ΄ΠΈΠ½ΡΠ² Ρ ΠΏΠ΅ΡΡΠΏΠ΅ΠΊΡΠΈΠ²Π½ΠΈΠΌΠΈ ΠΎΠ±βΡΠΊΡΠ°ΠΌΠΈ Π΄Π»Ρ Π²ΠΈΠ²ΡΠ΅Π½Π½Ρ Π±Π΅Π½Π·ΠΈΠ»ΡΠ½ΠΎΡ Π‘(7)-ΡΡΠ½ΠΊΡΡΠΎΠ½Π°Π»ΡΠ·Π°ΡΡΡ 4,7-Π΄ΠΈΠ³ΡΠ΄ΡΠΎΠ°Π·ΠΎΠ»ΠΎ[1,5-a]ΠΏΡΡΠΈΠΌΡΠ΄ΠΈΠ½ΡΠ², Π° ΡΠ°ΠΊΠΎΠΆ ΡΠ΅Π°ΠΊΡΡΠΉ,Β ΠΏΠΎΠ²βΡΠ·Π°Π½ΠΈΡ
Π· Π½Π°ΡΠ²Π½ΡΡΡΡ ΠΏΠΎΠ΄Π²ΡΠΉΠ½ΠΎΠ³ΠΎ C=C-Π·Π²βΡΠ·ΠΊΡ, Π°ΠΊΡΠΈΠ²ΠΎΠ²Π°Π½ΠΎΠ³ΠΎ Π΄Π²ΠΎΠΌΠ° Π°ΠΊΡΠ΅ΠΏΡΠΎΡΠ½ΠΈΠΌΠΈ Π³ΡΡΠΏΠ°ΠΌΠΈ. ΠΡΡΠΈΠΌΠ°Π½Π½ΡΒ ΠΊΠ»ΡΡΠΎΠ²ΠΈΡ
N(4)H- Ρ N(4)ΠΠ΅-ΠΏΠΎΡ
ΡΠ΄Π½ΠΈΡ
7-ΡΠ΅Π½ΡΠ»-4,7-Π΄ΠΈΠ³ΡΠ΄ΡΠΎ[1,2,4]ΡΡΠΈΠ°Π·ΠΎΠ»ΠΎ- ΡΠ° ΡΠ΅ΡΡΠ°Π·ΠΎΠ»ΠΎ[1,5-a]ΠΏΡΡΠΈΠΌΡΠ΄ΠΈΠ½-5,6-Π΄ΠΈΠΊΠ°ΡΠ±ΠΎΠΊΡΠΈΠ»Π°ΡΡΠ² ΡΠ°ΠΊΠΎΠΆ Π²ΡΠ΄ΠΊΡΠΈΠ²Π°Ρ ΡΠ»ΡΡ
Π΄ΠΎ Π±ΡΠΎΠ»ΠΎΠ³ΡΡΠ½ΠΈΡ
Π΄ΠΎΡΠ»ΡΠ΄ΠΆΠ΅Π½Ρ ΡΠΏΠΎΠ»ΡΠΊ ΡΡΠΎΠ³ΠΎ ΠΊΠ»Π°ΡΡ. ΠΡΠ΄Π·Π½Π°ΡΠΈΠΌΠΎ,Β ΡΠΎ Π΄ΠΎΡΠ»ΡΠ΄ΠΆΠ΅Π½Π° ΡΠ΅Π°ΠΊΡΡΡ, Π±ΡΠ΄ΡΡΠΈ ΡΡΠΈΠΊΠΎΠΌΠΏΠΎΠ½Π΅Π½ΡΠ½ΠΎΡ, Π±Π΅Π·ΡΠΌΠΎΠ²Π½ΠΎ ΠΏΡΠ΄Ρ
ΠΎΠ΄ΠΈΡΡ Π΄Π»Ρ ΡΠΈΠ½ΡΠ΅Π·Ρ ΡΠ° Π΄ΠΎΡΠ»ΡΠ΄ΠΆΠ΅Π½Π½ΡΒ ΠΊΠΎΠΌΠ±ΡΠ½Π°ΡΠΎΡΠ½ΠΈΡ
Π±ΡΠ±Π»ΡΠΎΡΠ΅ΠΊ ΠΏΠΎΡ
ΡΠ΄Π½ΠΈΡ
7-Π°ΡΠΈΠ»-4,7-Π΄ΠΈΠ³ΡΠ΄ΡΠΎ[1,2,4]ΡΡΠΈΠ°Π·ΠΎΠ»ΠΎ- ΡΠ° ΡΠ΅ΡΡΠ°Π·ΠΎΠ»ΠΎ[1,5-a]ΠΏΡΡΠΈΠΌΡΠ΄ΠΈΠ½ΡΠ²,Β ΡΠΎ ΠΌΡΡΡΡΡΡ Π΄Π²Π° Π΅Π»Π΅ΠΊΡΡΠΎΠ½ΠΎΠ°ΠΊΡΠ΅ΠΏΡΠΎΡΠ½Ρ Π·Π°ΠΌΡΡΠ½ΠΈΠΊΠΈ Ρ ΠΏΠΎΠ»ΠΎΠΆΠ΅Π½Π½ΡΡ
5 ΡΠ° 6
Bound, virtual and resonance -matrix poles from the Schr\"odinger equation
A general method, which we call the potential -matrix pole method, is
developed for obtaining the -matrix pole parameters for bound, virtual and
resonant states based on numerical solutions of the Schr\"odinger equation.
This method is well-known for bound states. In this work we generalize it for
resonant and virtual states, although the corresponding solutions increase
exponentially when . Concrete calculations are performed for the
ground and the first excited states of , the resonance
states (, ), low-lying states of and
, and the subthreshold resonances in the proton-proton system. We
also demonstrate that in the case the broad resonances their energy and width
can be found from the fitting of the experimental phase shifts using the
analytical expression for the elastic scattering -matrix. We compare the
-matrix pole and the -matrix for broad resonance in
Comment: 14 pages, 5 figures (figures 3 and 4 consist of two figures each) and
4 table
Risk factors and clinical and neurological consequences of intraoperative rupture of brain aneurysms in microsurgical operations
Objective. to assess the frequency, risk factors and clinical and neurological consequences of intraoperative rupture of arterial aneurysm (AA) of the brain (B) in clipping operations of the B AA .
Materials and approaches. A retrospective analysis of microsurgical operations clipping of cerebral aneurysms in 1449 (100%) patients for the period from 2011 to 2018 was performed, of which 141 (9.73%) cases had intraoperative rupture of the aneurysm (IORA). Preoperative examination: clinical and neurological examination, CT of the brain, cerebral angiography( CAG), duplex scanning of the main vessels of the head and neck. The analyzed criteria are risk factors of IORA: AA size, localization, shape, duration of surgery after the primary rupture of AA, the presence of hypertension and the patient's condition before surgery.
Results. The frequency of IORA in clipping operations of B AA was 9.73% (141 patients) in a series of observations 1441 (100%). Most often IORA-141 (100%) was registered in clipping operations of AA of complex ACA-AcomA (86 (61%) cases out of 141 (100%)). IORA is possible at all stages of the operation with the maximum frequency of contact breaks β 135 (95.74%); the rarest-6 ( 4.26%) - non - contact IORA (at the stage of craniotomy) was recorded. At the preoperative stage, the vast majority of patients with subsequent IORA were diagnosed with cerebral edema, AA of large size, atherosclerotic changes in the aneurysm-affected segment of the artery and cervical areas of the aneurysm, high blood pressure during surgery, adhesive arachnoid changes. At the time of discharge from the hospital, according to the Glasgow results scale: 69 (48.94%) full or partial restoration of labor activity, 18 (12.77%) had limited daily activities without the need for outside assistance, 37 (26 24%) deep disability ) Deaths were in the group of "contact" IORA - 17 (12.06%). At 6 ( 4.26%) of "non-contact" IORA, a deepening of initial neurological symptoms was recorded with a suppression of the level of consciousness, the addition of pyramidal insufficiency, speech impairment and psycho-organic syndrome, and a deepening of the phenomena of initial cerebral arterial vasospasm.
Conclusions. IORA is predominantly in contact with a frequency of occurrence-9.73 %. The most common risk factors for IORA were: cerebral edema, large AA, atherosclerotic changes in the aneurysm-affected artery segment and cervical aneurysm sites, high blood pressure during surgery, adhesions arachnoid changes. IORA leads to deepening of initial neurological symptoms, phenomena of initial vasospasm of cerebral arteries with the level of total mortality-17 (12.06%)
Anisotropic fragmentation in low-energy dissociative recombination
On a dense energy grid reaching up to 75 meV electron collision energy the
fragmentation angle and the kinetic energy release of neutral dissociative
recombination fragments have been studied in a twin merged beam experiment. The
anisotropy described by Legendre polynomials and the extracted rotational state
contributions were found to vary on a likewise narrow energy scale as the
rotationally averaged rate coefficient. For the first time angular dependences
higher than 2 order could be deduced. Moreover, a slight anisotropy at
zero collision energy was observed which is caused by the flattened velocity
distribution of the electron beam.Comment: 8 pages, 4 figures; The Article will be published in the proceedings
of DR 2007, a symposium on Dissociative Recombination held in Ameland, The
Netherlands (18.-23. July 2008); Reference 19 has been published meanwhile in
S. Novotny, PRL 100, 193201 (2008
Age and growth of blue Antimora Antimora rostrata (Moridae) in Southwestern Greenland waters
The results of determination of age and study on growth of blue antimora Antimora rostrata from the waters of Southwestern Greenland are presented. The results are based on the analysis of 200 fish otoliths. In the catches, we found specimens of antimora with total lengths of 18β70 cm, body weights of 23β2731 g, at the age of 7β38 years. Minimal age of males (not considering juvenile individuals) was 10 years at body length of 27β33 cm; maximal age was 18 years at 42 cm. Minimal age of females was 9 years at length of 21β27 cm; maximal age was 38 years at 70 cm. The rate of linear growth in blue antimora from Southwestern Greenland waters is comparable to that in the fish from New Zealand and Ross Sea waters but considerably lower than indicated earlier for fish from the waters of Iceland, Greenland, and the Mid-Atlantic Ridge. The age of reaching sexual maturity in males and females is preliminary determined as 15 and 19β20 years, respectively
Growth and age of the roughhead grenadier Macrourus berglax in waters off Southwest Greenland
Data on the age and growth of the roughhead grenadier Macrourus berglax from waters off Southwest Greenland have been obtained based on the analysis of otoliths. Specimens with a preanal length of 5β39 cm, a weight of 7β5275 g, and age from 2 to 22 years are recorded in trawl catches. Roughhead grenadier exhibits a similar rate of linear growth in waters off Southwest Greenland and other parts of the range in the Northwest Atlantic. No considerable differences from the rate of the linear growth calculated earlier from scales for the species in waters off West Greenland have been found. In the recent period, the rate of weight gain in roughhead grenadier in waters off Southwest Greenland has been lower than in the Northwest Atlantic in the first half of the 1980s. The age of mass maturation in males (7β9 years) and females (16β17 years) in waters off West and East Greenland is somewhat higher than in coastal waters of Norway and the Northwest Atlantic
Big data analytics for continuous assessment of astronaut health risk and its application to human-in-the-loop (HITL) related aerospace
Β© 2017, American Institute of Aeronautics and Astronautics Inc, AIAA. All rights reserved. The man-instrumentation-equipment-vehicle-environment ecosystem is complex in aerospace missions. Health status of the individual has important implications on decision making and performance that should be factored into assessments for probability of success/risk of failure both in offline and real-time models. To date probabilistic models have not considered the dynamic nature of health status. Big Data analytics is enabling new forms of analytics to assess health status in real-time. There is great potential to integrate dynamic health status information with platforms assessing risk and the probability of success for dynamic individualized real-time probabilistic predictive risk assessment. In this research we present an approach utilizing Big Data analytics to enable continuous assessment of astronaut health risk and show its implications for integration with HITL related aerospace mission
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