Rauvolfia vormitoria Effect on the Degradation of Aluminium Alloy in 2.5 M Hydrochloric Acid Solution

The deterioration of aluminium alloy in 2.5 M hydrochloric acid in the presence Rauvolfia vormitoria extract was examined using both gasometric and gravimetric techniques. Aluminium coupons measuring 4 cm by 1 cm were introduced into test solutions of uninhibited acid and also those containing extract quantities of 10, 20, 30 and 40 cm3 at ambient temperature of 250C for a total cumulative period of 117 minutes. The volumes of hydrogen gas evolved and weight loss readings were recorded and analyzed to obtain weight loss and corrosion rate for each coupon at specific time intervals. The results however, showed that while extract quantity was increasing; weight loss measurements increased but inhibitor efficiency decreased. Also, the metal surface-phytoconstituent interaction mechanism was consistent with the Temkin adsorption isotherm and the 3 minutes curve showed the best exposure time for phytochemicals to adsorb to alloy surface. Furthermore, microstructural studies showed an indirect relationship between metallic degradation and extract quantity, while uniformity of the irregular intermetallic phases increased with increasing extract quantity

Resource and cost management

Educational lecture notes contains the fundamentals of a general theory of resource and cost management, classification of costs for decision-making, methods of constructing cost functions of the enterprise, analysis of the relationship between costs, volume and profits, the methods and systems of cost calculation, principles of cost management system. Designed for students directions 073 «Management» and 076 «Entrepreneurship, trade and exchange activity»

Adsorption Behaviour of [(4-Hydroxy-6-methyl-2-oxo-2Hpyran- 3-yl)-(4-methoxy-phenyl)-1methyl]-urea on Stainless Steel in Phosphoric Media

The adsorption of [(4-hydroxy-6-methyl-2-oxo-2H-pyran-3-yl)-(4-methoxy-phenyl)- methyl]-urea on iron in phosphoric media was studied by using electrochemical technique. The adsorption mechanism was investigated using adsorption isotherms. The experimental data fit localized adsorption models. The values for free energy of adsorption, o DGads , were also calculated at each surface coverage, �, of the studied compound by applying the mathematical model of Bockris – Swinkels adsorption isotherm. The variation of free energy of adsorption o ads DG with surface coverage, �, was interpreted in terms of deviation from ideal condition assumed in Langmuir model. A possible adsorption model of HPU2 molecules on to the metal surface was suggested

Electrical conductivity of hot Abelian plasma with scalar charge carriers

We study the electrical conductivity of hot Abelian plasma containing scalar charge carriers in the leading logarithmic order in coupling constant $\alpha$ using the Boltzmann kinetic equation. The leading contribution to the collision integral is due to the M{\o}ller and Bhabha scattering of scalar particles with a singular cross section in the region of small momentum transfer. Regularizing this singularity by taking into account the hard thermal loop corrections to the propagators of intermediate particles, we derive the second order differential equation which determines the kinetic function. We solve this equation numerically and also use a variational approach in order to find a simple analytical formula for the conductivity. It has the standard parametric dependence on the coupling constant $\sigma\approx 2.38\, T/(\alpha \log\alpha^{-1})$ with the prefactor taking a somewhat lower value compared to the fermionic case. Finally, we consider the general case of hot Abelian plasma with an arbitrary number of scalar and fermionic particle species and derive the simple analytical formula for its conductivity.Comment: 36 pages, 2 figures, 4 table

Investigating the Acid Failure of Aluminium Alloy in 2 M Hydrochloric Acid Using Vernonia amygdalina

The acid failure of aluminium alloy in 2 M hydrochloric acid solution in the presence of Vernonia amygdalina extract was investigated using gasometric technique. Aluminium alloy coupons of dimension 4 cm by 1 cm were immersed in test solutions of free acid and also those containing extract volumes of 2, 3, 4 and 5 cm3 at ambient temperature for 30 minutes. The volumes of hydrogen gas evolved as a result of the rate of reaction were recorded and analyzed. Analysis revealed that maximum inhibitor efficiency which corresponds to the lowest corrosion rate was obtained at optimum inhibitor volumes of 5 cm3, with reduction in the corrosion rate observed to follow in order of increasing extract volumes. Adsorption study revealed that Temkin isotherm best described the metal surface interaction with the extract phytochemicals, with 12 minutes becoming the best exposure time for the phytochemicals to adsorb to the metal surface at all volumes. Statistical modelling of the corrosion rate yielded an important relationship suitable for estimating corrosion rate values once volumes of the extract is known. Microstructural studies, showed an indirect relationship between crack growth rates and extract volumes, while consistency of the irregular intermetallic phases increases with increasing extract volumes

Band twisting and resilience to disorder in long-range topological superconductors

Planar topological superconductors with power-law-decaying pairing display different kinds of topological phase transitions where quasiparticles dubbed nonlocal-massive Dirac fermions emerge. These exotic particles form through long-range interactions between distant Majorana modes at the boundary of the system. We show how these propagating-massive Dirac fermions neither mix with bulk states nor Anderson-localize up to large amounts of static disorder despite being finite energy. Analyzing the density of states (DOS) and the band spectrum of the long-range topological superconductor, we identify the formation of an edge gap and a surprising double peak structure in the DOS which can be linked to a twisting of energy bands with nontrivial topology. Our findings are amenable to experimental verification in the near future using atom arrays on conventional superconductors, planar Josephson junctions on two-dimensional electron gases, and Floquet driving of topological superconductors.Comment: 9 pages, 8 figure