Materials’ Methods: NMR in Battery Research

Improving electrochemical energy storage is one of the major issues of our time. The search for new battery materials together with the drive to improve performance and lower cost of existing and new batteries is not without its challenges. Success in these matters is undoubtedly based on first understanding the underlying chemistries of the materials and the relations between the components involved. A combined application of experimental and theoretical techniques has proven to be a powerful strategy to gain insights into many of the questions that arise from the “how do batteries work and why do they fail” challenge. In this Review, we highlight the application of solid-state nuclear magnetic resonance (NMR) spectroscopy in battery research: a technique that can be extremely powerful in characterizing local structures in battery materials, even in highly disordered systems. An introduction on electrochemical energy storage illustrates the research aims and prospective approaches to reach these. We particularly address “NMR in battery research” by giving a brief introduction to electrochemical techniques and applications as well as background information on both in and ex situ solid-state NMR spectroscopy. We will try to answer the question “Is NMR suitable and how can it help me to solve my problem?” by shortly reviewing some of our recent research on electrodes, microstructure formation, electrolytes and interfaces, in which the application of NMR was helpful. Finally, we share hands-on experience directly from the lab bench to answer the fundamental question “Where and how should I start?” to help guide a researcher’s way through the manifold possible approaches.This project has received funding from the European Union’s Horizon 2020 research and innovation program under the Marie Skłodowska-Curie grant agreement No 655444 (O.P.). K.J.G. thanks the Winston Churchill Foundation of the United States and the Herchel Smith Scholarship for financial support

Obesity-induced changes in lipid mediators persist after weight loss.

BackgroundObesity induces significant changes in lipid mediators, however, the extent to which these changes persist after weight loss has not been investigated.Subjects/methodsWe fed C57BL6 mice a high-fat diet to generate obesity and then switched the diet to a lower-fat diet to induce weight loss. We performed a comprehensive metabolic profiling of lipid mediators including oxylipins, endocannabinoids, sphingosines and ceramides in key metabolic tissues (including adipose, liver, muscle and hypothalamus) and plasma.ResultsWe found that changes induced by obesity were largely reversible in most metabolic tissues but the adipose tissue retained a persistent obese metabolic signature. Prostaglandin signaling was perturbed in the obese state and lasting increases in PGD2, and downstream metabolites 15-deoxy PGJ2 and delta-12-PGJ2 were observed after weight loss. Furthermore expression of the enzyme responsible for PGD2 synthesis (hematopoietic prostaglandin D synthase, HPGDS) was increased in obese adipose tissues and remained high after weight loss. We found that inhibition of HPGDS over the course of 5 days resulted in decreased food intake in mice. Increased HPGDS expression was also observed in human adipose tissues obtained from obese compared with lean individuals. We then measured circulating levels of PGD2 in obese patients before and after weight loss and found that while elevated relative to lean subjects, levels of this metabolite did not decrease after significant weight loss.ConclusionsThese results suggest that lasting changes in lipid mediators induced by obesity, still present after weight loss, may play a role in the biological drive to regain weight

Optimising Ferrite-less Pad Reflection Winding with a Multi-Objective Genetic Algorithm

Inductive power transfer is the leading technology for roadway electric vehicle wireless power transfer. A robust magnetic design is desired for magnetic couplers (pads) that are to be buried in a road surface. Ferrite-less designs including a reflection winding have been shown to be a possible way to increase the robustness of pads and reduce leakage magnetic field. This paper presents a methodology to optimise the reflection winding of a ferrite-less pad with a genetic algorithm and presents the results of an example optimisation with an axisymmetric approximation of the wireless power transfer standard SAE J2954 WPT3/Z3 secondary pad, with the results verified in the finite element analysis package FEMM, and in the laboratory. The results verify the reflection coil concept and indicate that improvements in leakage per power can be gained by allowing the reflection winding to be non-planar

Mobility of Discrete Solitons in Quadratically Nonlinear Media

We study the mobility of solitons in second-harmonic-generating lattices. Contrary to what is known for their cubic counterparts, discrete quadratic solitons are mobile not only in the one-dimensional (1D) setting, but also in two dimensions (2D). We identify parametric regions where an initial kick applied to a soliton leads to three possible outcomes, namely, staying put, persistent motion, or destruction. For the 2D lattice, it is found that, for the solitary waves, the direction along which they can sustain the largest kick and can attain the largest speed is the diagonal. Basic dynamical properties of the discrete solitons are also discussed in the context of an analytical approximation, in terms of an effective Peierls-Nabarro potential in the lattice setting.Comment: 4 page

Statics, Dynamics and Manipulations of Bright Matter-Wave Solitons in Optical Lattices

Motivated by recent experimental achievement in the work with Bose-Einstein condensates (BECs), we consider bright matter-wave solitons, in the presence of a parabolic magnetic trap and a spatially periodic optical lattice (OL), in the attractive BEC. We examine pinned states of the soliton and their stability by means of perturbation theory. The analytical predictions are found to be in good agreement with numerical simulations. We then explore possibilities to use a time-modulated OL as a means of stopping and trapping a moving soliton, and of transferring an initially stationary soliton to a prescribed position by a moving OL. We also study the emission of radiation from the soliton moving across the combined magnetic trap and OL. We find that the soliton moves freely (without radiation) across a weak lattice, but suffers strong loss for stronger OLs.Comment: 7 pages, 5 figs, Phys Rev A in Press (2005

Towards two-dimensional metallic behavior at LaAlO3/SrTiO3 interfaces

Using a low-temperature conductive-tip atomic force microscope in cross-section geometry we have characterized the local transport properties of the metallic electron gas that forms at the interface between LaAlO3 and SrTiO3. At low temperature, we find that the carriers do not spread away from the interface but are confined within ~10 nm, just like at room temperature. Simulations taking into account both the large temperature and electric-field dependence of the permittivity of SrTiO3 predict a confinement over a few nm for sheet carrier densities larger than ~6 10^13 cm-2. We discuss the experimental and simulations results in terms of a multi-band carrier system. Remarkably, the Fermi wavelength estimated from Hall measurements is ~16 nm, indicating that the electron gas in on the verge of two-dimensionality.Comment: Accepted for publication in Physical Review Letter

Flavonoides presentes en extractos hexánicos de especies del género Sideritis

In continuation to the studies of the Genus Sideritis that this Pharmacology Department has done, we have isolated and identificated the flavonoid compounds in the hexanic extracts of ten species of this Genus by an HPLC method. We have to remark the presence of Isoscutellarein-7-0-(allosyl-glucoside), in all the studied extracts.Continuando con los trabajos llevados a cabo en el Dep. de Farmacología, sobre el género Sideri tis, hemos separado e identificado los flavonoides presentes en los extractos hexánicos correspondientes a 10 especies de dicho género, por técnicas de HPLC y con ayuda de patrones. Entre los compuestos aislados, cabe destacar la isoscutelareina 7-0-(alosil-glucósido), presente en todos los extractos

Enhancing nonlinear interactions by the superposition of plasmonic lattices on ꭕ(2)-nonlinear photonic crystals

Plasmonic structures have been revealed as efficient units to enhance localized nonlinear phenomena generated at dielectric-metal interfaces. However, their effect on the nonlinear interactions provided by quasi-phase matching processes in ꭕ(2) modulated dielectric crystals have been scarcely addressed, mainly due to the complexity in manufacturing appropriate periodic plasmonic structures overlying the ꭕ(2) dielectric structure. Here, by a simple method we have fabricated a periodic structure based on the combination of two commensurate lattices: a periodic lattice of chains of Ag nanoparticles and a periodic lattice of ꭕ(2)-modulation based on a ferroelectric domains structure. The hybrid system supports multiple surface plasmon lattice resonances (SLRs) at the technologically relevant NIR spectral region, which yield the enhancement of the nonlinear diffraction pattern generated by the ꭕ(2) structure. The superposition of the plasmonic and the ꭕ(2)-modulation lattice results in a 20-fold enhancement of the directional SHG due to the excitation of SLRs by the interacting waves involved in the nonlinear process. The results are obtained in lithium niobate, a widely used crystal in optoelectronics, and demonstrate the potential of the approach to design integrated solid-state platforms for on-chip optical steering, multiplexing or quantum technologiesThis work has been supported by the Spanish Government (Contracts MAT2016-76106-R and PID2019-108257GB-I00/ AEI/10.13039/501100011033 and María de Maeztu “Pro gramme for Units of Excellence in R&D CEX2018-000805-M) and Comunidad de Madrid (Grant SI1/PJI/2019-00105