Change but no climate change: discourses of climate change in corporate social responsibility reporting in the oil industry

Using corpus linguistic tools and methods, this paper investigates the discourses of climate change in corporate social responsibility (CSR) and environmental reports produced by major oil companies from 2000 to 2013. It focuses on the frequency of key references to climatic changes and examines in detail discourses surrounding the most frequently used term ‘climate change’. The analysis points to shifting patterns in the ways in which climate change has been discursively constructed in the studied sample. Whereas in the mid-2000s, it was seen as a phenomenon that something could be done about, in recent years the corporate discourse has increasingly emphasised the notion of risk portraying climate change as an unpredictable agent. A pro-active stance signalled by the use of force metaphors is offset by a distancing strategy often indicated through the use of hedging devices and ‘relocation’ of climate change to the future and other stakeholders. In doing so, the discourse obscures the sector’s large contribution to environmental degradation and ‘grooms’ the public perception to believe that the industry actively engages in climate change mitigation. At the methodological level, this study shows how a combination of quantitative corpus-linguistic and qualitative discourse-analytical techniques can offer insights into the existence of salient discursive patterns and contribute to a better understanding of the role of language in performing ideological work in corporate communications

The use of complementary and alternative medicine products in preceding two days among Finnish parents - a population survey

<p>Abstract</p> <p>Background</p> <p>The use of complementary and alternative medicines (CAM) has been extensively studied globally among adult and paediatric populations. Parents, as a group, had not been studied to assess their knowledge and attitude to CAM and general medicine use. This study is necessary since parents' attitude to medicine use is known to influence their child's attitude to medicine use later in life. We therefore aim to assess the extent and types of CAM use among Finnish parents, and to determine the factors that promote the CAM use. Also, we aim to determine parents' attitude to general medicine use.</p> <p>Methods</p> <p>Children less than 12 years old, as of spring 2007, were identified from the database of the Finnish Population Register Centre and were selected by random sampling. The parents of these children were identified and a questionnaire was sent to them. Only the parent who regularly takes care of the child's medicine was requested to fill the questionnaire. Cross-tabulations and Chi-square test were used to determine the associations between categorical variables. CAMs were defined as natural products that are not registered as medicines, such as homeopathic preparations, dietary food supplements, and traditional medicinal products.</p> <p>Results</p> <p>The response rate of the survey was 67% (n = 4032). The use of CAM was 31% in the preceding two days. The most commonly used CAM products were vitamins and minerals, followed by fish oils and fatty acids. Prescription and OTC medicines were used concomitantly with CAM by one-third of the parents. CAM was frequently used by parents over 30 years (33%), female parents (32%), highly educated parents (35%), and parents with high monthly net income (3000-3999 euros, 34%). The users of CAM had more negative attitudes towards medicines than non-users of CAM.</p> <p>Conclusions</p> <p>Our findings are in accordance with those of previous studies that women over 30 years of age with a high education and income typically use CAMs. Finnish parents seem to use CAMs as complementary rather than alternative to medicines. Health care professionals should take into consideration both the concomitant use as well as the negative attitudes among CAM users in encounters with the parents.</p

Functionalized isothianaphthene containing polymers as n-type fullerene substitutes in organic photovoltaics

N-type donor-acceptor block copolymers were synthesized containing functionalized isothianaphthene (ITN) acceptors as possible fullerene substitutes for organic photovoltaics. The ITN monomer was functionalized with strong electron withdrawing substituents which resulted in a slight decrease in the polymers' HOMO and a significant decrease in the LUMO. In such manner, the energy levels of ITN polymers were tuned by varying the electron-withdrawing strength of the substituents. For instance, by incorporating two nitrile groups into the ITN unit, a polymer was synthesized (ITN-CN) with energy levels comparable to that of the fullerene n-types commonly used in bulk heterojunctions. The resulting polymers were employed in lieu of fullerene acceptors using poly(3-(4- n-octyl)-phenylthiophene) as the p-type polymer. Using ITN-CN, photoconversion efficiencies (PCE) of up to 0.30% were obtained

Fast synthetic X-mode Doppler reflectometry diagnostics for the full-f global gyrokinetic modeling of the FT-2 tokamak

The fast linear (Born approximation) version of the X-mode Doppler reflectometry (DR) synthetic diagnostics is developed in the framework of the ELMFIRE global gyrokinetic modeling of the FT-2 tokamak ohmic discharge. The DR signal frequency spectra and the dependence of their frequency shift and shape on the probing antenna position are computed and shown to be similar to those measured in the high magnetic field side probing DR experiment at the FT-2 tokamak. The fluctuation poloidal velocities are determined using the DR experiment and synthetic diagnostics and shown to be within 15%. However, the computed and measured dependences of the DR signal power on the antenna position appear to be different presumably due to underestimation of the small-scale trapped electron mode turbulence component in the measurement region by the code.Peer reviewe

Influence of the probing wave phase modulation on the X-mode radial correlation Doppler reflectometry performance in the FT-2 tokamak

The cross-correlation function of high field side radial correlation X-mode Doppler reflectometry (DR) measured in the FT-2 tokamak experiment is shown to be a factor of three narrower than that computed using the fast linear (Born approximation) version of the X-mode DR synthetic diagnostics developed in the framework of the ELMFIRE global gyrokinetic modeling of the FT-2 ohmic discharge. This difference is observed in spite of the fact that the computed DR signal frequency spectra are shown to be similar to those measured. A modest phase modulation of the probing and backscattering waves by the long-scale turbulent density fluctuations is shown, both experimentally and in computation, to be responsible for the observed effect.Peer reviewe

Validation of full-f global gyrokinetic modeling results against the FT-2 tokamak Doppler reflectometry data using synthetic diagnostics

International audienceTwo versions of the X-mode Doppler reflectometry (DR) synthetic diagnostics are developed within the framework of the ELMFIRE global gyrokinetic modeling of the FT-2 tokamak ohmic discharge. In the 'fast' version the DR signal is computed in the linear theory approximation using the reciprocity theorem, utilizing the probing wave field pattern provided by computation and taking into account the 2D plasma inhomogeneity effects; whereas the alternative 'slow' version DR synthetic diagnostic is based on the full-wave code IPF-FD3D describing the probing and scattered wave propagation in turbulent plasma. The DR signal frequency spectra and the dependence of their frequency shift, width and shape on the probing antenna position are computed and shown to be similar to those measured in the high-field side probing DR experiment at the FT-2 tokamak. The geodesic acoustic mode characteristics provided by the measurements and by the synthetic DR are close within a 12% accuracy. However, a substantial difference was found in the decay of the DR signal cross-correlation functions with growing frequency shift in the probing wave channels. The quick decrease in the radial correlation DR coherence observed in the experiment and full-wave synthetic diagnostic, compared to the fast synthetic DR, is attributed to the nonlinear effect of the probing wave phase modulation by the turbulence in the former two cases. The variation in the DR signal at a growing incidence angle in the experiment is also shown to be slower than predicted by both of the synthetic diagnostics, presumably due to underestimation of the probing wave phase modulation and consequent nonlinear saturation of the DR signal at lower incidence angles in modeling

Control of Polymer-Packing Orientation in Thin Films through Synthetic Tailoring of Backbone Coplanarity

Controlling solid-state order of π-conjugated polymers through macromolecular design is essential for achieving high electronic device performance; yet, it remains a challenge, especially with respect to polymer-packing orientation. Our work investigates the influence of backbone coplanarity on a polymer’s preference to pack face-on or edge-on relative to the substrate. Isoindigo-based polymers were synthesized with increasing planarity by systematically substituting thiophenes for phenyl rings in the acceptor comonomer. This increasing backbone coplanarity, supported by density functional theory (DFT) calculations of representative trimers, leads to the narrowing of polymer band gaps as characterized by ultraviolet-visible-near infrared (UV-vis-NIR) spectroscopy and cyclic voltammetry. Among the polymers studied, regiosymmetric II and TII polymers exhibited the highest hole mobilities in organic field-effect transistors (OFETs), while in organic photovoltaics (OPVs), TBII polymers that display intermediate levels of planarity provided the highest power conversion efficiencies. Upon thin-film analysis by atomic force microscropy (AFM) and grazing-incidence X-ray diffraction (GIXD), we discovered that polymer-packing orientation could be controlled by tuning polymer planarity and solubility. Highly soluble, planar polymers favor face-on orientation in thin films while the less soluble, nonplanar polymers favor an edge-on orientation. This study advances our fundamental understanding of how polymer structure influences nanostructural order and reveals a new synthetic strategy for the design of semiconducting materials with rationally engineered solid-state properties